• Title/Summary/Keyword: Total internal energy

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Internal Energy Distributions of OH Products in the Reaction of O(3PJ) with HSiCl3

  • Kwak, Hyon-Tae;Ha, Seung-Chul;Jang, Sung-Woo;Kim, Hong-Lae;Park, Chan-Ryang
    • Bulletin of the Korean Chemical Society
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    • v.30 no.2
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    • pp.429-434
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    • 2009
  • The OH($X^2{\Pi},\;{\nu}$"=0, 1) internal state distributions from the reaction of electronically ground state oxygen atoms with HSi$Cl_3$ were measured using laser-induced fluorescence. The ground-state O$(^3P_J)$ atoms with kinetic energies above the reaction barrier were produced by photolysis of N$O_2$ at 355 nm. The OH product revealed strong vibrational population inversion, P(${\nu}$"=1)/P(${\nu}$"=0) = 4.0 ${\pm}$ 0.6, and rotational distributions in both vibrational states exhibit substantial rotational excitations to the limit of total available energy. However, no preferential populations in either of the two $\Lambda$ doublet states were observed from the micropopulations, which supports a mechanism involving a direct abstraction of hydrogen by the atomic oxygen. It was also found that the collision energy between O and HSi$Cl_3$ is effectively coupled into the excitation of the internal degrees of freedom of the OH product ($$ = 0.62, and $<\;f_{rot}>$ = 0.20). The dynamics appear consistent with expectations for the kinematically constrained reaction which supports the reaction type, heavy + light-heavy $\rightarrow$ heavy-light + heavy (H + LH′ $\rightarrow$ HL + H′). The dynamics of oxygen atom collision with HSi$Cl_3$ are discussed in comparison to those with Si$H_4$.

A Study on the Performance of the Heat Transfer for the Liquid Filling as the Ratio of Working Fluid Volume to Total Volume of the Thermosyphon with Axial Internal Fins (축방향 내부 핀을 가진 열사이폰의 작동유체 체적변화에 대한 열전달 성능에 관한 연구)

  • Lee, Jung-Han;Lee, Ki-Baik;Cho, Dong-Hyun
    • Journal of the Korean Solar Energy Society
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    • v.22 no.1
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    • pp.23-30
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    • 2002
  • This study concerns the performance of the heat transfer of the thermosyphon having 80 internal fins in which boiling and condensation occur. Water has been used as the working fluid. The Liquid filling as the ratio of working fluid volume to total volume of thermosyphon have been used as the experimental parameters. The heat flux and heat transfer coefficient at the condenser are estimated from the experimental results. The experimental results have been assessed and compared with existing theories. As a result of the experimental investigation we can state that the maximum heat flow rate in the thermosyphon prove to depend upon the liquid fill quantity. The relatively high rates of heat transfer have been achived operating in the thermosyphon with axial internal fins. Also, the thermosyphon with internal micro fins can be used to achieve some inexpensive and compact heat exchangers in low temperature. In addition, it is to obtain the overall heat transfer coefficients and the characteristics as a operating temperature for the practical applications.

A Study of Motor Expertise about Kinematic and Kinetic Characteristics of Lower Extremity in the Seokmun Ilwol Martial Art Yin-yang Bo Gait Pattern (석문일월무예 음양보법의 숙련성에 따른 보행 패턴의 하지 운동학 및 운동역학적 특성)

  • Park, Bok-Hee;Kim, Ky-Hyoung
    • Korean Journal of Applied Biomechanics
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    • v.24 no.3
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    • pp.239-248
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    • 2014
  • The purpose of this study was to quantify kinematic and kinetic characteristics of Yin-yang Bo gait according to their motor expertise, one of the Seokmun Ilwol martial art gait patterns. Yin-yang Bo gait pattern shows initial forefoot contact instead of heel contact, and increased time of stance phase time, internal-external rotation of ankle-knee-hip joints and pelvic. It aims to produce and store the more energy through continuous homeostasis of center of gravity (COG) and performance of stretch-shortening cycle. Some of these characteristics also were similar to the gait modification strategies for reducing knee adduction moment such as toe-out progression, medial thrust, internal rotation of hip joint. To identify the characteristics, four factors of expert Yin-yang Bo gait performance group were compared to that of none expert group; 1) angles of COG displacement and rotation 2) distal joint pre-rotation in internal-external rotation of ankle-knee-hip joints and pelvic, 3) invariability pelvic potential and pelvic segment total energy 4) knee abduction moment. Six healthy(three male) subjects participated in the experiment to perform Yin-yang gait pattern. Three-dimensional and force plate data were collected. Kinematic and kinetic data were compared between two groups using t-tests. Results showed that 1) the peak point of COG internal rotation angle was reduced in expert group, 2) kneeexternal and hip joint -internal and pelvic rotation angle peak frames were more near points in expert group.

