• Title/Summary/Keyword: Total mercury

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Studies on the contents of heavy metals in Anguilla Japonica (자연산 및 양식뱀장어의 중금속 함유량 조사연구)

  • Son Byeong Mog;Bae Chung Ho
    • Journal of environmental and Sanitary engineering
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    • v.4 no.1 s.6
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    • pp.53-60
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    • 1989
  • This study was performed to investigate the contents of heavy metals in Anguilla japonica habiting in Korea. The samples were collected along by Nak Tongriver, Young San river and culture farms. Lead, Cadmium, Copper, Zinc, Manganese, Chromium were tested by the Atomic Absoption Spectrop-hotometer after wet digestion, Mercury was tested by using mercury analyzer. The results were as follows: 1. Aresenic, Copper contents in the four parts were the higest values in liver 2. In total mercury contents of the each parts, the higest value was detected in muscle. 3. In all metals, Zinc and Manganese were detected with high contents, Mecury and Cadmium were detected with low contents. Lead, Cadmium, Zinc, chromiumi, Manganese were detected with high in bone. 4, The difference was not significant between natural and feeding Anguilla Japonica, but significant correlation with parts.

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Permeability of a Filling Material in Teeth and Its Influence to Pulp Response (몇가지 충전재료의 치아경조직내 침투성과 치수의 반응에 관한 연구)

  • Kim, Yung-Hai
    • The Journal of the Korean dental association
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    • v.11 no.3
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    • pp.185-189
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    • 1973
  • Dental amalgam in the clinic practice of dentistry is one of the most important materials. Mercury, one of the component of this alloy, is emitted in the form of vapor after filling as long as 5 days Silver particles penetrate into the dentine deeply along the tubles underneath cavity floor. To determine the permeability of mercury in the teeth following experiments were performed. Class 5 cavities total 40 from 10 dogs were prepared on upper and lower canines and amalgam alloys which contain about 10uCi of radioactive mercury were inserted. The animals were sacrificed 7 days after the experiments and the teeth were decalcified, sectioned and autoradiographed by means of emulsion and stained by H & E. Following are the results obtained from this experiments. 1. Blackened silver grains were found along the dentinal tubules underneath the cavity floor. Beyond the border of dentine and pulp chamber grains were seen in odontoblastic layer (Fig. 1, 2, 3, 4) 2. Underneath the odontoblastic layer, the pulp tissue showed almost normal appearance except slight dilatation of blood vessel.

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Time for Young Adults to Reach Resting Blood Pressure after Walking as measured by an Automatic and a Mercury Sphygmomanometer (20대 성인의 보행 후 휴식시간에 따른 진동식 자동혈압계와 수은혈압계의 안정혈압 도달 시점)

  • Choi, Min-Jung;Sohng, Kyeong-Yae
    • Journal of Korean Academy of Fundamentals of Nursing
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    • v.21 no.4
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    • pp.370-379
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    • 2014
  • Purpose: The purpose of this study was to identify the time for young adults to reach resting blood pressure after walking as measured by an automatic and a mercury sphygmomanometer. Methods: Participants were 33 nursing students in their 20s. Blood pressure after walking was measured every minute on both arms simultaneously for a total of 6 times after walking for 12 minutes on a treadmill at ratings of perceived exertion (RPE) of 11. Data were analyzed using paired t-test, Bland-Altman plots and repeated measures ANOVA. Results: Systolic blood pressure after walking was the same as measurements corresponding to resting blood pressure after 3 minutes of resting if measured with the automatic sphygmomanometer and 4 minutes of resting if measured with the mercury sphygmomanometer. Conclusions: In order to measure the resting blood pressure for healthy young adults who performed low-density walking for 12 minutes on flat land, the measurement needs to be made after a resting time of at least 3 minutes in the case of an automatic sphygmomanometer and 4 minutes in the case of a mercury sphygmomanometer.

