• 제목/요약/키워드: Total porosity

검색결과 282건 처리시간 0.024초

순환골재를 재활용한 폴리머 복합재료의 물성 (Physical Properties of Polymer Composite Recycling Recycled Aggregate)

  • 황의환;전종기
    • 공업화학
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    • 제20권1호
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    • pp.67-74
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    • 2009
  • 오늘날 대규모 건설사업에 따른 골재의 고갈과 환경보호 측면에서 폐콘크리트 순환골재의 재활용이 절실히 요구되고있다. 폐콘크리트 순환골재를 재활용한 폴리머 복합재료를 개발하기 위하여 순환골재의 치환율을 5단계로 변화시키고(0, 25, 50, 75, 100%) 또 폴리머-시멘트비도 5단계로 변화시켜(0, 5, 10, 15, 20%) 총 25종류의 공시체를 제조하였다. 공시체의 제 성능을 조사하기 위하여 공시체의 압축 및 휨강도, 흡수시험, 내열수성시험, 총세공량 및 공극률에 대하여 조사하였다. 시험결과, 폴리머 복합재료의 물성은 폴리머 시멘트비의 증가에 따라 현저히 증가되었으나 폐콘크리트 순환골재의 치환율 증가에 따라서는 크게 저하되었다.

Electromagnetic Interference Shielding Properties of CO2 Activated Carbon Black Filled Polymer Coating Materials

  • Hu, Quanli;Kim, Myung-Soo
    • Carbon letters
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    • 제9권4호
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    • pp.298-302
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    • 2008
  • Carbon blacks could be used as the filler for the electromagnetic interference (EMI) shielding. The poly vinyl alcohol (PVA) and polyvinylidene fluoride (PVDF) were used as the matrix for the carbon black fillers. Porous carbon blacks were prepared by $CO_2$ activation. The activation was performed by treating the carbon blacks in $CO_2$ to different degrees of burnoff. During the activation, the enlargement of pore diameters, and development of microporous and mesoporous structures were introduced in the carbon blacks, resulting in an increase of extremely large specific surface areas. The porosity of carbon blacks was an increasing function of the degree of burn-off. The surface area increased from $80\;m^2/g$ to $1142\;m^2/g$ and the total pore volume increased from $0.14073\;cc{\cdot}g^{-1}$ to $0.9343\;cc{\cdot}g^{-1}$. Also, the C=O functional group characterized by aldehydes, ketones, carboxylic acids and esters was enhanced during the activation process. The EMI shielding effectiveness (SE) of raw N330 carbon blacks filled with PVA was about 1 dB and those of the activated carbon blacks increased to the values between 6 and 9 dB. The EMI SE of raw N330 carbon blacks filled with PVDF was about 7 dB and the EMI SE increased to the range from 11 to 15 dB by the activation.

$V_2O_5$를 dopant로 한 $TiO_2$의 감습(感濕)에 미치는 $M_2CO_3$(M=Li, K)의 영향(影響) (Effect of $M_2CO_3$(M=Li, K) Addition on the Humidity Sensitivity of $V_2O_5$-doped $TiO_2$)

  • 강이국;송창열;신용덕
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1995년도 추계학술대회 논문집 학회본부
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    • pp.427-429
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    • 1995
  • In this paper, the effect of alkaline oxides on the humidity sensitivity of $V_2O_5$(2mol%)-doped $TiO_2$(98mol%) was investigated as functions of $Li_2CO_3$, $K_2CO_3$, additives (x= 0.0 mol%, 1mol%, 2mol%, 5mol%, 10mol%). 1. The porosity and total intrusion volume of sample containing 1, 2, 5mol% $K_2O$ was increased, and then those of 10mol% $K_2O$ was reduced again. 2. The humidity sensitivity of samples containing 1, 2, 5, 10mol% $K_2O$ were good generally. Especially the sample containing 5mol% $K_2O$ were the better. 3. the stability of the humidity sensitivity of samples containing $K_2O$ at low and high temperatures is very good.

