• Title/Summary/Keyword: Trace pollutants

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Remote Sensing of Atmospheric Trace Species using Multi Axis Differential Optical Absorption Spectroscopy (Multi Axis DOAS를 이용한 대기미량 물질 원격 측정)

  • Lee Chul-Kyu;Kim Young-Joon
    • Korean Journal of Remote Sensing
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    • v.22 no.2
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    • pp.141-151
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    • 2006
  • UV-visible absorption measurement techniques using several horizone viewing directions in addition to the traditional zenith-sky pointing have been recently developed in ground-based remote sensing of atmospheric constituents. The spatial distribution of various trace gases close to the instrument can be derived by combing several viewing directions. Multi-axis differential optical absorption spectroscopy (MAX-DOAS) technique, one of the remote sensing techniques for air quality measurements, uses the scattered sunlight as a light source and measures it at various elevation angles (corresponding to the viewing directions) by sequential scanning with a stepper motor. A MAX-DOAS system developed by GIST/ADEMRC has been applied to measuring trace gases in urban air and plumes of the volcano and fossil fuel power plant in January, May, and October 2004, respectively. MAX-DOAS spectra were analyzed to identify and quantify $SO_2,\;NO_2,\;BrO,\;and\;O_4$ (based on Slant Column Densities, SCD) in the urban air, volcanic plume, and fossil fuel power plant utilizing theirs specific structured absorption features in the UV-visible region. Vertical scan through the multiple elevation angles was performed at different directions perpendicular to the plume dispersion to retrieve cross-sectional distribution of $SO_2\;or\;NO_2$ in the plumes of the volcano and fossil fuel power plant. Based on the estimated cross sections of the plumes the mixing ratios were estimated to 580 $SO_2$ ppbv in the volcanic Plume, and 337 $NO_2\;and\;227\;SO_2$ ppbv in the plume of the fossil fuel power plant, respectively.

Emission Characteristics for the MTBE Gasoline Engine (MTBE 가솔린기관의 배기가스 특성에 관한 연구)

  • 노병준;이삼구;김규철
    • Journal of the Korean Society of Propulsion Engineers
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    • v.5 no.2
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    • pp.32-37
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    • 2001
  • This article is to provide reasonably accurate vehicle emission estimates for the four sampled fuels which are commercially available across the nation. Emission quantities are obtained by testing a vehicle on a chassis dynamometer and capturing a sample of the emissions from the tailpipe in vehicle. The vehicle is driven following a particular pattern of idle, acceleration, cruise, and deceleration. Shown here is the trace of the test cycle known as the CVS-75 Mode which is used to certify the emission performance standards. The mode of CVS-75 consists of a cold start cycle, a hot stabilized cycle, and a hot start cycle. Emissions for the pollutants are measured in vehicle testing. These are carbon monoxide (CO), oxides of nitrogen (NOx), and total hydrocarbon (THC). The test results summarized in this report indicate that the differences for the amount of emission are quantitatively minimal.

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Comparative Analysis of Resources Characteristics for Deep Ocean water and Brine Groundwater (해양심층수와 지하염수의 자원특성 비교분석)

  • Mun, Deok-Su;Jeong, Dong-Ho;Kim, Hyeon-Ju
    • Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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    • 2003.10a
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    • pp.333-335
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    • 2003
  • Deep Ocean Water is formed within restricted area including polar sea (high latitude) by cooling of surface seawater and globally circulated in the state of insolation with surface seawater. Although not as obvious as estuaries mixing, Brine groundwater is mixture of recirculated seawater and groundwater. Seawater having high osmotic pressure infiltrate into unconfined aquifer where is connected to the sea. The ions dissolved in seawater are present in constant proportions to each other and to the total salt content of seawater. However deviation in ion proportions have been observed in some brine groundwater. Some causes of these exception to the Rule of constant proportions are due to many chemical reactions between periphery soil and groundwater. While Deep Ocean Water (DOW) have a large quantity of functional trace metals and biological affinity relative to brine groundwater, DOW have relatively small amount of harmful bacteria and artificial pollutants.

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Analysis of Solids in Runoff to Prevent Solids Pollution (오염저감 기법개발을 위한 유출수내 고형물질 특성 규명)

  • Lee, Young-Soo
    • Journal of Korean Society of Water and Wastewater
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    • v.18 no.1
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    • pp.22-28
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    • 2004
  • The fate and transport mechanism of pollutants which have affinities to particles, such as trace metals and some petroleum product based compounds, can be effectively explained by the movement of sediment. The sediment release from lands to adjacent water bodies due to rainfall events was investigated in an effort to predict the total suspended solids (TSS) concentrations in runoff. The contribution of sediment from land origin to the river TSS can be better understood by the relationship between TSS concentration and particle size in runoff. The sieve analysis was used to determine the particle size distribution and these results were incorporated into statistical models. The critical size of particles was set to $74{\mu}m$ which contributes to the river TSS concentration since fine particles (wash load) of the sediment in the runoff play the key role in constituting TSS in a water column of the river. Empirical relationships were developed to predict TSS in runoff from the percentage of the critical particle size and were proven statistically to be valid.

