• Proceedings of the Korean Powder Metallurgy Institute Conference
• /
• 1999.04a
• /
• pp.5-5
• /
• 1999

The Principal deficiency of the existing notion about the sintering-mixtures consists in the fact that almost no attention is focused on the Phenomenon of alloy formation during sintering, its connection with dimensional changes of powder bodies, and no correct ideas on the driving force for the sintering process in the stage of establishing chemical equilibrium in a system are available as well. Another disadvantage of the classical sintering theory is an erroneous conception on the dissolution mechanism of solid in liquid. The two-particle model widely used in the literature to describe the sintering phenomenon in solid state disregards the nature of the neighbouring surrounding particles, the presence of pores between them, and the rise of so called arch effect. In this presentation, new basic scientific principles of the driving forces for the sintering process of a two-component powder body, of a diffusion mechanism of the interaction between solid and liquid phases, of stresses and deformation arising in the diffusion zone have been developed. The major driving force for sintering the mixture from components capable of forming solid solutions and intermetallic compounds is attributed to the alloy formation rather than the reduction of the free surface area until the chemical equilibrium is achieved in a system. The lecture considers a multiparticle model of the mixed powder-body and the nature of its volume changes during solid-state and liquid-phase sintering. It explains the discovered S-and V-type concentration dependencies of the change in the compact volume during solid-state sintering. It is supposed in the literature that the dissolution of solid in liquid is realised due to the removal of atoms from the surface of the solid phase into the melt and then their diffusicn transfer from the solid-liquid interface into the bulk of liquid. It has been shown in our experimental studies that the mechanism of the interaction between two components, one of them being liquid, consist in diffusion of the solvent atoms from the liquid into the solid phase until the concentration of solid solutions or an intermetallic compound in the surface layer enables them to pass into the liquid by means of melting. The lecture discusses peculimities of liquid phase formation in systems with intermediate compounds and the role of the liquid phase in bringing about the exothermic effect. At the frist stage of liquid phase sintering the diffusion of atoms from the melt into the solid causes the powder body to grow. At the second stage the diminution of particles in size as a result of their dissolution in the liquid draws their centres closer to each other and makes the compact to shrink Analytical equations were derived to describe quantitatively the porosity and volume changes of compacts as a result of alloy formation during liquid phase sinteIing. Selection criteria for an additive, its concentration and the temperature regime of sintering to control the density the structure of sintered alloys are given.

• Economic and Environmental Geology
• /
• v.53 no.4
• /
• pp.479-489
• /
• 2020

A fault is a geological structure that can be a migration path or a cap rock of hydrocarbon such as oil and gas, formed from source rock. The fault is one of the main targets of seismic exploration to find reservoirs in which hydrocarbon have accumulated. However, conventional fault detection methods using lateral discontinuity in seismic data such as semblance, coherence, variance, gradient magnitude and fault likelihood, have problem that professional interpreters have to invest lots of time and computational costs. Therefore, many researchers are conducting various studies to save computational costs and time for fault interpretation, and machine learning technologies attracted attention recently. Among various machine learning technologies, many researchers are conducting fault interpretation studies using the support vector machine, multi-layer perceptron, deep neural networks and convolutional neural networks algorithms. Especially, researchers use not only their own convolution networks but also proven networks in image processing to predict fault locations and fault information such as strike and dip. In this paper, by investigating and analyzing these studies, we found that the convolutional neural networks based on the U-Net from image processing is the most effective one for fault detection and interpretation. Further studies can expect better results from fault detection and interpretation using the convolutional neural networks along with transfer learning and data augmentation.

• Journal of the Korea institute for structural maintenance and inspection
• /
• v.15 no.2
• /
• pp.61-69
• /
• 2011

Fiber Reinforced Plastic (FRP) sheets have been widely used to retrofit and rehabilitate RC structures, while in case of retrofitting steel structures, there are no codes and researches. It stems from configuration of member and characteristics of bonding behavior. This study focused on the static behavior of steel beams reinforcement by AFRP sheets. The main objective of the experimental programme was the evaluation of the force transfer mechanism, the increment of the beam load carrying capacity and the bending stiffness. A bending test was conducted on a H-shaped steel beam, with aramid FRP sheets bonded to its flanges. The mid-span deflection and the strain from three points along AFRP sheets were recorded Test results exhibit that the increment of the load-carrying capacity with reference to a mid-span deflection level of 15 mm(1/125mm of the clear span) was equal to 9.4% and for the two layers case, an elastic stiffness increment is slightly higher than one layer case.

