• Bulletin of the Korean Chemical Society
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• 제30권9호
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• pp.2071-2076
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• 2009

The single-walled carbon nanotubes (SWCNTs) produced by chemical vapor deposition (CVD) were directly fluorinated with fluorine ($F_2$) gas in a temperature range 20 ~ 400 ${^{\circ}C}$. The surface properties and morphology of the SWCNTs were investigated in terms of fluorination temperature. As a result, Raman spectra showed a pair of bands at 1340 and 1590 $cm^{-1}$ peculiar to disordered $sp^2$-carbons. These results indicated that C-F bonds were formed on the rear surfaces of the nanotubes by fluorination, while the external surfaces as well as the layers between the internal and external surfaces retained their $sp^2$-hybridization. XPS analysis exhibited that fluorine atoms were bonded to carbon atoms on internal surfaces (rear surfaces) of the nanotubes and the amount of fluorine attached on the nanotubes was increased with increasing the fluorination temperature. Consequently, the direct fluorination of carbon nanotubes led to functionalization and modification of pristine nanotubes with respect to surface and morphological properties.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2008년도 추계학술대회 논문집 전기설비전문위원
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• pp.203-206
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• 2008

To improve mean-life and reliability of power cable in this study, we have investigated chemical properties showing by changing the content of carbon black that is semiconductive additives for underground power transmission. Specimens were made of sheet form with the three of existing resins and the nine of specimens for measurement. Chemical properties of specimens was measured by FT-ATR (Fourier Transform Attenuated Total Reflectance). The condition of specimens was a solid sheet. We could observe functional group (C=O, carbonyl group) of specimens through FT-ATR. From these experimental result, the concentration of functional group (C=O) was high according to increasing the content of carbon black. We could know EEA was excellent more than other specimens from above experimental results.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2011년도 춘계학술대회 초록집
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• pp.159.2-159.2
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• 2011

In this study, we prepared the activated graphite nanofibers (A-GNFs) via chemical activation with KOH reagent. The effect of A-GNFs on the surface and textural properties of Ni-loaded graphite nanofibers (Ni/GNFs) was investigated by X-ray diffraction (XRD), transmission electron microscope (TEM), and Brunauer-Emmett-Teller (BET). The textural properties of samples were investigated by $N_2$/77K adsorption isotherms. The electrochemical performances were investigated by cyclic voltammetry. As a results, the electrochemical performances of Ni/GNFs were improved with usage of A-GNFs. This could be interpreted by the high specific surface area and large total pore volume of the A-GNFs.

• 한국결정학회지
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• 제11권4호
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• pp.195-199
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• 2000

Ceramics based on CaTiO₃-NdAlO₃ solid solutions were synthesized in order to study their dielectric microwave properties. Microstructural analysis was performed with scanning electron microscopy (SEM) and transmission electron microscopy (TEM) using different analytical methods such as energy-dispersive X-ray spectroscopy (EDXS). It was observed that the heating conditions during sintering and cooling strongly affect the microstructural development of CaTiO₃-NdAlO₃-based ceramics. Various types and concentrations of structural defects were identified, for example, dislocations, twins and/or antiphase boundaries. all such defects resulted in a degradation of the dielectric microwave properties, in particular the quality factor Q. Dielectric properties of CaTiO₃-NdAlO₃-based ceramics can be improved by an appropriate thermal treatment of ceramics which results in a decrease in the concentrations of the identified microstructural defects.

• 한국세라믹학회지
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• 제29권3호
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• pp.177-182
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• 1992

The effect of heat-treatment temperature on the microwave absorbing properties was investigated in Ni0.8Zn0.2Fe2O4 specimens. The composite specimens were prepared by modling and curing the mixture of prereacted ferrite powder and silicone rubber. The measurement of complex permeability and permittivity was made by the reflection/transmission method. The most sensitive material constants with heat-treatment temperature is the imaginary (loss) component of permeability. The higher the heat-treatment temperature, the greater the magnetic loss. The composite specimens with high magnetic loss exhibited superior microwave absorbing properties. The quantitative estimation of microwave absorbing properties were made by plotting the observed material constants on the calculated solution map of impedance-matching.

