• Title/Summary/Keyword: Trace element

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Groundwater Flow Analysis using Numerical model in Small Basin (소규모유역의 수치모헝을 이응한 지하수 유동해석)

  • 최윤영
    • Journal of Environmental Science International
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    • v.12 no.6
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    • pp.615-626
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    • 2003
  • The applied model for this study area is WINFLOW using mite element method, It is thought that the simulation result by WINFLOW model under the steady flow state reflects well the ground water distribution within the reliability level which shows the error range of 1.1% to 8.0% from the comparison between the computed values and the observed, and analyzed that the constant head distribution is shown along the east-west direction and gentle and stable head gradient along the north-south direction. Ground water of the study area shows stable movement from the south to the stream area, and the particle trace for each location shows relatively linear shape from the upstream to the pumping location while the radius of influence according to the pumping amount shows a significant difference at the down stream area from the pumping location. The simultaneous pumping from P and P1 shows more complicated appearance, not the increase of the radius of influence than pumping from a single well P or P1, and it is analyzed that the particle path takes nearly linear form. It is known that the flow direction of the ground water and the velocity of the flow affect on the magnitude of the radius of influence of the wells from the fact that the more decreasing pattern of the ground water head is observed at the side of the well and the down stream area than the upstream area when the ground water moves from south to north regarding the radius of influence according to the pumping amount. Satisfactory results in analyses of ground water movement are obtained through the significant reduction of the physical uncertainties in the flow system as well as the relatively convenient model application using WINFLOW model which is proposed in this study.

Dynamic Change of Stresses in Subsoil under Concrete Slab Track Subjected to Increasing Train Speeds (열차 증속에 따른 콘크리트 궤도 노반의 동적 응력 변화)

  • Lee, Tae-Hee;Choi, Chan-Yong;Nsabimana, Ernest;Jung, Young-Hoon
    • Journal of the Korean Geotechnical Society
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    • v.29 no.10
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    • pp.57-66
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    • 2013
  • Societal interest on a faster transportation demands an increase of the train speed exceeding current operation speed of 350 km/h. To trace the pattern of variations in displacements and subsoil stresses in the concrete slab track system, finite element simulations were conducted. For a simple track-vehicle modeling, a mass-point system representing the moving train load was developed. Dynamic responses with various train speeds from 100 to 700 km/h were investigated. As train speeds increase the displacement at rail and subsoil increases nonlinearly, whereas significant dynamic amplification at the critical velocity has not been found. At low train speed, the velocity of elastic wave carrying elastic energy is faster than the train speed. At high train speed exceeding 400 km/h, however, the train speed is approximately identical to the elastic wave velocity. Nonlinearity in the stress history in subsoil is amplified with increasing train speeds, which may cause significant plastic strains in path-dependent subsoil materials.

Mineralogical and Geochemical Studies of Uranium Deposits of the Okchon Group in Southwestern District off Taejon, Korea (대전서남지대(大田西南地帶)에 있어서의 옥천대(沃川帶) 우라늄광상(鑛床)에 대(對)한 광물학적(鑛物學的) 및 지화학적(地化學的) 연구(硏究))

  • Yun, Suckew
    • Economic and Environmental Geology
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    • v.17 no.4
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    • pp.289-298
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    • 1984
  • Uraniferous black slates of the Okchon sequence occur in Koesan (northeast) through Miwon-Boun (middle) to the southwest off Taejon (southwest) within the Okchon fold belt. The Uraniferous balck slates in the southwest off Taejon are particularly well developed in Chubu (northeast) and Moksso-ri (middle) areas whereas they are less developed in Jinsan (southwest) area. The uraniferous beds range from less than a meter to 40 meters in thickness and range from less than 0.02% $U_3O_8$ (cut-off-grade) to 0.05% $U_3O_8$ in the southwestern district off Taejon. Electron microprobe analysis of uranium-minerals found in graphitic slate samples enables to estimate their major compositions semi-quantitatively so that uraninite, ferro-uranophane and chlopinite are tentatively identified. Uranium-minerals are closely associated with carbon and metal sulfides. Correlation analysis of trace element concentrations revealed that U and F.C., and U and Mo are lineary correlative respectively and their correlation coefficients are positively high whereas those of U and V, U and Mn, and U and Zr are negatively low, implying that uranium mineralization has been closely related with concentrations of carbon and molybdenum. Stable isotope analyses of pyrite sulfur range widely from +11.5% to -23.3% in ${\delta}^{34}S$ values whereas those of graphite carbon fall within a narrow range between -23.3% and -28.9% in ${\delta}^{13}C$ values. The wide range of ${\delta}^{34}S$ values suggests that the sulfur could be of meteoric origin rather than of igneous source. The narrow range of ${\delta}^{13}C$ values, which are close to those of coal, indicates that the graphite is organic carbon in origin. Therefore, it is concluded that the uranium mineralization in the Okchon sequence took place primarily in sedimentary environment rich in organic matter and sulfide ion, both of which served as the reducing agents to convert soluble uranyl complex to insoluble uranium dioxide.