Theoretical Considerations on Effect of Environments on Strain Hardening

  • Lee, Byoung-Whie
    • Nuclear Engineering and Technology
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    • v.3 no.1
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    • pp.21-31
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    • 1971
  • The part of the work of plastic deformation of metal goes into the changes in the total surface free energy. This contribution is dependent on the specific surface free energy, which is affected by the environment. Based on thermodynamical approach, volume constancy requirement and adsorption induced two distinct dislocation interaction mechanisms for strengthening or weakening of metals at surface, theoretical derivation has been made to show that the environmental contribution on the strain hardening, the stress and the energy required for plastic deformation can be expressed in terms of solid surface tension in vacuum (${\gamma}$$_{s}$), interfacial tension (${\gamma}$$_{se}$ ), surface dislocation density ($\rho$$_{s}$), internal dislocation density ($\rho$$_{i}$) and fraction of surface site uncoverage (f). On the basis of theoretical derivation, the various mechanical behaviours under different environments are predicted.d.d.

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Internal Resonance and Stability Change for the Two Degree Nonlinear Coupled System (2 자유도 비선형 연성시스템에서 내부공진과 안정성 변화)

  • Kim, Myoung-Gu;Pak, Chul-Hui;Cho, Chong-Du
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2007.11a
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    • pp.853-861
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    • 2007
  • To understand the concept of dynamic motion in two degree nonlinear coupled system, free vibration not including damping and excitation is investigated with the concept of nonlinear normal mode. Stability analysis of a coupled system is conducted, and the theoretical analysis performed for the bifurcation phenomenon in the system. Bifurcation point is estimated using harmonic balance method. When the bifurcation occurs, the saddle point is always found on Poincare's map. Nonlinear phenomenon result in amplitude modulation near the saddle point and the internal resonance in the system making continuous interchange of energy. If the bifurcation in the normal mode is local, the motion remains stable for a long time even when the total energy is increased in the system. On the other hand, if the bifurcation is global, the motion in the normal mode disappears into the chaos range as the range becomes gradually large.

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Free vibrations of arbitrary quadrilateral thick plates with internal columns and uniform elastic edge supports by pb-2 Ritz method

  • Wu, L.H.
    • Structural Engineering and Mechanics
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    • v.44 no.3
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    • pp.267-288
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    • 2012
  • Free vibration analysis of arbitrary quadrilateral thick plates with internal columns and elastic edge supports is presented by using the powerful pb-2 Ritz method and Reddy's third order shear deformation plate theory. The computing domain of arbitrary quadrilateral planform is mapped onto a standard square form by coordinate transformation. The versatile pb-2 Ritz functions defined by the product of a two-dimensional polynomial and a basic function are taken to be the admissible functions. Substituting these displacement functions into the energy functional and minimizing the total energy by differentiation, leads to a typical eigenvalue problem, which is solved by a standard eigenvalue solver. Stiffness and mass matrices are numerically integrated over the plate by using Gaussian quadrature. The accuracy and efficiency of the proposed method are demonstrated through several numerical examples by comparison and convergency studies. A lot of numerical results for reasonable natural frequency parameters of quadrilateral plates with different combinations of elastic boundary conditions and column supports at any locations are presented, which can be used as a benchmark for future studies in this area.

DENSITY STRUCTURE AND STABILITY OF THE SUBCOMPONENTS IN GIANT MOLECULAR CLOUD COMPLEXES

  • Yoo, Chin-Woo;Hong, Seung-Soo
    • Journal of The Korean Astronomical Society
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    • v.19 no.1
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    • pp.33-49
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    • 1986
  • Radial distribution of internal density has been determined for thirteen subclouds in the three giant molecular cloud complexes accompanying Mon OB1, Mon OB2 and CMa OB1 associations, We modeled their radial density structures with the density distribution of isothermal gas spheres. Most of the subclouds, nine out of the thirteen, are well described by isothermal spheres of single component; while the rest four require an additional component. Total mass and potential energy of each subcloud are also derived from the radial density structure; thermal energy and internal velocity dispersion required for sustaining the density structure are deduced from the isothermal gas model. Our derived masses of the clouds are comparable to the values determined by Blitz (1978) under LTE assumption. This agreement suggests that the correction factor for non-LTE effect on mass-estimate is not far from unity. The ratio of the gravitational potential energy to the kinetic energy of thermal motion is as large as 250; hence the thermal motion alone cannot support these clouds against the gravity. Being supported by turbulence motion with velocities of six to seven times the thermal velocity, the clouds of one-component type seem to be in equilibrium with the gravity; while the clouds of two-component type are likely to be in the stage of gravitational collapse.

