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A Study on Fire Characteristics of Solid Combustible Materials Based on Real Scale Fire Test (실규모 실험에 의한 고체가연물의 화재특성 연구)

  • Kim, Sung-Chan
    • Fire Science and Engineering
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    • v.25 no.5
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    • pp.62-68
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    • 2011
  • A series of fire tests involving realistic solid combustible materials was conducted to quantify the heat release rate and investigate the fire growth characteristics during the initial fire growth stage. For these tests, single/double wood cribs, urethane cushion having polypropylene covers and wood crib on nylon carpet with urethane carpet padding were used as a fuel source. The fire growth coefficient of the solid combustible materials was quantified and the fire growth characteristics were compared with the $t^2$ fire scenario. The mean effective heat of combustion was evaluated by the total mass loss of fuel and total energy release concept and examined the effect of the ventilation and fire condition. The present study provides the practical information on the fire growth characteristics of solid combustible material to design to a set of fire scenarios for the fire risk analysis.

Characterization of Poly(vinyl phosphate-b-styrene) by Solid-State $^{31}P$ NMR and Titration

  • Li, Guang-Hua;Kim, Sang-Hun;Cho, Chang-Gi;Park, Tae-Joon;Kim, Yong-Ae
    • Macromolecular Research
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    • v.14 no.5
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    • pp.504-509
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    • 2006
  • Poly(vinyl phosphate-b-styrene) (PVPP-b-PS) block copolymers were synthesized successfully from poly(vinyl alcohol-b-styrene) (PVA-b-PS) by reaction with phosphorus oxychloride and subsequent hydrolysis. The obtained block copolymers were slightly crosslinked, and were characterized by various analytical techniques. The total phosphorus content and the ratio of the differently bound phosphorus were obtained by both solid-state $^{31}P$ NMR and pH titration, but the results differed slightly. Characterization by energy dispersion X-ray analysis (EDS) or Rutherford back scattering (RBS), on the other hand, determined the total phosphorus contents, but the results were quite different from those by solid-state $^{31}P$ NMR.

Manufacturing Characteristics of Solid-State Fermentation Distilled Spirits Using Rice Nuruk (Fermented Starter) and Sorghum (쌀누룩과 수수를 사용한 고체발효 증류주의 제조 특성)

  • Shin, J.Y.;Jeong, D.S.;Kang, C.S.;Choi, H.S.
    • Journal of Practical Agriculture & Fisheries Research
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    • v.23 no.1
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    • pp.39-48
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    • 2021
  • In this study, characteristics of solid-state fermentation distilled spirits with nuruk (fermentation starter) and sorghum were investigated. The starch digestion activity was highest in black koji (A. usamii) at 359.15 U/g dry base, white koji (A. luchuensis) at 306.98 and yellow koji (A. oryzae) at 15.31 was followed. The pH of the solid-state fermented mash in yellow, white and black koji showed 5.09, 4.46 and 4.50 respectively with significant differences (p<0.001). The total acid content of white and black koji was 0.73% as citric acid. The alcohol content of mash prepared with yellow, white and black koji was 4.34, 4.24, 3.89% respectively. The contents of reducing sugar showed 3.28, 3.23 and 2.64%. Total sugar were 14.88, 17.84 and 17.60% respectively. The alcohol content of each distillate ranged from 44.3 to 39.9%, and the furfural content in yellow koji was 1.25 times lower than the others.

Optimization of Carbon Sources to Improve Antioxidant Activity in Solid State Fermentation of Persimmon peel Using Lactic Acid Bacteria

  • Hwang, Joo Hwan;Kim, Eun Joong;Lee, Sang Moo
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.32 no.4
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    • pp.361-368
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    • 2012
  • The present study was conducted to develop persimmon peel, a by-product of dried persimmon manufacturing, as a feed additive via lactic acid bacteria fermentation. Pediococcus pentosaceus, Lactobacillus plantarum, and three strains of Leuconostoc mesenteroides were used as a starter culture in the solid state fermentation of persimmon peel, and antioxidant activity and total polyphenol content were assessed. Leuconostoc mesenteroides KCTC 3100 showed high antioxidant activity (p<0.05), whereas Pediococcus pentosaceus showed high total polyphenol content (p<0.05). These two strains were thus selected as starter culture strains. Glucose, sucrose and molasses were used as variables for optimization and a total 15 experimental runs were produced according to Box-Behnken design. Regarding significant effects of variables, molasses showed linear and square effects on antioxidant activity of persimmon peel fermentation (p<0.05). In conclusion, optimum concentrations of glucose, sucrose, and molasses were determined to be 4.2, 3.9 and 5.3 g/L, respectively, using a response surface model. Antioxidant activity was also improved 2.5 fold after optimization.