Antitoxic Effect of Korean Red Ginseng Extract on Serum Protein of Mouse Treated with Methyl Mercury (생쥐의 혈청 단백질에 미치는 메틸수은 독성에 대한 홍삼 추출물의 해독 효과)

  • Chung, Hee-Won
    • The Korean Journal of Ecology
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    • v.9 no.4
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    • pp.193-200
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    • 1986
  • In order to investigate the antiotoxic effect of red ginseng extract on serum protein of mouse treated with methyl mercury playing a role as toxic contaminant in ecosystem, variations of the serum protein contents, electrophoretic patterns, and blood components were studied. Mice were divided into 3 groups: Control, group I treated only with methyl mercury, and group II treated together with methyl mercury and red ginseng extract. The total serum protein content of the control group was 5.8g/dl and those of groups I and II were slightly decreased as compared with the control. The control group showed 11 serum protein fractions and groups I and II showed 10 fractions except prealbumin. The amounts of albumin, ${\alpha}_1-$, ${\alpha}_2-$ globulin fractions were decreased and those $\beta$-, $\gamma$-globulin fractions were increased in groups I and II. The amount of each serum protein fraction in group II showed approximately the same level as the control. The hematocrit value and the number of white blood cells of groups I and II were increased, whereas the number of red blood cells showed the decrease as compared with the control.

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Total Mercury Content and Risk Assessment of Farmed Fish Tissues (양식산 어류의 부위별 총수은 함량 및 위해도 평가)

  • Choi, WooSeok;Yoon, Minchul;Jo, MiRa;Kwon, Ji Young;Son, KwangTae;Kim, Ji Hoe;Lee, Tae Seek
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.49 no.1
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    • pp.7-12
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    • 2016
  • Total mercury (TM) is a hazardous element that is of particular concern to human health. Due to the diversity of dietary habits among fishes, tissue-specific analysis of hazardous elements is necessary. In this study, the tissue-specific TM in cultured fish was analyzed to conduct risk assessment. The highest concentrations of TM were found in the farmed marine fish Pagrus major (0.111 mg/kg) and in the farmed freshwater fish Channa argus (0.162 mg/kg). TM concentration was significantly correlated with total fish length (P<0.01). Significant differences in TM were found between three types of fish tissue, with the concentration in fish muscle being significantly higher than those of gill or liver (P<0.01). Moreover, the tissue-specific TM concentrations of farmed freshwater fish were significantly higher than those of farmed marine fish (P<0.01). According to the risk assessment, the TM body exposure rate of muscle and liver in cultured fishes ranged from 0.001 to 0.389% of the Provisional Tolerable Weekly Intake. Therefore, these results showing the tissue-specific TM contents of cultured fish could be useful to assess the health risks of Korean dietary habits.

Monitoring of Heavy Metal Contents in Commercial Herbal Medicines in Korea: Cultivated Herbal Medicines in the Seoul and Daegu Areas (국내 유통 한약재의 중금속 함량 모니터링 -서울과 대구지역 한약재 중심으로 -)

  • Jang, Seol;Lee, Ah-Reum;Lee, A-Eong;Choi, Go-Ya;Kim, Ho-Kyoung
    • Journal of Environmental Health Sciences
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    • v.41 no.1
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    • pp.30-39
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    • 2015
  • Objectives: This study was conducted to determine the heavy metal contents in commercial herbal medicines in Korea. Methods: Monitoring of lead, arsenic, cadmium and mercury was carried out on 116 samples of eleven types of herbal medicines. Among the total samples, 71 samples were domestic and 45 were imported. The samples were digested using the microwave method. The heavy metal contents were measured by inductively coupled plasma atomic emission spectrometry (ICP-AES) and a mercury analyzer. ICP-AES was used to analyze lead, arsenic cadmium. Mercury was analyzed by the amalgamation method. Results: The mean values of the heavy metal contents in the herbal medicines were Pb 0.64mg/kg, As 0.26mg/kg, Cd 0.07mg/kg and Hg 0.004mg/kg. Of the total samples, one violated the MFDS (Ministry of Food and Drug Safety) regulatory guidance on heavy metals in herbal medicines. Lead was detected at more than 5mg/kg in one sample. The measured values of arsenic, cadmium and mercury in the herbal medicines showed levels lower than the recommended levels for herbal medicines in MFDS regulatory guidance. In the comparison of domestic samples with imported herbal medicines, it was found that one domestic sample surpassed the maximum residue limits for lead. Conclusion: These results will be used to establish the regulation and control of heavy metal contents in herbal medicines. In addition, continuous monitoring is needed to ensure confidence in and the safety of these herbal medicines.