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A Comparative Study on the Determination of the Selenium in Biological Samples using 75Se and 77mSe Nuclides (75Se과 77mSe 핵종을 이용한 생물시료 중의 셀렌 분석에 대한 비교 연구)

  • Moon, Jong-Hwa;Kang, Sang-Hoon;Kim, Sun-Ha;Chung, Yong-Sam;Kim, Young-Jin
    • Analytical Science and Technology
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    • v.18 no.1
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    • pp.23-26
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    • 2005
  • Se is well known as an anti-oxidant trace element and many customers are interested in an analysis and contents of Se in the various foodstuff samples. This study was aimed at establishig and comparing an analytical method for the determination of the Se in biological samples by neutron activation analysis using two nuclides, $^{75}Se$ and $^{77m}Se$. Keeping this objective, three NIST biological standard reference materials were chosen and the concentrations of the Se were determined under the prefixed analytical conditions such as the irradiation, decay and measurement time. The measured values by both analytical methods were evaluated with certified values. In addition, the detection limits and measurement uncertainty for the analytical results using $^{75}Se$ and $^{77m}Se$ were compared with each other.

Growth Characteristics of Creeping bentgrass Cultivars (크리핑 벤트그래스 품종의 생육 특성)

  • 이혜원;정대영;심상렬
    • Asian Journal of Turfgrass Science
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    • v.17 no.2_3
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    • pp.87-97
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    • 2003
  • The growth characteristics of creeping bentgrass seeded in the seaside landfill golf course are as follows. 1. As a result of analysis on the chemical characteristics of soil mixture used for turfgrass ground in this experiment, soil pH was 7.9, which is somewhat higher than the creeping bentgrass reference value of pH 5.5∼6.5; T-N(%) was 0.02, which is proper for the reference value, and trace element too lacked. 2. The cultivar with the fastest water infiltration was Seaside II recorded as 226.2cm/sec, while that with the slowest water infiltration was Pennlinks recorded as 141.1 cm/hr which was too faster than the USGA water infiltration reference value of 15∼30cm/hr. For the surface hardness of turfgrass ground with different cultivars, no statistically significant variation was found between the Penncross grass and the Pennlinks recorded as 18.6mm and 19.1 mm, respectively. The soil penetration was the highest in Pennlinks recorded as 7.6kg/$\textrm{cm}^2$ and lowest in Penn A-1 as 6.1kg/$\textrm{cm}^2$. 3. As a result of evaluation on visual quality at the early stage of growth, Penncross showed the most excellent visual quality compared to the others. However, Penn A-1 showed the most excellent visual quality at a late stage of growth around Sep. 17, 2003, and it was also excellent in the evaluation of visual color. Seaside II showed higher density around the root and the longest root length and was highly resistant to salt compared to others, but the initial sprouting rate was not satisfied, and the visual quality in the summer season was inferior to others. 4. As a result of measurement of the traffic injury, Penncross showed the most tolerant to the traffic stress and Pennlinks showed the most susceptible.