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Effect of using recycled coarse aggregate and recycled asphalt pavement on the properties of pervious concrete

  • Shatarat, Nasim K.;Katkhuda, Hasan N.;Hyari, Khaled H.;Asi, Ibrahim
    • Structural Engineering and Mechanics
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    • 제67권3호
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    • pp.283-290
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    • 2018
  • This paper presents the results of a study that investigated the influence of using recycled coarse aggregate (RCA) and recycled asphalt pavement (RAP) on the properties of pervious concrete (PC). The natural aggregate (NA) was replaced by RCA and RAP in the PC with replacement levels of 0%, 20%, 40%, 60% and 80% by the total weight of NA, respectively. In addition to incorporating RAP and RCA in the same mixes with replacement levels of: (1) 20% RAP and 80% RCA; (2) 60% RAP and 40% RCA; and (3) 80% RAP and 20% RCA. Water permeability, thermal conductivity, density, porosity, void content, and compressive, splitting tensile and flexural strengths were studied in this paper. The results showed that using RCA, RAP, and (RAP-RCA) enhanced the properties of PC in general and improved the mechanical properties significantly in particular. The optimum mix was reported to be the 60% RAP and 40% RCA. Accordingly, the RAP has the potential to be used in PC in order to reduce the negative impact of RAP on the human health and environment.

Buckling analysis of sandwich beam reinforced by GPLs using various shear deformation theories

  • Hanifehlou, Sona;Mohammadimehr, Mehdi
    • Computers and Concrete
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    • 제25권5호
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    • pp.427-432
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    • 2020
  • In this research, the buckling analysis of sandwich beam with composite reinforced by graphene platelets (GPLs) in two face sheets is investigated. Three type various porosity patterns including uniform, symmetric and asymmetric are considered through the thickness direction of the core. Also, the top and bottom face sheets layers are considered composite reinforced by GPLs/CNTs based on Halpin-Tsai micromechanics model and extended mixture rule, respectively. Based on various shear deformation theories such as Euler-Bernoulli, Timoshenko and Reddy beam theories, the governing equations of equilibrium using minimum total potential energy are obtained. It is seen that the critical buckling load decreases with an increase in the porous coefficient, because the stiffness of sandwich beam reduces. Also, it is shown that the critical buckling load for asymmetric distribution is lower than the other cases. It can see that the effect of graphene platelets on the critical buckling load is higher than carbon nanotubes. Moreover, it is seen that the difference between carbon nanotubes and graphene platelets for Reddy and Euler-Bernoulli beam theories is most and least, respectively.

물과 공기 다공을 갖는 다공성 매질의 주파수 및 다공율 변화에 따른 음향특성 (Frequency- and Porosity-dependent Acoustic Characteristics of Porous Medium with Water- and Air-filled Pores)

  • 이강일;노희설;윤석왕
    • 한국음향학회:학술대회논문집
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    • 한국음향학회 2001년도 추계학술발표대회 논문집 제20권 2호
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    • pp.209-212
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    • 2001
  • 수중에서 물과 공기 다공을 갖는 다공성 매질의 주파수 및 다공율 변화에 따른 음향특성을 고찰하였다. 다공성 매질로서 원통형 다공을 인위적으로 균일하게 배열한 판형 루사이트 (Lucite)를 사용하였다. 수중에서 음파를 다공성 매질의 원통형 다공의 축 방향과 평행하게 입사하였을 때, 빠른 파 (fast wave)는 다공 내의 매질에 영향을 받지 않으나, 느린 파 (slow wave) 및 원통형 다공을 전파하는 비평면 고차 정상 모드 파 (nonplanar higher normal mode wave)는 다공 내의 매질에 크게 영향을 받는다. 3MHz부터 4MHz까지의 주파수 영역에서 전체 파 (total wave), 빠른 파 및 느린 파의 음속 및 음압투과계수를 주파수 및 물과 공기 다공율 변화에 따라 측정하였다. 비강체 다공성 매질에서의 음파 전파특성에 대한 MBA (modified Biot-Attenborough) 모델의 이론 결과와 실험결과를 비교, 분석하였다.

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덕산온천 지역의 수리적 성질 (Hydraulic Properties of Duksan Hot-spring Area)

  • 함세영;조병욱;성익환
    • 지질공학
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    • 제9권2호
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    • pp.101-118
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    • 1999
  • 본 연구는 덕산온천내에 수행된 28개 양수시험자료를 종합하여 덕산온천의 수리적 특성 및 매개변수를 파악하였다. 프락탈 모델, 누수성 프락탈 모델 그리고 정상류의 이중공극 프락탈 모델을 이용한 양수시험분석 결과, 대체로 온천의 중심부에서는 1.9 또는 2.0의 유동차원을 보이며, 주변부에서는 1.5∼l.7의 유동차원을 보인다. 2.0차원의 경우에, 투수량계수와 대수층 손실에 의한 산출계수의 상관성이 총 수위강하를 이용한 비양수량의 상관성보다 훨씬 높게 나타난다. 그러나, 1.9차원의 경우에는 일반화 투수량계수와 산출계수간의 상관성이 일반화 투수량계수와 비양수량간의 상관성과 비슷하게 나타나며 상관계수도 높게 나타난다.