Evaluate of high solid manure characteristics and theoretical methane potential in domestic (국내 고상가축분뇨 특성 및 이론적 메탄 잠재성에 대한 평가)

  • Choi, Yongjun;Lee, Sangrak
    • Journal of Animal Environmental Science
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    • v.22 no.1
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    • pp.35-44
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    • 2016
  • This study was conducted to establish a database of high solid manure(HSM) in domestic. Theoretical methane potential and HSM characteristics was evaluated using breef and dairy manure (n=156). Total solids and Volatile solids of HSM increased depending on time flow, the results showed $20.4{\pm}3.2$ and $17.4{\pm}2.8%$. respectively. C/N ratio of breef HSM was higher than dairy HSM C/N ratio. In theoretical methane potential, the result of breef and dairy HSM was showed $505.2{\pm}25.3$ and $493.5{\pm}20.2$, respectively. Nitrogen content of total HSM increased depending on time flow, the result of breef and dairy nitrogen content was showed $1.9{\pm}0.3$ and $2.8{\pm}0.2$, respectively. Carbon content of total HSM showed approximately 10% reduction. The optimal time of bed replacement was indicated between 29 amd 31 days based on the optimal C/N ratio. Therefore, this study was considered that it has high utilization for livestock manure recycling and basis of relevant research.

The Experiments for the Enhancement of Regression Rate of Hybrid Rocket Fuel

  • Shin Kyung-Hoon;Lee Changjin;Yu Yung H.
    • Journal of Mechanical Science and Technology
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    • v.19 no.10
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    • pp.1939-1949
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    • 2005
  • Many studies have been conducted to increase regression rate of solid fuel in hybrid rocket. One of them resorts to swirl flow since it can extend the residence time of oxidizer in the fuel grain. Also, metal wires may lead to increase the regression rate of solid fuel as shown in solid propellants. In this study, a series of experiments was designed to investigate the enhancement of regression rate of solid fuel by embedded metal wires and by fuel port grain. And fuel port was designed with a helical configuration to attempt to induce swirl flow. PMMA with gaseous oxygen is the solid fuel used for investigation. Test results showed that embedded metal wires turned out to be ineffective method because only $3-4\%$ increases in regression rate were observed. However, fuel port grain configuration yields higher burning performance of up to $50\%$ increase in regression rate. Also pitch number as well as total impulse was found to be a design variable.

Stability Evaluation of One-Dimensional Flow in Solid Rocket Motors Based on Computational Fluid Dynamics

  • Kato, Takashi;Hanzawa, Masahisa;Morita, Takakazu;Shimada, Tbru
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2004.03a
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    • pp.565-572
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    • 2004
  • Numerical stability analysis of one-dimensional axial flow in solid rocket motors is performed based on the Euler equation coupled with an unsteady combustion equation of solid propellant. In order to check the numerical scheme, behavior of a standing wave in a closed tube is examined. A standing wave in solid rocket motor decays or grows depending on the total effect of propellant combustion, nozzle flow, and so on. The stability boundary of the fundamental mode standing wave is determined by changing one of the combustion parameters. In addition growth rates of the wave are calculated numerically in relatively low Mach number flow region for the motors with different port and nozzle throat diameters. The results obtained here agree well with the approximate solution. The same scheme is applied to a motor with shorter length and L*-instability is observed.

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Characterization of household solid waste and current status of municipal waste management in Rishikesh, Uttarakhand

  • Rawat, Suman;Daverey, Achlesh
    • Environmental Engineering Research
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    • v.23 no.3
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    • pp.323-329
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    • 2018
  • The municipal solid waste (MSW) management system in one of the Class II Indian cities i.e. Rishikesh was studied and analysed to identify the key issues in solid waste management in the city. A total of 329 solid waste samples from 47 households were collected to characterize the household solid waste (HSW). The average (HSW) generation rate was 0.26 kg/c/d and it was composed of organic waste (57.3%), plastics (14%), paper (10.9%), and glass and ceramic (1.3%) and other materials (16.5%). There was an inverse relationship between household waste generation rate and family size (p < 0.05). The MSW management system practiced in Rishikesh is unsound. There is no waste segregation at source, no provisions of composting and no recycling by formal sector. The collection and transportation of waste is inadequate and inappropriate. Collected waste is dumped in open dumping site without scientific management. Following are some recommendations for developing a sustainable solid waste management system in Rishikesh city: (1) sensitize people for segregation at source; (2) promote reduction, reuse and recycling of wastes; (3) promote community based composting; (4) provision for 100% door to door collection and; (5) formalize the informal sectors such as rag pickers and recycling industries.

