• Title/Summary/Keyword: Transition state theory

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Augmentation of Hidden Markov Chain for Complex Sequential Data in Context

  • Sin, Bong-Kee
    • Journal of Multimedia Information System
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    • v.8 no.1
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    • pp.31-34
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    • 2021
  • The classical HMM is defined by a parameter triple �� = (��, A, B), where each parameter represents a collection of probability distributions: initial state, state transition and output distributions in order. This paper proposes a new stationary parameter e = (e1, e2, …, eN) where N is the number of states and et = P(|xt = i, y) for describing how an input pattern y ends in state xt = i at time t followed by nothing. It is often said that all is well that ends well. We argue here that all should end well. The paper sets the framework for the theory and presents an efficient inference and training algorithms based on dynamic programming and expectation-maximization. The proposed model is applicable to analyzing any sequential data with two or more finite segmental patterns are concatenated, each forming a context to its neighbors. Experiments on online Hangul handwriting characters have proven the effect of the proposed augmentation in terms of highly intuitive segmentation as well as recognition performance and 13.2% error rate reduction.

Multichannel Quantum-Defect Study of q reversals in Overlapping Resonances in Systems involving 1 Open and 2 Closed Channels

  • Cho, Byung-Hoon;Lee, Chun-Woo
    • Bulletin of the Korean Chemical Society
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    • v.31 no.2
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    • pp.315-326
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    • 2010
  • This study examined the overlapping resonances in the systems involving 1 open and 2 closed channels using the phase-shifted version of multichannel quantum-defect theory (MQDT). The results showed that 21 patterns for the q reversals in the autoionization spectra are possible depending on the relative arrangements of the two simple poles and roots of the quadratic equations. Complete cases could be generated easily using the q zero planes determined using only 3 asymmetric spectral line profile indices. The transition of the spectra of the coarse interloper Rydberg series from the lines into a structured continuum by being dispersed onto the entire Rydberg series was found. The overall behavior of the time delays was found to be governed by the dense Rydberg series, which is quite different from the one of the autoionization cross sections that is governed by an interloper, indicating that different dynamics prevail for them. This is in contrast to the two channel system where both quantities behave similarly. The dynamics obtained in the presence of overlapping resonances is as follows. The absorption process is instant and dominated by a transition to the interloper line. This process is followed by rapid leakage into the dense Rydberg series, which has a longer residence time before ionization than that of the interloper state. This is because the orbiting period is proportional to $\upsilon^3$ so that an excited electron has a shorter lifetime in the interloper state belonging to a lower member of the Rydberg series.

Synthesis of Asynchronous Circuits from Deterministic Signal Transition Graph with Timing Constraints (시간 제한 조건을 가진 결정성 신호 전이 그래프로부터 비동기 회로의 합성)

  • Kim, Hee-Sook;Jung, Sung-Tae
    • Journal of KIISE:Computer Systems and Theory
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    • v.27 no.2
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    • pp.216-226
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    • 2000
  • This paper presents a new method to synthesize timed asynchronous circuits directly from the specification without generating a state graph. The synthesis procedure begins with a deterministic signal transition graph specification with timing constraints. First, a timing analysis extracts the timed concurrency and timed causality relations between any two signal transitions. Then, a hazard-free implementation under the timing constraints is synthesized by constructing a precedence graph and finding paths in the graph. The major result of this work is that the method does not suffer from the state explosion problem, achieves significant reductions in synthesis time, and generates circuits that have nearly the same area as compared to previous methods.