Optimization of Influencing Factors on Biomass Accumulation and 5-Aminolevulinic Acid (ALA) Yield in Rhodobacter sphaeroides Wastewater Treatment

  • Liu, Shuli;Li, Xiangkun;Zhang, Guangming;Zhang, Jie
    • Journal of Microbiology and Biotechnology
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    • v.25 no.11
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    • pp.1920-1927
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    • 2015
  • This study aimed to optimize four factors affecting biomass accumulation and 5-aminolevulinic acid (ALA) yield together with pollutants removal in Rhodobacter sphaeroides wastewater treatment. Results showed that it was feasible to produce biomass and ALA in R. sphaeroides wastewater treatment. Microaerobic, 1,000-3,000 lux, and pH 7.0 were optimal conditions for the highest ALA yield of 4.5 ± 0.5 mg/g-biomass. Under these conditions, COD removal and biomass production rate were 93.3 ± 0.9% and 31.8 ± 0.5 mg/l/h, respectively. In addition, trace elements Fe2+, Mg2+, Ni2+, and Zn2+ further improved the ALA yield, COD removal, and biomass production rate. Specifically, the highest ALA yield (12.5 ± 0.6 mg/g-biomass) was achieved with Fe2+ addition.

Impacts of Asian Dust on Atmospheric Environment (황사의 대기환경영향)

  • Ghim, Young-Sung
    • Journal of Korean Society for Atmospheric Environment
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    • v.27 no.3
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    • pp.255-271
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    • 2011
  • ACE-Asia (Asian Pacific Regional Aerosol Characterization Experiment) in spring 2001 was a turning point to trigger international research interest on Asian dust (AD). This basically arose from the lack of research on AD, the important natural phenomenon to characterize the Northeast Asia. In contrast, health risk related to AD has been the primary concern in Korea. Although due in part to severe AD events of 2001~2002, research and mitigation measures on AD in Korea are typically based on the assumption that AD events are increasing in frequency and severity. However, contrary to the trend in Korea, the number of AD days and emission amounts of AD in China have decreased since 1980s. This paper reviews the impacts of AD on ambient air quality and variations in toxic substances during the AD event, reflecting the concern in Korea. While a great amount of dust particles flow into Korea during the AD event, a considerable amount of dust particles are locally generated as well. Since dust particles are mixed with toxic substances as they pass over polluted areas, the levels of toxic substances become lower in dust particles that do not pass over polluted areas. Broadening the research scope on AD is warranted to understand the AD as an important natural phenomenon, irrespective of its associated health risk.

Geochemical Characteristics of Bottom Sediments of the Anyang River and the Influence on the Stream Water Contamination (안양천 바닥 퇴적물의 지구화학적 특성에 따른 하천수 오염영향)

  • 문지원
    • Economic and Environmental Geology
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    • v.33 no.3
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    • pp.205-215
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    • 2000
  • The Anyang River runs through highly industrialized area and joins the lower part of the Han River. loading out large amounts of potential pollutants. Attempts were made to understand geochemical behavior of trace elements in the stream sedimens collected from the bottom of the river and the stream water. Bottom sediments, suspended solids and stream waters were collected and analysed for the chemical and mineralogical composition. Heavy metals including Cr, Zn, Ni, and Co in the sediments were enriched appeared to reflect anthropogenic input. Pb, Cu, As were also enriched between several to 10 times , compared to background levels. Although some heavy metals were derived from anthropogeic input, geochemical associations seem to implyh much of the elements are originated from natural sources as well, mainly from granitic rocks . This is also supported by the mineralogical composition of the suspended solids, which are mainly composed of quartz, feldspar and mica. Most of the elements are associated with total carbon and clay sized fractions, with high values of correlation coefficient. Most of the elements are associated with total carbon and clay sized fractions , with high values of correlation coefficient. It was noteworthy that Hg was detected between 2 and 4 ppb in the stream water.

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An Experimental Study on the Adsorption rates of Heavy Metals by Yellow Loess, Tidal Plat Sediment and Mud (황토, 갯벌 및 머드의 중금속 흡착율에 관한 실험적 연구)