A Study on the solid waste of Buk Han Mt National Park (북한산 국립공원의 고형 폐기물에 관한 연구)

  • 도갑수;장일영;김광진
    • Journal of the Korean Professional Engineers Association
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    • v.19 no.1
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    • pp.12-24
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    • 1986
  • The number of visiters to Bukhan Mt. national park, generation quantity of solid waste and collection system were researched to consider a counterplan for the pollution control of the national park and study for developing the effective treatment of solid waste was tried through the proximate analysis of each component containing. Results obtained in this study were summerized as follows; The great part of visitors go on an excursion to the Bukhan Mt. national park during July and August and also, the solid waste was generated nearly a half of the total amount at the same period. The major collection facilities in the national park were waste basket and incineration box. But the incineration box was too large in volume and very far in distance, and its collection period was irregular, so it was cause to the congestion of solid waste and bad smell and dirty. Therefore, to complete collection of solid waste, we must set up the waste basket which able to find within 40~50m from the origination place of solid waste and induce the visitors to throw the solid waste. It was obtained as moisture content: 48.5 wt%, volatile solid: 28.4wt%, fixed solid: 23.1 wt%, lower heating value: 1,320kca1/kg from experimental analysis of solid waste. According to this analysis, the incineration operation is possible, but the generation quantity of solid waste was too small to construct incineration plant for heat recovery. It was found that it is suitable for the aerobic composting by mixing with the night soil which generate in the national park after the recovery of resources such as metals, glasses and plastics.

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Influence of Ga Content on the Ionic Conductivity of Li1+XGaXTi2-X(PO4)3 Solid-State Electrolyte Synthesized by the Sol-Gel Method

  • Seong-Jin Cho;Jeong-Hwan Song
    • Korean Journal of Materials Research
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    • v.34 no.4
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    • pp.185-193
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    • 2024
  • In this study, NASICON-type Li1+XGaXTi2-X(PO4)3 (x = 0.1, 0.3 and 0.4) solid-state electrolytes for all-solid-state batteries were synthesized through the sol-gel method. In addition, the influence on the ion conductivity of solid-state electrolytes when partially substituted for Ti4+ (0.61Å) site to Ga3+ (0.62Å) of trivalent cations was investigated. The obtained precursor was heat treated at 450 ℃, and a single crystalline phase of Li1+XGaXTi2-X(PO4)3 systems was obtained at a calcination temperature above 650 ℃. Additionally, the calcinated powders were pelletized and sintered at temperatures from 800 ℃ to 1,000 ℃ at 100 ℃ intervals. The synthesized powder and sintered bodies of Li1+XGaXTi2-X(PO4)3 were characterized using TG-DTA, XRD, XPS and FE-SEM. The ionic conduction properties as solid-state electrolytes were investigated by AC impedance. As a result, Li1+XGaXTi2-X(PO4)3 was successfully produced in all cases. However, a GaPO4 impurity was formed due to the high sintering temperatures and high Ga content. The crystallinity of Li1+XGaXTi2-X(PO4)3 increased with the sintering temperature as evidenced by FE-SEM observations, which demonstrated that the edges of the larger cube-shaped grains become sharper with increases in the sintering temperature. In samples with high sintering temperatures at 1,000 ℃ and high Ga content above 0.3, coarsening of grains occurred. This resulted in the formation of many grain boundaries, leading to low sinterability. These two factors, the impurity and grain boundary, have an enormous impact on the properties of Li1+XGaXTi2-X(PO4)3. The Li1.3Ga0.3Ti1.7(PO4)3 pellet sintered at 900 ℃ was denser than those sintered at other conditions, showing the highest total ion conductivity of 7.66 × 10-5 S/cm at room temperature. The total activation energy of Li-ion transport for the Li1.3Ga0.3Ti1.7(PO4)3 solid-state electrolyte was estimated to be as low as 0.36 eV. Although the Li1+XGaXTi2-X(PO4)3 sintered at 1,000 ℃ had a relatively high apparent density, it had less total ionic conductivity due to an increase in the grain-boundary resistance with coarse grains.