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A state transition based situation modeling and its application to design of SAC(Situation-Action Converter) for situation-aware control for embedded systems (임베디드 시스템에서의 상황인식 제어를 위한 상태전이 기반 상황 모델링과 이를 응용한 상황-동작 변환기 (SAC)의 설계)

  • Heo Gil;Park Joshua;Cho We-Duke;Choi Jae-Young
    • Journal of KIISE:Computer Systems and Theory
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    • v.33 no.9
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    • pp.642-649
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    • 2006
  • In order to recognize a situation from a environment which provides an intelligent service, we propose state-transition based situation modeling which is suitable for a low computing power and restricted resources like embedded systems, and we designed its application to a situation-action converter(SAC)which is consist of two parts; situation detector recognized wanted situations and action generator generated various control actions. Then, we implemented a situation manager for smart scheduler service by using a SAC which is installed to a ARM processor based embedded Linux evaluation board.

The Characteristics of PET Micro Fiber Fabrics Decomposed dy Sodium Ethylene glycol Solution (Sodium ethylene glycolate 용액에 의한 PET 극세사 직물의 분해 특성)

  • Bae, Jung-Sook;Cho, Yong-Suk
    • Journal of the Korean Home Economics Association
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    • v.36 no.8
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    • pp.95-104
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    • 1998
  • PET microfiber fabric dissociation reactions by ethylene glycol (EG) catalayzed by the corresponding EG anions were examined to provide an empirical basis for the improvement of a PET microfiber fabrics. The alkoxide ions, monosodium ethylene glycolate in ethylene glycol solution(MSEG-EG) are prepared by the reaction between NaH and the EG respectively. The dissociation reactions were carried out until the sample PET microfiber fabrics dissociate up to 80%. Temperature used ranged 100~$160^{\circ}C$. The kinetic behaviors of the dissociated PET microfiber fabrics were examined. The results are as follows : 1. In all cases, it was found that the PET-alkoxide dissociation rate constants increased exponentially with increasing temperature. The activation energies (Ea) of the reactions were 23.31kcal/mol in PET-EG system respectively. The calculated enthalpies of the activated [PET-EG] complexes from the corresponding Ea values were 22.53 ~ 22.61 kcal/mol, and the entropies were -19.03 ~ -19.24 kcal/mol/k respectively. 2. The kinetic behavior of the PET-alkoxide dissociation reactions examined was explained by the transition state theory. PET-alkoxide transition state is believed to be formed during the ester interchange mechanism between PET and MSEG-EG in the course of the PET dissociation reactions.

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Photodissocaition Dynamics of Propiolic Acid at 212 nm: The OH Production Channel

  • Shin, Myeong Suk;Lee, Ji Hye;Hwang, Hyonseok;Kwon, Chan Ho;Kim, Hong Lae
    • Bulletin of the Korean Chemical Society
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    • v.33 no.11
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    • pp.3618-3624
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    • 2012
  • Photodissociation dynamics of propiolic acid ($HC{\equiv}C-COOH$) at 212 nm in the gas phase was investigated by measuring rotationally resolved laser-induced fluorescence spectra of OH ($^2{\Pi}$) radicals exclusively produced in the ground electronic state. From the spectra, internal energies of OH and total translational energy of products were determined. The electronic transition at 212 nm responsible for OH dissociation was assigned as the ${\pi}_{C{\equiv}C}{\rightarrow}{\pi}^*{_{C=O}}$ transition by time-dependent density functional theory calculations. Potential energy surfaces of both the ground and electronically excited states were obtained employing quantum chemical calculations. It was suggested that the dissociation of OH from propiolic acid excited at 212 nm should take place along the $S_1/T_1$ potential energy surfaces after internal conversion and/or intersystem crossing from the initially populated $S_2$ state based upon the potential energy calculations and model calculations for energy partitioning of the available energy among products.

