• Title/Summary/Keyword: Trace analysis

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Study on Solvent Extraction Using Salen(NEt2)2 as a Chelating Agent for Determination of Trace Cu(II), Mn(II), and Zn(II) in Water Samples

  • In, Gyo;Kim, Young-Sang;Choi, Jong-Moon
    • Bulletin of the Korean Chemical Society
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    • v.29 no.5
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    • pp.969-973
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    • 2008
  • Solvent extraction using a Schiff-base, salen$(NEt_2)_2$, as a chelating agent has been conducted on several water samples to study the determination of trace Cu(II), Mn(II) and Zn(II). Experimental conditions for the formation and extraction of metal complexes were optimized with an aqueous solution similar in composition to the samples. The matrix difference between the sample and standard solutions was approximately matched, and the pH of each sample solution was adjusted to 9.5 with $NaHCO_3/NaOH$ buffer. The concentration of salen$(NEt_2)_2$ was $7.3\;{\times}\;10^{-3}$ mol/L, and the complexes were extracted into MIBK solvent followed by the measurement of AAS absorbance. The potential interference of concomitant ions was investigated, but no interference from alkaline and alkali earth ions was shown in this procedure. The given procedure is precise, as judged from the relative standard deviation of less than 5% for five measured data. The recovery of 93-103% shows that this method is quantitative for such trace metal analysis.

A Study on Power Dissipation of Embedded Microprocessors (임베디드 마이크로 프로세서의 전력 소비에 대한 연구)

  • Lee, Jongbok
    • The Journal of the Institute of Internet, Broadcasting and Communication
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    • v.18 no.4
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    • pp.169-175
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    • 2018
  • Recently, power dissipation issue is very significant not only in high-end modern processors but also in embedded systems and mobile devices. Based on the power dissipation, hardware and software designers can correctly find the power/performance tradeoffs. Most power analysis tools calculate power dissipation when chip layout or floor planning are finished. In this paper, a trace-driven simulator that can interact with power analysis tool for an embedded microprocessor has been developed. Using MiBench embedded benchmarks as input, the trace-driven simulation has been performed to estimate the average power dissipation which is faster than the conventional tools.

Separation of Seismic Signals using a Polarization Filter based on the Complex Trace Analysis Method (복소트레이스 분극필터를 이용한 다성분 탄성파자료 신호분리)

  • Kim, Ki-Young;Lee, So-Young
    • 한국지구물리탐사학회:학술대회논문집
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    • 2005.05a
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    • pp.233-236
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    • 2005
  • Polarization filtering based on the multicomponent complex trace analysis method is performed to reject Rayleigh waves and to enhance S waves. To test the polarization filter, synthetic seismic data were constructed for a simple two-layer model based on the finite difference method. Rayleigh waves with elliptic motion are eliminated effectively and P and S waves with linear motions are well separated each other.

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Determination of Impurities in Uranium Dioxide by Neutron Activation Analysis (중성자방사화분석법에 의한 이산화우라늄중의 불순물정량)

  • Nak Bae Kim;Hae-Ill Bak;Chul Lee
    • Nuclear Engineering and Technology
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    • v.13 no.4
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    • pp.237-244
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    • 1981
  • The preliminary concentration of trace elements in uranium dioxide using an anion exchange resin is presented for neutron activation analysis. The uranyl solution in sulfuric acid is adjusted to the acidity of about pH 2.7 and loaded on a column of the anion exchange resin. An appropriate volume of eluates obtained from the column shows good recoveries of trace elements. By combining this preconcentration with a radiochemical separation scheme, which was developed for the determinations of impurities in aluminum, it is possible to determine 21 trace elements in reactor grade uranium dioxide.

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TRACE V5 CODE APPLICATION DVI LINE BREAK LOCA USING ATLAS FACILITY

  • Veronese, Fabio;Kozlowsk, Tomasz
    • Nuclear Engineering and Technology
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    • v.44 no.7
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    • pp.719-726
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    • 2012
  • The object of this work is the validation and assessment of the TRACE v5.0 code using the scaled test ATLAS1 facility in the context of a DVI2 line break. In particular, the experiment selected models the 50%, 6-inch break of a DVI line. The same experiment was also adopted as a reference test in the ISP-503. The ISP-50 was proposed to, and accepted by, the OECD/NEA/CSNI due to its technical importance in the development of a best-estimate of safety analysis methodology for DVI line break accidents. In particular, the behavior of the two-phase flow in the upper annulus downcomer was expected to be complicated. What resulted was the need for relevant models to be implemented into safety analysis codes, in order to predict these thermal hydraulic phenomena correctly.