• Journal of the Korean Chemical Society
• /
• v.37 no.8
• /
• pp.711-716
• /
• 1993

The mechanism for electrochemical oxidation of natural alkaloid, ${\iota}$-sparteine (SP) was studied in acetonitrile solvent. The cyclic voltammogram of SP shows two irreversible anodic peaks at +0.75 V and +1.45 V vs. Ag/AgCl (0.1M AgNO$_2$ in acetonitrile) electrode. Coulometry reveals that the number of electrons involved in each oxidation peaks is in the range of 1.2∼1.3 respectively. Neutral imine radical was produced by fast deprotonation of SP radical cation formed by oxidation of one nitrogen atom in SP. Two pathways are possible for the reaction of the neutral radical: Due to the disproportionation of the radical, SP and enamine were mainly produced. Also, the 1,2-dehydrosparteinium cation was formed as minor product through the second one electron transfer oxidation of this radical. The (+)-lupanine was produced by treatment of sparteinium cation with potassium hydroxide. We have isolated and confirmed the electrolysis products using IR, GC-MS, UV-Vis, and thin-layer spectroelectrochemical method.

• The Journal of the Acoustical Society of Korea
• /
• v.14 no.2E
• /
• pp.91-97
• /
• 1995

This paper describes the implementation of a multi-channel audio codec for HETV. This codec has the features of the 3/2-stereo plus low frequency enhancement, downward compatibility with the smaller number of channels, backward compatibility with the existing 2/0-stereo system(MPEG-1 audio), and multilingual capability. The encoder of this codec consists of 6-channel analog audio input part with the sampling rate of 48 kHz, 4-channel digital audio input part and three TMS320C40 /DSPs. The encoder implements multi-channel audio compression using a human perceptual psychoacoustic model, and has the bit rate reduction to 384 kbit/s without impairment of subjective quality. The decoder consists of 6-channel analog audio output part, 4-channel digital audio output part, and two TMS320C40 DSPs for a decoding procedure. The decoder analyzes the bit stream received with bit rate of 384 kbit/s from the encoder and reproduces the multi-channel audio signals for analog and digital outputs. The multi-processing of this audio codec using multiple DSPs is ensured by high speed transfer of date between DSPs through coordinating communication port activities with DMA coprocessors. Finally, some technical considerations are suggested to realize the problem of real-time operation, which are found out through the implementation of this codec using the MPEG-2 layer II sudio coding algorithm and the use of the hardware architecture with commercial multiple DSPs.

• Journal of the Computational Structural Engineering Institute of Korea
• /
• v.30 no.2
• /
• pp.119-125
• /
• 2017

Ablative material in a rocket nozzle is exposed to high temperature combustion gas, thus undergoes complicated thermal/chemical change in terms of chemical destruction of surface and thermal decomposition of inner material. Therefore, method for conjugate analysis of thermal response inside carbon/phenolic material including rocket nozzle flow, surface chemical reaction and thermal decomposition is developed in this research. CFD is used to simulate flow field inside nozzle and conduction in the ablative material. A change in material density and a heat absorption caused by the thermal decomposition is considered in solid energy equation. And algebraic equation under boundary layer assumption is used to deduce reaction rate on the surface and resulting destruction of the surface. In order to test the developed method, small rocket nozzle is solved numerically. Although the ablation of nozzle throat is deduced to be higher than the experiment, shape change and temperature distribution inside material is well predicted. Error in temperature with experimental results in rapid heating region is found to be within 100 K.

• Membrane Journal
• /
• v.30 no.1
• /
• pp.57-65
• /
• 2020

The purpose of this study was to compare the water channel morphology and the proton conductivity by changing the number of repeating units of the polymer backbone of PEMs, and to present a criterion for selecting an appropriate polymer model for MD simulation. In the model with the shortest polymer main chain, the movement of the main chain and the sulfonic acid group was observed to be large, but no change in the water channel morphology was found. In addition, due to the nature of the proton transport ability that is most affected by the water channel morphology, the proton conductivity did not show a significant correlation with the length of the polymer backbone. These results provide important information, particularly for the preparation of ionomers for binders. In general, a low molecular weight polymer electrolyte material is used for a binder ionomer. Since the movement of the main chain/sulfonic acid group is improved, it can play a role of enclosing the catalyst layer well. However, there is no change in its proton conducting performance. In conclusion, the preparation of ionomers for binders will require molecular weight and structure design with a focus on physical properties rather than proton transfer performance.