Concentrations and Risk Assessment of Total Mercury and Methyl Mercury in Commercial Marine Fisheries from Korea (한국산 수산물의 총 수은 및 메틸수은 농도 및 위해도 평가)

  • Choi, Minkyu;Yun, Sera;Park, Hye-Jung;Lee, Ja-Yeon;Lee, In-Seok;Hwang, Dong-Woon;Yoon, Min-Cheol;Choi, Woo Seok
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.50 no.6
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    • pp.675-683
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    • 2017
  • Total mercury (T-Hg) and methyl mercury (MeHg) were determined in marine fisheries (41 species, n=87) commonly consumed in Korea, using a gold amalgamation method and gas chromatography-cold vapor atomic fluorescent spectroscopy, respectively. Concentrations of T-Hg and MeHg in all samples (31 fish, 4 crustaceans, 4 cephalopods, and 2 gastropod species) were in the range of 0.016-0.495 (mean, 0.093) mg/kg-wet and not detected-0.338 (mean, 0.067) mg/kg-wet, respectively. The concentrations of MeHg in marine fisheries were significantly correlated with T-Hg concentrations (P<0.001). The highest mean concentrations of T-Hg and MeHg were found in fish species, followed by crustaceans. The contribution of MeHg to T-Hg was in the range of 64-95% (mean, 83%) in cephalopods, 28-98% (mean, 69%) in fish, and 26-88% (mean, 57%) in crustaceans. The weekly intakes of T-Hg and MeHg by fisheries consumption for the Korean general population were estimated to be 0.463 and $0.338{\mu}g/kg$ body weight/week, respectively. The concentrations and intakes of T-Hg and MeHg were less than the allowable residue levels and in the range of 12 to 17% of the provisional tolerable weekly intake (PTWI) applied in Korea.

The Pore-filling Effect of Bulk Graphite According to Viscosity of Impregnant (함침재의 점도에 따른 벌크흑연의 기공 채움 효과)

  • Lee, Sang-Min;Lee, Sang-Hye;Roh, Jae-Seung
    • Korean Journal of Materials Research
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    • v.31 no.2
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    • pp.101-107
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    • 2021
  • Pores produced by carbonization in bulk graphite process degrade the mechanical and electrical properties of bulk graphite. Therefore, the pores of bulk graphite must be reduced and an impregnation process needs to be performed for this reason. In this study, bulk graphite is impregnated by varying the viscosity of the impregnant. The pore volume and pore size distribution, according to the viscosity of the impregnant, are analyzed using a porosimeter. The total pore volume of bulk graphite is analyzed from the cumulative amount of mercury penetrated. The volume for a specific pore size is interpreted as the amount of mercury penetrating into that pore size. This decreases the cumulative amount of mercury penetrating into the recarbonized bulk graphite after impregnation because the viscosity of the impregnant is lower. The cumulative amount of mercury penetrating into bulk graphite before impregnation and after three times of impregnation with 5.1cP are 0.144 mL/g and 0.125 mL/gm, respectively. Therefore, it is confirmed that the impregnant filled the pores of the bulk graphite well. In this study, the impregnant with 5.1 cP, which is the lowest viscosity, shows the best effect for reducing the total pore volume. In addition, it is confirmed by Raman analysis that the impregnant is filled inside the pores. It is confirmed that phenolic resin, the impregnant, exists inside the pores through micro-Raman analysis from the inside of the pore to the outside.