An Efficient FTL Algorithm for Flash Memory (플래시 메모리를 위한 효율적인 사상 알고리즘)

  • Chung Tae-Sun;Park Hyung-Seok
    • Journal of KIISE:Computer Systems and Theory
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    • v.32 no.9
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    • pp.483-490
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    • 2005
  • Recently, flash memory is widely used in embedded applications since it has strong points: non-volatility, fast access speed, shock resistance, and low power consumption. However, due to its hardware characteristics, it requires a software layer called FTL(flash translation layer). The main functionality of FTL is to convert logical addresses from the host to physical addresses of flash memory We present a new FTL algorithm called STAFF(State Transition Applied Fast Flash Translation Layer). Compared to the previous FTL algorithms, STAFF shows five times higher performance than basic block mapping scheme and requires less memory. We provide performance results based on our implementation of STAFF and previous FTL algorithms.

The Adsorption of the 3-methyl 5-pyrazolone on the Ge(100) Surface

  • Lee, Myeong-Jin;Lee, Han-Gil
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.189.2-189.2
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    • 2014
  • The most stable adsorption structures and energies of four tautomerized forms (keto-1, enol-1, keto-2, and enol-2) of 3-methyl 5-pyrazolone (MP) adsorbed on Ge(100) surfaces have been investigated by Density Functional Theory (DFT) calculation method. Among its four tautomerized forms, we confirmed three tautomerized forms except keto-1 form show the stable adsorption structures when they adsorbed on the Ge(100)-$2{\times}1$ surface as we calculate the respective stable adsorption structures, activation barrier, transition state energy, and reaction pathways. Moreover, among three possible adsorption structures, we acquired that enol-2 form has most stable adsorption structure with O-H dissociated N-H dissociation bonding structure.

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Determination of Reactivities by Molecular Orbital Theory (VII). SCF-IMO Studies on the Diels-Alder Reactions between Cyclopentadiene and 2-Substituted Acrylonitriles (화학반응성의 분자궤도론적 연구 (제7보). 시클로펜타디엔과 아크릴로니트릴 치환체간의 Diels-Alder 반응에 대한 SCF-IMO 연구)

  • Lee Ikchoon;Choi Eun Wha
    • Journal of the Korean Chemical Society
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    • v.19 no.4
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    • pp.218-224
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    • 1975
  • The ground state SCF IMO theory was applied to the Diels-Alder reactions of cyclopentadiene with 2-substituted acrylonitriles. The CNDO/2 MO of the separate systems, including both $\sigma$ and $\pi$ electrons, was used as starting point. The qualitative prediction of the relative reactivity was made with the calculated primary interaction energies. Here the calculated activation energies appeared to be realistic. The stereoselectivity determined by the calculated secondary interaction energies represented the endo-selectivity for all the substituents. The reason for the slightly unsymmetrical ring closure at the transition state was discussed in terms of valence inactive electron densities of the reacting atoms.

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Capital Structure and Its Determinants: Evidence from Vietnam

  • NGUYEN, Tan Gia;NGUYEN, Lan;NGUYEN, Tuan Duc
    • The Journal of Asian Finance, Economics and Business
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    • v.8 no.10
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    • pp.1-10
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    • 2021
  • This paper attempts to investigate the determinants of capital structure of Vietnamese firms and also shed light on some of the factors of the modern theory of capital structure which is relevant for explaining the capital structure in advanced countries which are also relevant in the context of Vietnam. Using panel data from more than 1000 Vietnamese listed enterprises census 2017-2020, the paper finds that leverage ratio of Vietnamese firms is significantly related to probability. The firms have high level of fixed assets which they use as collateral, resulting in higher debt ratio, which is in line with the pecking order theory. The result also confirm that highly targeted debt ratio is positively correlated with the industry characteristics (using real estate firms as a benchmark), in which firm operates. Furthermore, consistent with the trade-off hypothesis, the leverage ratio is positively affected by non - debt tax shield. The result confirms that a large number of companies are state - owned, will have an insignificant impact of firm's size (as reverse proxy for bankruptcy cost) on leverage ratio. We also find that there is no distinction between state-owned enterprises and private enterprises due to strict adherence to the rules set by the Vietnamese government. Distinct from other countries, corporate income tax has slight impact on capital structure in Vietnamese firms.