Specification of Chemical Properties of Feed Coal and Bottom Ash Collected at a Coal-fired Power Plant

  • Ma, Chang-Jin;Kim, Jong-Ho;Kim, Ki-Hyun;Tohno, Susumu;Kasahara, Mikio
    • Asian Journal of Atmospheric Environment
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    • v.4 no.2
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    • pp.80-88
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    • 2010
  • In order to offer a better understanding of air pollution of China as well as East Asia we attempted to characterize the chemical properties of the raw coal materials mined in China and their combusted bottom ashes generated from coal fired power plant. To this end, we measured the chemical characteristics of individual bottom ashes and feed coal fragments collected at a coal fired power generator which was operated with the raw coal dug at a coal mine in China. The chemical properties of these two sample types were determined by a synchrotron radiation X-ray fluorescence (SR-XRF) microprobe method. Through an application of such technique, it was possible to draw the 2D elemental maps in and/or on raw coal fragments and fired bottom ashes. The pulverized fine pieces of feed coal mainly consisted of mineral components such as Fe, Ca, Ti, Ca, and Si, while Fe was detected as overwhelming majority. The elemental mass of combusted bottom ash shows strong enrichment of many elements that exist naturally in coal. There were significant variations in chemical properties of ash-to-ash and fragment-to-fragment. Although we were not able to clearly distinguish As and Pb peaks because of the folding in their X-ray energies, these two elements can be used as tracers of coal fire origin.

Effects of atopic dermatitis induced materials on the expression of cytokine genes in human monocytes and mast cells (인간의 단핵구와 비만세포에서 다양한 아토피 유발물질이 사이토카인 유전자의 발현에 미치는 영향)

  • Park, Koung-Suk;Kim, Kyung-Jun
    • The Journal of Korean Medicine Ophthalmology and Otolaryngology and Dermatology
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    • v.23 no.2
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    • pp.41-56
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    • 2010
  • Objectives : On an experimental basis, the effects of atopic dermatitis induced materials on the expression of cytokine genes in human monocytes (THP-1, U937) and mast cells were studied. This study was carried out to be considered a fundamental knowledge in the research on the good of oriental medicine. Methods : After culturing THP-1, U937, and HMC-1, with the three different concentrations of LPS ($1\;{\mu}g/ml$), DPE ($10\;{\mu}g/ml$), and DNCB ($1\;{\mu}g/ml$), atopic dermatitis induced materials were treated in the culture medium. To investigate cytokine genes expression patterns, with lysis buffer and separation reagent, total RNA was extracted from THP-1, U937, and HMC-1 at intervals of 0, 12, 24, and 48 hours. Both cytokine mRNA expression patterns by atopic dermatitis induced materials and change of cytokine genes expression patterns in relation to atopy by selenium were analyzed with RT-PCR. Also IL-4 and INF-$\gamma$, which were secreted in the HMC-1, were analyzed using ELISA method. Results : 1. After treating THP-1 and U937 with LPS, DPE, and DNCB, there was no significant change in cytokine genes themselves, but various cytokines (IL-4, IL-6, IL-8, IL-13, IFN-$\gamma$, IFN-a, MCP-1, B2-MG) were expressed. 2. In the case of HMC-1, the expressions of IL-6 and IL-8 were significantly increased in the analysis of mRNA expression by dust mite allergens in DPE. 3. As a result of ELISA method, it is certain that IL-4 and IFN-$\gamma$ protein were secreted in the HMC-1 by DPE. 4. Selenium, an essential trace element, decreased the IL-10 and IL-13 expression in the HMC-1 by DPE. Conclusion : The results suggest that it is necessary to choose proper atopic dermatitis induced materials and suitable cultured cells in establishment of in vitro model of atopic dermatitis.

