• Title/Summary/Keyword: Time mixture

Search Result 2,362, Processing Time 0.028 seconds

Utrastructural Analysis of the Delignification Behaviour in P-Cresol-Water Solvent Pulping (크레졸-물 용매펄프화의 탈리그닌에 관한 초미세구조적 분석)

  • Kim, Chang-Keun;Jo, Byoung-Muk
    • Journal of the Korean Wood Science and Technology
    • /
    • v.20 no.1
    • /
    • pp.60-71
    • /
    • 1992
  • To investigate the delignification behaviour in solvolysis pulping process, Populus alba ${\times}$ glandulosa H. and Pinus Kuraiensis S. et Z. were cooked with p-cresol and vater solvent(2:8, 5:5, 8:2 v/v) at $175^{\circ}C$ for 9 cooking time levels(20, 40, 60, 80, 100, 120, 140, 160, 180, min). Pulp yield, residual lignin content, de lignification rate, decarborhydration rate were determined. Delignification behaviours were analyzed by TEM. 1. The p-cresol-water solvent cooking of P. alba ${\times}$ glandulosa showed good delignification at the solvent system which the mixture ratio of p-cresol and water were 2:8(v/v), while the cooking of P. koraiensis with the p-cresol and water mixture ratio of 5:5 was no good. 2. P. alba ${\times}$ glandulosa showed three step-delignification phenomena at the solvent system which the mixture ratio of p-cresol and water were 2:8(v/v) anti 5:5(v/v). But P. koraiensis showed a first order delignification reaction at the same mixture ratio of p-cresol and water solvent system. 3. In TEM micrograph obtained for the solvent system which the mixture ratio of p-cresol and water was 5:5(v/v), the partial delignification of the cell corner of P. alba ${\times}$ glandulosa and P. koraiensis were observed at 60min. of cooking time. Complete delignification at the cell corner of P. alba ${\times}$ glandulosa was observed at 160min. and that of P. koraiensis was observed of 180min. of cooking time. 4. In optical microscopic observation, fiber separation of P. alba ${\times}$ glandulosa occured at 120min. and that of P. koraiensis began at 140min. of cooking time. 5. At the solvent system which the mixture ratio of p-cresol and water was 5:5(v/v), middle layer on secondary wall($S_2$) and cell corner of P. alba ${\times}$ glandulosa were more selectively delignified than primary wall(P) and outer layer on secondary wall($S_1$). However P. koraiensis did not showed any difference in delignification between cell wall layers and cell corner.

  • PDF

Hydrogen Separation from Multi-Component Mixture Gases by Pressure Swing Adsorption Process (PSA 공정을 이용한 다성분 혼합가스의 수소 분리)

  • Yang, Se-Il;Ahn, Eui-Sub;Jang, Seong-Cheol;Choi, Do-Young;Choi, Dae-Ki
    • 한국신재생에너지학회:학술대회논문집
    • /
    • 2006.11a
    • /
    • pp.447-450
    • /
    • 2006
  • Hydrogen separation from multi-component mixture gases by the four-bed PSA process was studied experimentally and theoretically using layered bed of activated carbon and zeolited 5A. Effects of the adsorption time, the linear velocity on the process performance were investigated. The adsorption time and linear velocity affected the purity and recovery of the product $H_2$ purity is increases according as the adsorption time and linear velocity decrease; however, $H_2$ recovery shows an opposite phenomena to the purity. PSA process simulation studied to find optimum operation condition. In the results, 50sec adsorption time, 3cm/s linear velocity might be optimal values to obtain more than 99.999% purity and 65% recovery hydrogen.

