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Characterization of Poly(vinyl phosphate-b-styrene) by Solid-State $^{31}P$ NMR and Titration  

Li, Guang-Hua (Center for Advanced Functional Polymers, Department of Fiber & Polymer Engineering, Hanyang University)
Kim, Sang-Hun (Center for Advanced Functional Polymers, Department of Fiber & Polymer Engineering, Hanyang University)
Cho, Chang-Gi (Center for Advanced Functional Polymers, Department of Fiber & Polymer Engineering, Hanyang University)
Park, Tae-Joon (Department of Chemistry, Hankuk University of Foreign Studies)
Kim, Yong-Ae (Department of Chemistry, Hankuk University of Foreign Studies)
Publication Information
Macromolecular Research / v.14, no.5, 2006 , pp. 504-509 More about this Journal
Abstract
Poly(vinyl phosphate-b-styrene) (PVPP-b-PS) block copolymers were synthesized successfully from poly(vinyl alcohol-b-styrene) (PVA-b-PS) by reaction with phosphorus oxychloride and subsequent hydrolysis. The obtained block copolymers were slightly crosslinked, and were characterized by various analytical techniques. The total phosphorus content and the ratio of the differently bound phosphorus were obtained by both solid-state $^{31}P$ NMR and pH titration, but the results differed slightly. Characterization by energy dispersion X-ray analysis (EDS) or Rutherford back scattering (RBS), on the other hand, determined the total phosphorus contents, but the results were quite different from those by solid-state $^{31}P$ NMR.
Keywords
poly(vinyl alcohol-b-styrene); poly(vinyl phosphate-b-styrene); $^{31}P$ solid-state NMR; Rutherford back scattering;
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1 D. S. Kim, H. B. Park, C. H. Lee, Y. M. Lee, G. Y. Moon, S. Y. Nam, H. S. Hwang, T. I. Yun, and J. W. Rhim, Macromol. Res., 13, 314 (2005)   DOI
2 G. H. Li and C. G. Cho, Macromol. Res., 10, 339 (2002)   DOI
3 G. H. Li and C. G. Cho, Colloid & Polymer Science, 283, 946 (2005)   DOI   ScienceOn
4 E. D. Becker, High Resolution NMR. Theory and Chemical Applications, 2nd Ed., Academic Press, New York, 1980
5 E. R. Andrew, Prog. Nucl. Magn. Reson. Spec., 8, 1 (1972)   DOI   ScienceOn
6 A. Ide-Ektessabi, T. Yamaguchi, and Y. Tanaka, Nuclear Instruments and Methods in Physics Research B, 241, 685 (2005)   DOI   ScienceOn
7 J. L. Acosta, J. L. Garcia, A. Linares, and M. J. Casanova, Polym. Int., 49, 1534 (2000)   DOI   ScienceOn
8 B. S. Pivovar, Y. Wang, and E. L. Cussler, J. Membr. Sci., 154, 155 (1999)   DOI   ScienceOn
9 L. Xiao, H. Zhang, E. Scanlon, L. S. Ramanathan, E.-W. Choe, D. Rogers, T. Apple, and B. C. Benicewicz, Chem. Mater., 17, 5328 (2005)   DOI   ScienceOn
10 I. Gitsov and J. M. J. Frechet, J. Am. Chem. Soc., 118, 3785 (1996)   DOI   ScienceOn
11 J. W. Rhim, S. W. Lee, and Y. K. Kim, J. Appl. Polym. Sci., 85, 1867 (2002)   DOI   ScienceOn
12 D. Batt-Coutrot, D. M. Haddleton, A. P. Jarvis, and R. L. Kelly, Eur. Polym. J., 39, 2243 (2003)   DOI   ScienceOn
13 B. Smitha, S. Sridhar, and A. A. Khan, Macromolecules, 37, 2233 (2004)   DOI   ScienceOn
14 M. Mehring, A. Pines, W. K. Rhim, and J. S. Waugh, J. Chem. Phys., 54, 3239 (1971)   DOI
15 J. A. Pople, H. B. Schneider, and H. Bernstein, High-Resolution NMR Spectroscopy, McGraw-Hill, New York, 1959
16 G. C. Daul, J. D. Reid, and R. M. Reinhardt, Ind. Eng. Chem., 46, 1042 (1954)   DOI
17 G. H. Li, C. H. Lee, Y. M. Lee, and C. G. Cho, Solid State Ionics, 177, 1083 (2006)   DOI   ScienceOn
18 Q. Zhang, E. E. Remsen, and K. Wooley, J. Am. Chem. Soc., 122, 3642 (2000)   DOI   ScienceOn
19 J. Zou, Y. Zhao, and W. Shi, J. Membr. Sci., 245, 35 (2004)   DOI