• Journal of the Korean Electrochemical Society
• /
• v.1 no.1
• /
• pp.33-39
• /
• 1998

To AC impedance study was performed in this study on the interfacial reaction between organic electrolyte and amorphous tungsten oxides thin film, cathodically coloring oxide, prepared by e-beam evaporation method in the 1 M $LiClO_4/PC$ organic solution. The electrochemical reactions at the interface were analyzed by the transient method and the complex impedance spectroscopy. The impedance spectrums showed that the electro-chemical intercalation of lithium cations was consisted of the following three steps; the first step, the charge transfer reaction of lithium cation at the interface between amorphous tungsten oxides thin film and the organic electrolyte, the second step, the adsorption of lithium atom on the surface of amorphous tungsten oxides thin film, and then the third step, the absorption and the diffusion of lithium atom into amorphous tungsten oxides thin layer. The bleaching and the coloring characteristics of amorphous tungsten oxides thin film were explained in terms of thermodynamic and kinetic variables, the simulated $R_{ct},\;C_{dl},\;D$ and $\sigma_{Li}$ by CNLS fitting method. Especially it was found that the limiting values of electrochromic reaction were the molar ratio of lithium, y=0.167 and the electrode potential, E=2.245 V (vs. Li).

• Journal of Korean Society of Forest Science
• /
• v.88 no.1
• /
• pp.38-46
• /
• 1999

Canopy structure conductances of a Norway spruce forest in the Solling Hills(Central Germany) and Central Forest Biosphere Reserve(320km to the north-west from Moscow) were derived from LE(latent heat flux) and H(sensible heat flux) fluxes measured(by Eddy correlation technique and energy balance method) and modelled(by one dimensional non-steady-state) SVAT(soil-vegetation-atmosphere-transfer) model(SLODSVAT) using a rearranged Penman-Monteith equation("Big-leaf" approximation) during June 1996. They were compared with canopy stomatal conductances estimated by consecutive intergrating the stomatal conductance of individual needles over the whole canopy("bottom-up" approach) using SLODSVAT model. The result indicate a significant difference between the canopy surface conductances derived from measured and modelled fluxes("top-down" approach) and the stomatal conductances modelled by the SLODSVAT("bottom-up" approach). This difference was influenced by some nonphysiological factors within the forest canopy(e.g. aerodynamic and boundary layer resistances, radiation budget, evapotranspiration from the forest understorey). In general, canopy surface conductances derived from measured and modelled fluxes exceeded canopy stomatal conductance during the whole modelled period, The contribution of the understorey's evapotranspiration to the total forest evapotranspiration was small (up to 5-9% of the total LE flux) and was not depended on total radiation balance of forest canopy. Ignoring contribution of the understorey's evapotranspiration resulted in an overestimation of the canopy surface conductance for a spruce forest up to 2mm/s(about 10-15%).

• Journal of the Korean Geotechnical Society
• /
• v.21 no.8
• /
• pp.73-84
• /
• 2005

A three layered neural network model was developed using back propagation algorithm to estimate the UU undrained shear strength of Korean soft soil based on the database of actual undrained shear strengths and piezocone measurements compiled from 8 sites over the Korea. The developed model was validated by comparing model predictions with measured values about new piezocone data, which were not previously employed during development of model. Performance of the neural network model was also compared with conventional empirical methods. It was found that the number of neuron in hidden layer is different for the different combination of transfer functions of neural network models. However, all piezocone neural network models are successful in inferring a complex relationship between piezocone measurements and the undrained shear strength of Korean soft soils, which give relatively high coefficients of determination ranging from 0.69 to 0.72. Since neural network model has been generalized by self-learning from database of piezocone measurements and undrained shear strength over the various sites, the developed neural network models give more precise and generally reliable undrained shear strengths than empirical approaches which still need site specific calibration.