Emission Characteristics of Mercury in Zn Smelting Process (아연제련시설에서의 수은 배출특성)

  • Park, Jung-Min;Lee, Sang-Bo;Kim, Hyung-Chun;Song, Duk-Jong;Kim, Min-Su;Kim, Min-Jung;Kim, Yong-Hee;Lee, Sang-Hak;Kim, Jong-Chun;Lee, Suk-Jo
    • Journal of Korean Society for Atmospheric Environment
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    • v.26 no.5
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    • pp.507-516
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    • 2010
  • Stationary combustion sources such as coal-fired power plants, waste incinerators, industrial manufacturing, etc. are recognized as major sources of mercury emissions. Due to rapid economic growth, zinc production in Korea has increased significantly during the last 30 years. Total zinc production in Korea exceeded 739,000 tons in 2008, and Korea is currently the third largest zinc producing country in the world. Previous studies have revealed that zinc smelting has become one of the largest single sectors of total mercury emissions in the World. However, studies on this sector are very limited, and a large gap in the knowledge regarding emissions from this sector needs to be bridged. In this paper, Hg emission measurements were performed to develop emission factors from zinc smelting process. Stack sampling and analysis were carried out utilizing the Ontario Hydro method and US EPA method 101A. Preliminary data showed that $Hg^0$ concentrations in the flue gas ranged from 4.56 to $9.90\;{\mu}g/m^3$ with an average of $6.40\;{\mu}g/m^3$, Hg(p) concentrations ranged from 0.03 to $0.09\;{\mu}g/m^3$ with an average of $0.04\;{\mu}g/m^3$, and RGM concentrations ranged from 0.23 to $1.17\;{\mu}g/m^3$ with an average of $6.40\;{\mu}g/m^3$. To date, emission factors of 7.5~8.0 g/ton for Europe, North America and Australia, and of 20 or 25 g/ton for Africa, Asia and South America are widely accepted by researchers. In this study, Hg emission factors were estimated using the data measured at the commercial facilities as emissions per ton of zinc product. Emission factors for mercury from zinc smelting pross ranged from 4.32 to 12.96 mg/ton with an average of 8.31 mg/ton. The emission factors that we obtained in this study are relatively low, considering Hg contents in the zinc ores and control technology in use. However, as these values are estimated by limited data of single measurement of each, the emission factor and total emission amount must be updated in future.

Selective determination of mercury (II) ion in aqueous solution by chemiluminescence method (화학발광법에 의한 수용액 중의 선택적 수은(II) 이온 정량)

  • Kim, Kyung-Min;Jang, Taek-Gyun;Kim, Young-Ho;Oh, Sang-Huyb;Lee, Sang-Hak
    • Analytical Science and Technology
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    • v.24 no.4
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    • pp.243-248
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    • 2011
  • A selective determination method of mercury (II) ion in aqueous solution by luminol-based chemiluminescence system (luminol CL system) has been developed. Determination of metal ions such as copper (II), iron (III), chromium (III) ion in solution by the luminol CL system using its catalytic role in the reaction of luminol and hydrogen peroxide has been reported by several groups. In this study, the catalytic activity of mercury (II) ion in the reaction of luminol and hydrogen peroxide was observed by the enhanced CL intensity of the luminol CL system. Based on this phenomenon, experimental conditions of the luminol CL system were investigated and optimized to determine mercury (II) ion in aqueous solution. While mercury (II) ion in mixed sample solution containing mercury (I) and (II) ions highly enhanced the CL intensity of the luminol CL system, the mercury (I) ion could not enhanced the CL intensity. Thus selective determination of the mercury (II) ions in a mixture containing mercury (I) and (II) ions could be achieved. Each concentration of mercury (I) and (II) ions in aqueous solution can be obtained from the results of the CL method that give the concentration of only mercury (II) ion and the inductively coupled plasma (ICP) method that give the total concentration of mercury ions. On the optimized conditions, the calibration curve of mercury (II) ion was linear over the range from $1.25{\times}10^{-5}$ to $2.50{\times}10^{-3}M$ with correlation coefficient of 0.991. The detection limit of mercury (II) ion in aqueous solution was calculated to be $1.25{\times}10^{-7}M$.