Dispersion and Enrichment of Potentially Toxic Elements in Chubu Area Covered with Black Shales and Slates in Korea (추부지역 흑색셰일 및 점판암 분포지역에서의 잠재적 독성원소들의 분산과 부화)

  • Kim, Jong Shin;Chon, Hyo Taek
    • Economic and Environmental Geology
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    • v.30 no.2
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    • pp.89-103
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    • 1997
  • The purpose of this research is to investigate the enrichment and distribution patterns of naturally occurring potentially toxic elements in soils derived from black shales and slates. Soil samples were collected from the Chubu area covered with uranium-enriched black shales and slates of the Changri Formation of the Okchon Super Group, and analysed for multiple-elements using INAA, ICP-AES and AAS. Soil pH and loss-an-ignition were also measured. Trace element contents in black shale and slate of the Chubu area are relatively lower than those in black shales, and higher than those in black slates reported elsewhere (Chon, Jung, 1991; Chon et al., 1996). Soil pH values range from 3.5 to 6.5, and loss-an-ignition values are in the range from 3 to 10%. Potentially toxic elements including As, Ba, Cr, Cu, Mo and U are highly enriched in residual soils with maximum content of $540{\mu}g/g$, $35,000{\mu}g/g$, $280{\mu}g/g$, $300{\mu}g/g$, $240{\mu}g/g$ and $860{\mu}g/g$, respectively. Significant concentrations of those elements were found in soils taken from the Tojangkol, the Chubu tunnel and the Meokti areas. Soils derived from black shales and slates, calcareous and phyllitic rocks, and intrusions were discriminated in terms of As, Ba, Co, Cr, Cu, Mo, Sc and U contents. Enrichment index was calculated using the concentrations of As, Ba, Cr and Mo, and enrichment index map shows very similar trend with U distribution in soils.

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Study of an innovative two-stage control system: Chevron knee bracing & shear panel in series connection

  • Vosooq, Amir Koorosh;Zahrai, Seyed Mehdi
    • Structural Engineering and Mechanics
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    • v.47 no.6
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    • pp.881-898
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    • 2013
  • This paper describes analytical investigation into a new dual function system including a couple of shear links which are connected in series using chevron bracing capable to correlate its performance with magnitude of earthquakes. In this proposed system, called Chevron Knee-Vertical Link Beam braced system (CK-VLB), the inherent hysteretic damping of vertical link beam placed above chevron bracing is exclusively utilized to dissipate the energy of moderate earthquakes through web plastic shear distortion while the rest of the structural elements are in elastic range. Under strong earthquakes, plastic deformation of VLB will be halted via restraining it by Stopper Device (SD) and further imposed displacement subsequently causes yielding of the knee elements located at the bottom of chevron bracing to significantly increase the energy dissipation capacity level. In this paper first by studying the knee yielding mode, a suitable shape and angle for diagonal-knee bracing is proposed. Then finite elements models are developed. Monotonic and cyclic analyses have been conducted to compare dissipation capacities on three individual models of passive systems (CK-VLB, knee braced system and SPS system) by General-purpose finite element program ABAQUS in which a bilinear kinematic hardening model is incorporated to trace the material nonlinearity. Also quasi-static cyclic loading based on the guidelines presented in ATC-24 has been imposed to different models of CK-VLB with changing of vertical link beam section in order to find prime effectiveness on structural frames. Results show that CK-VLB system exhibits stable behavior and is capable of dissipating a significant amount of energy in two separate levels of lateral forces due to different probable earthquakes.

Studies on the Production of Gibberellic acid (지베렐린 생산에 관한 연구)

  • 이영선;손형진;김익환;민태익
    • Microbiology and Biotechnology Letters
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    • v.11 no.3
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    • pp.217-222
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    • 1983
  • By the treatment of Gibberella fujkuroi I-892 with mutagen such as UV light and N-methyl-N'-nitro-N-nitrosoguanidine, a mutant G. fujkuroi G-471 was selected as the highest producer of gibberellic acid among 800 mutant strains. It showed 30% increase of production yield compared with that of the parent strain. At optimum medium composition (saccharose 1.0%, ammonium tartarate 50mM, malt extract 1.0% KH$_2$PO$_4$ 0.5%, MgSO$_4$0.5%, FeSO$_4$0.0002%, trace element sol.0.002% (v/v), the yield of submerged culture increased by 30% after 7 days culture at 24$^{\circ}C$ (253mg/$\ell$). In submerged culture, the initial pH showed much effects on the increase of gibberellic acid production. The highest yield of the production was attained with pH adjustment to 4.0 at the initial stage of fermention.

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