• 제목/요약/키워드: Trace pollutants

검색결과 69건 처리시간 0.024초

Multi Axis DOAS를 이용한 대기미량 물질 원격 측정 (Remote Sensing of Atmospheric Trace Species using Multi Axis Differential Optical Absorption Spectroscopy)

  • 이철규;김영준
    • 대한원격탐사학회지
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    • 제22권2호
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    • pp.141-151
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    • 2006
  • 태양광을 광원으로 하고 천정방향을 포함한 다양한 고도각을 이용하는 자외선/가시광선영역에서의 흡수분광학이 최근에 지상용 대기원격 측정에 개발되어오고 있다. 이를 이용하여 지표부근에 존재하는 대기 미량 물질의 공간적 분포가 유추될 수 있다. 대기질 측정기술 중 하나인 MAX-DOAS (Multi-axis Differential Optical Absorption Spectroscopy) 기술은 광원으로서 태양산란광을 이용하고, 다양한 고도각에서 태양산란광을 기록하고 분석을 통하여 대기 중 미량 물질을 측정한다. 광주과학기술원 환경모니터링 신기술 연구센터에서 개발된 MAX-DOAS 시스템은 9004년 1월, 5월, 10월에 각각 도시대기, 화산플룸, 화력발전소 플룸의 측정에 적용되었다. 각각의 경우에 $SO_2,\;NO_2,\;BrO,\;O_4$를 정량분석하기 위하여 기록된 MAX-DOAS 스펙트럼은 자외선/가시광선 영역에서의 고유 흡수스펙트럼을 이용한 DOAS 기술을 이용하여 분석 되었다. 그 결과는 Slant Column Density (SCD)로 표현되었다. 플룸 측정의 경우에서는 플룸 속에 포함된 $NO_2,\;SO_2$의 공간적 분포를 파악하기 위하여 플룸의 진행방향과 수직적인 방향에서 MAX-DOAS 스캔이 이루어졌다. 이를 통하여 얻은 단면적을 토대로 $SO_2,\;NO_2$ 농도가 계산되었다. 화산플룸에서 $SO_2$는 580ppbv, 화력발전소 플룸에서 $NO_2$는 337ppbv, $SO_2$는 227ppbv 로 계산되었다.

MTBE 가솔린기관의 배기가스 특성에 관한 연구 (Emission Characteristics for the MTBE Gasoline Engine)

  • 노병준;이삼구;김규철
    • 한국추진공학회지
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    • 제5권2호
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    • pp.32-37
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    • 2001
  • 본 논문에서는 현재 시판되고 있는 주요 정유회사의 MTBE 가솔린을 이용하여 차량 배출 배기가스를 측정하였다. 배출 가스량은 차량 동력계상에 실제차량을 탑재하여 시험차량의 배기관에서 배출된 배출가스를 포집 하였으며, 우리나라의 공인배출가스 시험방법인 CVS-75 모드를 추적 주행하여 측정 하였다. CVS-75 모드는 cold start cycle, hot stabilized cycle 및 hot start cycle로 구성되며, 본 실험에서 분석한 배출가스는 일산화탄소, 질소산화물 및 탄화수소 등이다. 실험결과 배출 가스의 양에 있어서 근소한 차이만 보이고 있음을 알 수 있었다.

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해양심층수와 지하염수의 자원특성 비교분석 (Comparative Analysis of Resources Characteristics for Deep Ocean water and Brine Groundwater)

  • 문덕수;정동호;김현주
    • 한국해양공학회:학술대회논문집
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    • 한국해양공학회 2003년도 추계학술대회 논문집
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    • pp.333-335
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    • 2003
  • Deep Ocean Water is formed within restricted area including polar sea (high latitude) by cooling of surface seawater and globally circulated in the state of insolation with surface seawater. Although not as obvious as estuaries mixing, Brine groundwater is mixture of recirculated seawater and groundwater. Seawater having high osmotic pressure infiltrate into unconfined aquifer where is connected to the sea. The ions dissolved in seawater are present in constant proportions to each other and to the total salt content of seawater. However deviation in ion proportions have been observed in some brine groundwater. Some causes of these exception to the Rule of constant proportions are due to many chemical reactions between periphery soil and groundwater. While Deep Ocean Water (DOW) have a large quantity of functional trace metals and biological affinity relative to brine groundwater, DOW have relatively small amount of harmful bacteria and artificial pollutants.

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오염저감 기법개발을 위한 유출수내 고형물질 특성 규명 (Analysis of Solids in Runoff to Prevent Solids Pollution)

  • 이영수
    • 상하수도학회지
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    • 제18권1호
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    • pp.22-28
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    • 2004
  • The fate and transport mechanism of pollutants which have affinities to particles, such as trace metals and some petroleum product based compounds, can be effectively explained by the movement of sediment. The sediment release from lands to adjacent water bodies due to rainfall events was investigated in an effort to predict the total suspended solids (TSS) concentrations in runoff. The contribution of sediment from land origin to the river TSS can be better understood by the relationship between TSS concentration and particle size in runoff. The sieve analysis was used to determine the particle size distribution and these results were incorporated into statistical models. The critical size of particles was set to $74{\mu}m$ which contributes to the river TSS concentration since fine particles (wash load) of the sediment in the runoff play the key role in constituting TSS in a water column of the river. Empirical relationships were developed to predict TSS in runoff from the percentage of the critical particle size and were proven statistically to be valid.