Separation of Seismic Signals using a Polarization Filter based on the Complex Trace Analysis Method (복소트레이스 분극필터를 이용한 다성분 탄성파자료 신호분리)

  • Kim, Ki-Young;Lee, So-Young
    • Journal of the Korean Geophysical Society
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    • v.8 no.1
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    • pp.35-38
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    • 2005
  • Polarization filtering based on the multicomponent complex trace analysis method is performed to reject Rayleigh waves and to enhance S waves. To test the polarization filter, synthetic seismic data were constructed for a simple two-layer model based on the finite difference method. Rayleigh waves with elliptic motion are eliminated effectively and P and S waves with linear motions are well separated each other.

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A Study on the Present Levels of Mercury and other Trace Elements in Fresh-water Fish by Neutron Activation Analysis

  • Kim, Nak-Bae;Lee, Chul;Bak, Hae-Ill
    • Nuclear Engineering and Technology
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    • v.8 no.1
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    • pp.41-47
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    • 1976
  • A nondestructive, instrumental neutron activation analysis using a Ge(Li) detector is applied to investigate the present levels of mercury and other trace elements in some fresh-water fish. The results show large variations of mercury content which are indicative of important local sources and indicate the inter-dependence relations between two of some trace elements. Analytical results for mercury in antracites are also given with the concern for their combustion as one of major causes of the mercury pollution.

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Data intercomparison and determination of toxic and trace elements in Algae using Instrumental Neutron Activation Analysis (중성자방사화분석에 의한 Algae중의 독성미량원소의 정량 및 실험실간 비교검증)

  • Chung, Yong-Sam;Moon, Jong-Hwa;Park, Kwang-Won;Lee, KiI-Yong;Yoon, Yoon-Yeol
    • Analytical Science and Technology
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    • v.12 no.4
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    • pp.346-353
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    • 1999
  • For the non-destructive multi-elemental analysis of environmental and biological materials, instrumental neutron activation analysis (INAA) was applied for the determination of toxic and trace elements in a set of three Algae samples provided by the International Atomic Energy Agency (IAEA). The analytical quality control was evaluated by comparing the analytical results of two standard reference materials of the National Institute of Standards and Technology (NIST); Oyster Tissue (SRM 1566a) and Citrus Leaves (SRM 1572). According to given analytical procedure, the concentration of 15-25 elements including spiked elements such as As, Cd, Cr and Hg in Algae samples were determined. To identify and validate these results, a data intercomparison program using more than 35 analytical methods in 150 laboratories was carried out and the estimated statistical data are summarized. Result of INAA is favorable, therefore, it is illustrated that can be applied for routine analysis of essential and toxic elements in algae samples as well as analytical quality assurance.

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Monte Calro Analysis of Cancer Risk from Airborne Trace Metals (대기중 미량금속의 발암 위해도에 대한 몬테 카를로 분석)

  • 장미숙;이진홍
    • Journal of Korean Society for Atmospheric Environment
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    • v.18 no.6
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    • pp.465-474
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    • 2002
  • In order to reflect variability due to exposure factors as well as to assess uncertainty associated with cancer risk posed by airborne trace metals, a Monte Calro analysis has been made in this study. Input parameters for Monte Carlo analysis were developed or adjusted using body weight, lifetime, and exposure frequency of Koreans. Ambient distributions of toxic metals were founded to be lognormal distributions for most of them using goodness-of-fit tests. Thus, the 95% UCL and 95% LCL of carcinogenic metals were estimated by H-statistic method for lognormal distribution, respectively. The results of Monte Carlo analysis of 95% UCL showed that the 95th percentile risks for men and women were 1.2 and 1.1 times higher than an acceptable risk of 10$^{-5}$ , respectively. The probabilities which those risks exceed the acceptable risk were estimated to be 8% and 6%, respectively, while to be 95% and 94%, respectively on the basis of the minimum acceptable risk of 10$^{-6}$ , respectively. Approximately 90% of total cancer risk came from human carcinogens such as arsenic and hexavalent chromium. Therefore, it is necessary to properly manage both arsenic and hexavalent chromium emissions in the study area.

Analysis of Ash and Trace Metals in Korean Native Bee Honey

  • Kim, Seok-Chang;Lee, Jong-Tae;Park, Chae-Kyu;Shim, Sang-Kwon;Han, Sang-Bae;Kwak, Yi-Seong;Whang, Mi-Sun;Won, Jun-Yeon
    • Journal of Applied Biological Chemistry
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    • v.49 no.4
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    • pp.154-156
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    • 2006
  • Trace metals in honey have an influence on the taste of honey along with pollens. Western bee honeys, which are mostly collected from acacia, have less than 0.1% of ash. Savor of Korean native-bee honey is thought to be due to the difference of the contents of trace metals. Korean native-bee honeys collected from Jirisan District, which is the greatest producing area of native-bee honey in Korea, showed high contents of ash. Korean native-bee honeys from the districts other than Jirisan District also showed similar results($0.44{\sim}0.83%$ of ash) to those from Jirisan District. Potassium was found to be the principal factor of high content of ash with over 85% of trace metals in ash.