• 한국세라믹학회지
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• 제32권1호
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• pp.131-139
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• 1995

In order to improve transmittance and response properties, various compositions of light controllable films were prepared by phase separation method. The optical and response properties were measured with the variation of PMMA/suspension ratio and block copolymer/light polarizing particles. According to the increase of the PMMA/suspension ratio, the separated droplets of suspension were interconnected in the film. Decay time was 2.6 sec when PMMA/suspension ratio was 0.5 : 1 and ΔT(difference of the transmittance at OFF/ON states) was reduced with increasing of the ratio of PMMA/suspension. On block copolymer/light polarizing particles ratio variation, the highest transmittance of the film was 67.4% when its ratio was 0.6 : 1 and decay time was varied from 2.15 to 46.6 sec as block copolymer content increased 0.2 : 1 to 1 : 1.

• Fibers and Polymers
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• 제6권4호
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• pp.289-296
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• 2005

Biodegradable nanocomposites were prepared by mixing a polymer resin and layered silicates by the melt intercalation method. Internal structure of the nanocomposite was characterized by using the small angle X-ray scattering (SAXS) and transmission electron microscope (TEM). Nanocomposites having exfoliated and intercalated structures were obtained by employing two different organically modified nanoclays. Rheological properties in shear and extensional flows and biodegradability of nanocomposites were measured. In shear flow, shear thinning behavior and increased storage modulus were observed as the clay loading increased. In extensional flow, strain hardening behavior was observed in well dispersed system. Nanocomposites with the exfoliated structure had better biodegradability than nanocomposites with the intercalated structure or pure polymer.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2001년도 추계학술대회 논문집 Vol.14 No.1
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• pp.255-257
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• 2001

In this paper, the silicon rubber insulator for transmission line was experimented for 1,000 hours aging test in salt-fog condition. To evaluate and examine the aging properties of silicon rubber insulator for test, the leakage current of surface was measured. Also hydrophobicity and scanning electron microscopy were compared with initial and aged sample respectively. Above results, we can confirm that the surface properties of silicon rubber insulator easily aged by salt-fog condition.

• 동력기계공학회지
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• 제18권3호
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• pp.100-105
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• 2014

This study is to investigate the effect of thermo mechanical treatment on the mechanical properties of 316L stainless steel. ${\alpha}^{\prime}$ and ${\varepsilon}$-martensite was formed by deformation. With increasing number of thermo mechanical treatment, volume fraction of martensite was increased rapidly, and then unchanged. With increasing number of thermo mechanical treatment, hardness and strength was increased rapidly, and then unchanged while elongation was decreased rapidly, and then unchanged. With increasing volume fraction of martensite formed by thermo mechanical treatment, hardness and strength was increased rapidly, elongation was decreased rapidly. Thus, hardness, strength and elongation of thermo mechanical treated 316L stainless steel was strongly affected by martensite formed by thermo mechanical treatment. Good combination of strength and elongation was obtained from thermomechanical treatment.

• Korea-Australia Rheology Journal
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• 제20권4호
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• pp.227-233
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• 2008

High impact polystyrene (HIPS)/organoclay nanocomposites via in situ polymerization were synthesized and their rheological properties were investigated. For the study, two types of organoclays were used: a commercially available organoclay, Cloisite 10A (C10A), and a laboratory-prepared organoclay having a reactant group, vinylclay (ODVC). The X-ray diffraction and transmission electron microscopy experiments revealed that the HIPS/ODVC nanocomposite achieved an exfoliated structure, whereas the HIPS/C10A nanocomposite achieved an intercalated structure. In the small-amplitude oscillatory shear experiments, both storage modulus and complex viscosity increased with increasing organoclay. A pronounced effect of the organoclay content was observed, resulting in larger storage modulus and stronger yield behavior in the low frequency region when compared to neat HIPS. The crossover frequencies associated with the inverse of a longest relaxation time decreased as the organoclay content increased. Over a certain value of ODVC content, a change of pattern in rheological properties could be found, indicating a solid-like response with storage modulus greater than loss modulus at all frequencies.