Optimization of Influencing Factors on Biomass Accumulation and 5-Aminolevulinic Acid (ALA) Yield in Rhodobacter sphaeroides Wastewater Treatment

  • Liu, Shuli;Li, Xiangkun;Zhang, Guangming;Zhang, Jie
    • Journal of Microbiology and Biotechnology
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    • 제25권11호
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    • pp.1920-1927
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    • 2015
  • This study aimed to optimize four factors affecting biomass accumulation and 5-aminolevulinic acid (ALA) yield together with pollutants removal in Rhodobacter sphaeroides wastewater treatment. Results showed that it was feasible to produce biomass and ALA in R. sphaeroides wastewater treatment. Microaerobic, 1,000-3,000 lux, and pH 7.0 were optimal conditions for the highest ALA yield of 4.5 ± 0.5 mg/g-biomass. Under these conditions, COD removal and biomass production rate were 93.3 ± 0.9% and 31.8 ± 0.5 mg/l/h, respectively. In addition, trace elements Fe2+, Mg2+, Ni2+, and Zn2+ further improved the ALA yield, COD removal, and biomass production rate. Specifically, the highest ALA yield (12.5 ± 0.6 mg/g-biomass) was achieved with Fe2+ addition.

황사의 대기환경영향 (Impacts of Asian Dust on Atmospheric Environment)

  • 김영성
    • 한국대기환경학회지
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    • 제27권3호
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    • pp.255-271
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    • 2011
  • ACE-Asia (Asian Pacific Regional Aerosol Characterization Experiment) in spring 2001 was a turning point to trigger international research interest on Asian dust (AD). This basically arose from the lack of research on AD, the important natural phenomenon to characterize the Northeast Asia. In contrast, health risk related to AD has been the primary concern in Korea. Although due in part to severe AD events of 2001~2002, research and mitigation measures on AD in Korea are typically based on the assumption that AD events are increasing in frequency and severity. However, contrary to the trend in Korea, the number of AD days and emission amounts of AD in China have decreased since 1980s. This paper reviews the impacts of AD on ambient air quality and variations in toxic substances during the AD event, reflecting the concern in Korea. While a great amount of dust particles flow into Korea during the AD event, a considerable amount of dust particles are locally generated as well. Since dust particles are mixed with toxic substances as they pass over polluted areas, the levels of toxic substances become lower in dust particles that do not pass over polluted areas. Broadening the research scope on AD is warranted to understand the AD as an important natural phenomenon, irrespective of its associated health risk.

안양천 바닥 퇴적물의 지구화학적 특성에 따른 하천수 오염영향 (Geochemical Characteristics of Bottom Sediments of the Anyang River and the Influence on the Stream Water Contamination)

  • 문지원
    • 자원환경지질
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    • 제33권3호
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    • pp.205-215
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    • 2000
  • The Anyang River runs through highly industrialized area and joins the lower part of the Han River. loading out large amounts of potential pollutants. Attempts were made to understand geochemical behavior of trace elements in the stream sedimens collected from the bottom of the river and the stream water. Bottom sediments, suspended solids and stream waters were collected and analysed for the chemical and mineralogical composition. Heavy metals including Cr, Zn, Ni, and Co in the sediments were enriched appeared to reflect anthropogenic input. Pb, Cu, As were also enriched between several to 10 times , compared to background levels. Although some heavy metals were derived from anthropogeic input, geochemical associations seem to implyh much of the elements are originated from natural sources as well, mainly from granitic rocks . This is also supported by the mineralogical composition of the suspended solids, which are mainly composed of quartz, feldspar and mica. Most of the elements are associated with total carbon and clay sized fractions, with high values of correlation coefficient. Most of the elements are associated with total carbon and clay sized fractions , with high values of correlation coefficient. It was noteworthy that Hg was detected between 2 and 4 ppb in the stream water.

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황토, 갯벌 및 머드의 중금속 흡착율에 관한 실험적 연구 (An Experimental Study on the Adsorption rates of Heavy Metals by Yellow Loess, Tidal Plat Sediment and Mud)