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Distribution of Silver Particles in Silver-containing Activated Carbon Fibers

  • Ryu, S.K.;Eom, S.Y.;Cho, T.H.;Edie, D.D.
    • Carbon letters
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    • 제4권4호
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    • pp.168-174
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    • 2003
  • Silver nitrate ($AgNO_3$) powder was mixed into a reformed pitch precursor. Then, the silver-containing pitch was melt spun to form round and "C" shape fibers. A wire mesh was inserted prior to the nozzle to improve the spinnability of the silvercontaining precursor pitch. Silver particles in the carbon fibers (CFs) were detected by XRD and TEM. These tests showed that silver particles were uniformly distributed and the total amount of silver remained constant during stabilization and carbonization. Next, the silver-containing CFs were activated by steam diluted in nitrogen gas. Silver particles accelerated the activation rate, but the specific surface areas of the silver-containing ACFs were similar to those of non-silver containing ACFs at the same burn-off levels. The specific surface area of the C-shaped activated carbon fibers was larger than that of the round activated carbon fibers. The likely reason is that the surface area of a C-shaped CF is about two times larger than that of a round CF when equivalent cross-sectional areas are compared. A small amount of silver particles in the periphery of the CFs was removed during the activation, but the remainder of silver was stayed within the ACFs.

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플라즈마 용사법을 이용한 원통형 고체산화물 연료전지의 요소피막 제조 (Fabrication of the Functional Coatings of a Tubular Solid Oxide Fuel by Plasma Spray Processes.)

  • 주원태;홍상희
    • 한국표면공학회지
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    • 제30권5호
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    • pp.333-346
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    • 1997
  • Plasma spray processes for functional coatings of tubular SOFC ( Soild oxide Fuel Cell).consisting of air electrode, oxide electrolyte, an fuel electrode, are optimized by fully saturated fractional factorial testing. Material and electric characteristics of each coating are analtsed by the implementation of SEM and optical microscope for evaluating microstructure and porosity, X-ray diffraction method for investigating compositional change between raw powder and sprayed coating, and Van der Pauw method for measuring electrical conductivity. LSM ($La_{0.65}Sr_{0.35}MnO_3$air electrode and Ni-YSL fuel electrode coatings have porosities of around 23~30% sufficient for effective fuel and oxidant gas supply to electrochemical reaction interfaces and electrical conductivities of around 90 S/cm and 1000 S/cm, respectively, enough for acting as current collecting electrodes. YSZ($ZrO_2-8mol%Y_2O_3$) electrolyte film has a high ionic conductivities of 0.05~0.07 S/cm at $1000^{\circ}C$ in air atmosphere, but appears to be somewhat too porous to reduce the thickness. for enhancing the cell efficiency. A unit tubular SOFC has beem fabricated by the optimized plasma spray processes for each functional coating and the cell. Its electrochemical chracteristics are investigated by measuring voltage-current and power density with variation of operationg temperature, radio of fuel to air gas flowrates, and total gas flowrate of reactants.

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Effect of the Mg Ion Containing Oxide Films on the Biocompatibility of Plasma Electrolytic Oxidized Ti-6Al-4V

  • Lee, Kang;Choe, Han-Cheol
    • 한국표면공학회지
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    • 제49권2호
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    • pp.135-140
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    • 2016
  • In this study, we prepared magnesium ion containing oxide films formed on the Ti-6Al-4V using plasma electrolytic oxidation (PEO) treatment. Ti-6Al-4V surface was treated using PEO in Mg containing electrolytes at 270V for 5 min. The phase, composition and morphology of the Mg ion containing oxide films were evaluated with X-ray diffraction (XRD), Attenuated total reflectance Fourier transform infrared (ATR-FTIR) and filed-emission scanning electron microscopy (FE-SEM) with energy dispersive X-ray spectrometer (EDS). The biocompatibility of Mg ion containing oxide films was evaluated by immersing in simulated body fluid (SBF). According to surface properties of PEO films, the optimum condition was formed when the applied was 270 V. The PEO films formed in the condition contained the properties of porosity, anatase phase, and near 1.7 Ca(Mg)/P ratio in the oxide film. Our experimental results demonstrate that Mg ion containing oxide promotes bone like apatite nucleation and growth from SBF. The phase and morphologies of bone like apatite were influenced by the Mg ion concentration.