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Numerical Analysis Research for Evaluating the Energy Efficiency of Electric Vehicles (전기자동차 에너지효율 평가를 위한 수치해석 연구)

  • Mingi Choi
    • Journal of ILASS-Korea
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    • v.29 no.1
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    • pp.1-6
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    • 2024
  • This paper is a numerical analysis study for evaluating the energy efficiency of electric vehicles. Currently, the methods for testing and evaluating the energy consumption efficiency of electric vehicles have limitations such as resources and time. Therefore, there is a need for research on developing models to predict the energy consumption efficiency of electric vehicles. In this study, a numerical analysis research is conducted to predict the energy efficiency of electric vehicles using a vehicle dynamics numerical analysis model. To validate the accuracy of the simulation model, it is compared the results of dynamometer tests with the simulation results and used the Unified Diagnostic Services (UDS) protocol to acquire internal data from the electric vehicle. It is ensured the reliability of the simulation model by comparing data such as motor speed, battery voltage, current, state of charge (SOC), regenerative braking power generation, and total driving distance of the test vehicle with dynamometer test data and simulation model results.

Analysis of cable structures through energy minimization

  • Toklu, Yusuf Cengiz;Bekdas, Gebrail;Temur, Rasim
    • Structural Engineering and Mechanics
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    • v.62 no.6
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    • pp.749-758
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    • 2017
  • In structural mechanics, traditional analyses methods usually employ matrix operations for obtaining displacement and internal forces of the structure under the external effects, such as distributed loads, earthquake or wind excitations, and temperature changing inter alia. These matrices are derived from the well-known principle of mechanics called minimum potential energy. According to this principle, a system can be in the equilibrium state only in case when the total potential energy of system is minimum. A close examination of the expression of the well-known equilibrium condition for linear problems, $P=K{\Delta}$, where P is the load vector, K is the stiffness matrix and ${\Delta}$ is the displacement vector, it is seen that, basically this principle searches the displacement set (or deformed shape) for a system that minimizes the total potential energy of it. Instead of using mathematical operations used in the conventional methods, with a different formulation, meta-heuristic algorithms can also be used for solving this minimization problem by defining total potential energy as objective function and displacements as design variables. Based on this idea the technique called Total Potential Optimization using Meta-heuristic Algorithms (TPO/MA) is proposed. The method has been successfully applied for linear and non-linear analyses of trusses and truss-like structures, and the results have shown that the approach is much more successful than conventional methods, especially for analyses of non-linear systems. In this study, the application of TPO/MA, with Harmony Search as the selected meta-heuristic algorithm, to cables net system is presented. The results have shown that the method is robust, powerful and accurate.

The Indoor Environmental Quality Improving and Energy Saving Potential of Phase-Change Material Integrated Facades for High-Rise Office Buildings in Shanghai

  • Jin, Qian
    • International Journal of High-Rise Buildings
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    • v.6 no.2
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    • pp.197-205
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    • 2017
  • The conflict between indoor environmental quality and energy consumption has become an unneglectable problem for highrise office buildings, where occupants' productivity is highly affected by their working environment. An effective Façade, therefore, should play the role of an active building skin by adapting to the ever-changing external environment and internal requirements. This paper explores the energy-saving and indoor environment-improving potential of a phase-change material (PCM) integrated Façade. Building performance simulations, combined with parametric study and sensitivity analysis, are adopted in this research. The result quantifies the potential of a PCM-integrated Façade with different configurations and PCM properties, taking as an example a south-oriented typical office room in Shanghai. It is found that a melting temperature of around $22^{\circ}C$ for the PCM layer is optimal. Compared to a conventional Façade, a PCM-integrated Façade effectively reduces total energy use, peak heating/cooling load, and operative temperature fluctuation during the periods of May-July and November-December.