  • 이인숙;이미영;이택중;김현정;이병창;정명상;방은옥;송현실;황혜경;이중호;조영채
    • 환경위생공학
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    • 제19권2호
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    • pp.15-22
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    • 2004
  • Yellow loess, Tidal plat sediment, and mud are blown to be high in adsorption though they have great distinction according to the ratio of clay minerals content and their kinds. Thus one of the samples for this study can be obtained by drying of Yellow loess, Tidal plat sediment, and the mud which is semifinished products that are from the progress of heat treatment and making homogeneity which can be found everywhere in our county. Another sample can be prepared by reducing pollutants with the adsorbent and by homing heavy metals of their on. With the samples, noxious heavy metals such as Pb, Cd, and essential trace elements such as Cu, Fe, Mn by each concentration is tested for adsorption according to pH, the kinds of adsorbents and the amount of injection. With the help of these steps, this study shows that the adsorbents, which are green, reducing the additional pollution and low in price, can be found. It also shows that the optimal condition for removing pollutants can be found and the basic materials for treating water can be offered. The results were as follows ; Yellow loess shows the rates of adsorption by more than 50% and Tidal plat sediment and Mud show it by more than 90%. Thus Tidal plat sediment and Mud are higher than Yellow loess the rates of adsorption. The pH should be treated in natural condition because the rates of adsorption of Pb, Cd, Cu, Mn excepting Fe in mud is higher in pH 7 than in pH 3 of Yellow loess, Tidal plat sediment, and Mud. The drying adsorbents are good to use because the rates of adsorption of heavy metals has tendency to be higher in the drying method than in the burning method. It is considered that the more the mont of the injection of the adsorbent is , the higher the rates of adsorption is, and one gram is reasonable for the amount of the injection of Tidal plat sediment and mud. Yellow loess is suitable for the treatment of the water that includes low concentration of heavy metals because it has the lower rate of adsorption as the concentration of noxious heavy metals is higher. It is thought that Tidal plat sediment and Mud is proper for the treatment of the water that includes high concentration of heavy metals because the rates of adsorption has not been changed as the concentration of heavy metals increases.

시화호의 계절변화에 따른 지화학적 환경요인 특성 연구 (The Environmental Impacts of Seasonal Variation on Characteristics of Geochemical Parameters in Lake Shihwa, Korea)

  • 김태하;박용철;이효진;김동화;박준건;김성준;이미연
    • 한국환경과학회지
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    • 제13권12호
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    • pp.1089-1102
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    • 2004
  • Seasonal variation of biogeochemical characteristics was determined in Lake Shihwa from October 2002 to August 2003. When the lake was artificially constructed for the freshwater reservoir in 1988, the development of the strong haline density stratification resulted in two-layered system in water column and hypoxic/anoxic environment prevailed in the bottom layer due to oxidation of accumulated organic matters in the lake. Recently, seawater flux to the lake through the sluice has been increased to improve water quality in the lake since 2000, but seasonal stratification and hypoxic bottom layer of the lake still developed in the summer due to the nature of artificially enclosed lake system. As the lake is still receiving tremendous amount of organic matters and other pollutants from neighboring streams during the rainy summer season, limited seawater flux sluicing into the lake may not be enough for the physical and biogeochemical mass balance especially in the summer. The excess of accumulated organic matters in the bottom layer apparently exhausted dissolved oxygen and affected biogeochemical distributions and processes of organic and inorganic compounds in the stratified two-layered environment in the summer. During the summer, ammonia and dissolved organic carbon remarkably increased in the bottom layer due to the hypoxic/anoxic condition in the bottom layer. Phosphate also increased as the result of benthic flux from the bottom sediment. Meanwhile, dissolved organic carbon showed the highest value at the upstream area and decreased along the salinity gradient in the lake. In addition to the sources from the upstream, autochthonous origin of particulate organic carbon from algal bloom in the lake might be more important for sustaining aggravated water quality and development of deteriorated bottom environment in the summer. The removal of trace metals could be attributed to scavenging by strong insoluble metal-sulfide compounds in the hypoxic/anoxic bottom layer in the summer.

하수처리시설 방류수 내 잔류 향정신성 의약품의 독성평가를 위한 zebrafish의 행동성 변화 연구 (A Study on the Behavior Change of Zebrafish For Toxicity Evaluation of Residual Psychoactive Medication in Wastewater Treatment Plant Effluent)

  • 윤효직;김민재;김종락;김성표
    • 한국물환경학회지
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    • 제35권6호
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    • pp.574-579
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    • 2019
  • As interest in health issues increases, it is imperative to ensure good water quality from wastewater treatment plant effluent to preserve environmental health. In particular, currently there is a lack of water ecosystem risk assessment on pharmaceutical substances remaining in effluent. In this study, antidepressant escitalopram (ESC), antiepileptic carbamazepine (CBZ) and lead, which impact the behavior of aquatic organisms, were used to test their impact on the potential behavior of zebrafish. Zebrafish have been widely used in toxicological assessment studies due to the ease of handlinggenerically and genetically. It was possible to observe changes in the growth of organisms through monitoring the embryos' cognitive and behavior assessment. In this study, the embryo lethal dose test showed that the lethal concentration of ESC and CBZ was at 10 ppb, which is below the water quality criterion (100 ppb), increased by 32.5 % and 40 %, respectively. In the cognitive test, it was found that the cognitive ability function decreased by 22 % and 17% for ESC(500 ppb) and CBZ(1,000 ppb) respectively relative to control. Based on these results, it is necessary to initiate efforts to remove these trace pollutants from sewage treatment facilities to protect the health of aquatic organisms.