  • Lee I.S.;Lee M.Y.;Lee T.J.;Kim H.J.;Lee B.C.;Jeong M.S.;Bang E.O.;Song H.S.;Hwang H.K.;Lee J.H.;Cho Y.C.
    • Journal of environmental and Sanitary engineering
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    • v.19 no.2
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    • pp.15-22
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    • 2004
  • Yellow loess, Tidal plat sediment, and mud are blown to be high in adsorption though they have great distinction according to the ratio of clay minerals content and their kinds. Thus one of the samples for this study can be obtained by drying of Yellow loess, Tidal plat sediment, and the mud which is semifinished products that are from the progress of heat treatment and making homogeneity which can be found everywhere in our county. Another sample can be prepared by reducing pollutants with the adsorbent and by homing heavy metals of their on. With the samples, noxious heavy metals such as Pb, Cd, and essential trace elements such as Cu, Fe, Mn by each concentration is tested for adsorption according to pH, the kinds of adsorbents and the amount of injection. With the help of these steps, this study shows that the adsorbents, which are green, reducing the additional pollution and low in price, can be found. It also shows that the optimal condition for removing pollutants can be found and the basic materials for treating water can be offered. The results were as follows ; Yellow loess shows the rates of adsorption by more than 50% and Tidal plat sediment and Mud show it by more than 90%. Thus Tidal plat sediment and Mud are higher than Yellow loess the rates of adsorption. The pH should be treated in natural condition because the rates of adsorption of Pb, Cd, Cu, Mn excepting Fe in mud is higher in pH 7 than in pH 3 of Yellow loess, Tidal plat sediment, and Mud. The drying adsorbents are good to use because the rates of adsorption of heavy metals has tendency to be higher in the drying method than in the burning method. It is considered that the more the mont of the injection of the adsorbent is , the higher the rates of adsorption is, and one gram is reasonable for the amount of the injection of Tidal plat sediment and mud. Yellow loess is suitable for the treatment of the water that includes low concentration of heavy metals because it has the lower rate of adsorption as the concentration of noxious heavy metals is higher. It is thought that Tidal plat sediment and Mud is proper for the treatment of the water that includes high concentration of heavy metals because the rates of adsorption has not been changed as the concentration of heavy metals increases.

The Environmental Impacts of Seasonal Variation on Characteristics of Geochemical Parameters in Lake Shihwa, Korea (시화호의 계절변화에 따른 지화학적 환경요인 특성 연구)

  • Kim Tae-Ha;Park Yong-Chul;Lee Hyo-Jin;Kim Dong-Hwa;Park Jun-Kun;Kim Sung-Jun;Lee Mi-Yeon
    • Journal of Environmental Science International
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    • v.13 no.12
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    • pp.1089-1102
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    • 2004
  • Seasonal variation of biogeochemical characteristics was determined in Lake Shihwa from October 2002 to August 2003. When the lake was artificially constructed for the freshwater reservoir in 1988, the development of the strong haline density stratification resulted in two-layered system in water column and hypoxic/anoxic environment prevailed in the bottom layer due to oxidation of accumulated organic matters in the lake. Recently, seawater flux to the lake through the sluice has been increased to improve water quality in the lake since 2000, but seasonal stratification and hypoxic bottom layer of the lake still developed in the summer due to the nature of artificially enclosed lake system. As the lake is still receiving tremendous amount of organic matters and other pollutants from neighboring streams during the rainy summer season, limited seawater flux sluicing into the lake may not be enough for the physical and biogeochemical mass balance especially in the summer. The excess of accumulated organic matters in the bottom layer apparently exhausted dissolved oxygen and affected biogeochemical distributions and processes of organic and inorganic compounds in the stratified two-layered environment in the summer. During the summer, ammonia and dissolved organic carbon remarkably increased in the bottom layer due to the hypoxic/anoxic condition in the bottom layer. Phosphate also increased as the result of benthic flux from the bottom sediment. Meanwhile, dissolved organic carbon showed the highest value at the upstream area and decreased along the salinity gradient in the lake. In addition to the sources from the upstream, autochthonous origin of particulate organic carbon from algal bloom in the lake might be more important for sustaining aggravated water quality and development of deteriorated bottom environment in the summer. The removal of trace metals could be attributed to scavenging by strong insoluble metal-sulfide compounds in the hypoxic/anoxic bottom layer in the summer.

A Study on the Behavior Change of Zebrafish For Toxicity Evaluation of Residual Psychoactive Medication in Wastewater Treatment Plant Effluent (하수처리시설 방류수 내 잔류 향정신성 의약품의 독성평가를 위한 zebrafish의 행동성 변화 연구)

  • Yoon, Hyojik;Kim, Minjae;Kim, Jongrack;Kim, Sungpyo
    • Journal of Korean Society on Water Environment
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    • v.35 no.6
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    • pp.574-579
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    • 2019
  • As interest in health issues increases, it is imperative to ensure good water quality from wastewater treatment plant effluent to preserve environmental health. In particular, currently there is a lack of water ecosystem risk assessment on pharmaceutical substances remaining in effluent. In this study, antidepressant escitalopram (ESC), antiepileptic carbamazepine (CBZ) and lead, which impact the behavior of aquatic organisms, were used to test their impact on the potential behavior of zebrafish. Zebrafish have been widely used in toxicological assessment studies due to the ease of handlinggenerically and genetically. It was possible to observe changes in the growth of organisms through monitoring the embryos' cognitive and behavior assessment. In this study, the embryo lethal dose test showed that the lethal concentration of ESC and CBZ was at 10 ppb, which is below the water quality criterion (100 ppb), increased by 32.5 % and 40 %, respectively. In the cognitive test, it was found that the cognitive ability function decreased by 22 % and 17% for ESC(500 ppb) and CBZ(1,000 ppb) respectively relative to control. Based on these results, it is necessary to initiate efforts to remove these trace pollutants from sewage treatment facilities to protect the health of aquatic organisms.