  • PDF

A Study on the Prediction of Durability of Concrete Structures Subjected to Chloride Attack by Chloride Diffusion Model (염소이온의 확산모델에 의한 염해를 받는 콘크리트 구조물의 내구성 예측연구)

  • 오병환;장승엽;차수원;이명규
    • Proceedings of the Korea Concrete Institute Conference
    • /
    • 1997.04a
    • /
    • pp.254-260
    • /
    • 1997
  • Chloride-induced corrosion of reinforcement is one of the main factors which cause the deterioration of concrete structures. Durability and service lives of the concrete sturctures should be predicted in order to minimize the risk of corrosion of reinforcement. The objective of this study is to suggest the basis of analytical methods of predicting the corrosion threhold time of concrete structures. Based on the chemistry and physics of chloride ion transport and corrosion process, chloride intrusion with various exposure conditions, variability of diffusivity and transport of pore water in concrete are taken into consideration in applying finite element formulation to the predicion of corrosion threhold time. The effects of main factors on the prediction of chloride intrusion and corrosion threhold time are examined. In addition, after chloride diffusivities of several mixture proportions with different parameters are measured by chloride diffusion test, the exemplary anayses of corrosion threhold time of those mixture proportions are carried out.

  • PDF

A Study on the Homogeneity of Powder Mixture (분말약품 혼합의 균일성에 관한 연구)

  • 김길수;이민화
    • YAKHAK HOEJI
    • /
    • v.21 no.2
    • /
    • pp.95-100
    • /
    • 1977
  • The effects of the particle size on the homogeneity of mixing and segregation of caffeine-lactose (1:99) mixture were studied. Using the two kinds of caffein, milled and unmilled caffein, V-type blender, the degree of mixing according to the particle size was predicted and the experiment on the change of mixedness by mixing time was carried out by the method derived from mixing index theory by Poole et al. and Hersey. the results could be summarized as follows; (1) The homogeneity of mixing was greatly affected by the particle size and the particle size should be reduced to the adepuate level to attain the desirable mixedness. (2) The homogeneity was not proportional to the mixing time and optimum mixing time for caffein-lactose was about 10 minutes. (3) Segregation tendency was increased by the particle size increase and greatly affected by the flow time in the segregation cell.

  • PDF

Microwave Dielectric Characterization of Binary Mixtures of 3-Nitrotoluene with Dimethylacetamide, Dimethylformamide and Dimethylsulphoxide

  • Chaudhari, Ajay;Chaudhari, H.C.;Mehrotra, S.C.
    • Bulletin of the Korean Chemical Society
    • /
    • v.25 no.9
    • /
    • pp.1403-1407
    • /
    • 2004
  • Dielectric relaxation measurements on 3-nitrotoluene (3-NT) mixture of dimethylacetamide (DMA), dimethylformamide (DMF) and dimethysulphoxide (DMSO) have been carried out across the entire concentration range using Time domain reflectometry technique at 15, 25, 35 and $45^{\circ}C$ over the frequency range from 10 MHz to 20 GHz. For all the mixtures, only one dielectric loss peak was observed in this frequency range and the relaxation in these mixtures can be well described by a single relaxation time using Debye model. Bilinear calibration method is used to obtain complex permittivity ${\varepsilon}^{*}({\omega})$ from complex reflection coefficient ${\rho}^{*}({\omega})$ over frequency range 10 MHz to 20 GHz. The excess permittivity, excess inverse relaxation time, Kirkwood correlation factor, molar energy of activation are also calculated for these mixtures to study the solute-solvent interaction.

Sorption Characteristics of Binary Mixture of Sugar and Sodium Chloride (저장상대습도(貯藏相對濕度)에 따른 당(糖)과 소금 이상혼합물(二相混合物)의 흡습특성(吸濕特性))

  • Oh, Hoon-Il;Kim, Woo-Jung;Park, Nae-Jung
    • Korean Journal of Food Science and Technology
    • /
    • v.15 no.1
    • /
    • pp.19-26
    • /
    • 1983
  • A study was designed to investigate the sorption characteristics of binary mixtures of NaCl and sucrose or glucose stored at various relative humidities ranging from 46% to 92%. At low relative humidity below RH 65%, the sorption equilibrium was easily achieved, whereas at higher relative humidity values over 73%, all of the mixtures tended to cintinously absorb moisture with increase in storage time. A linear equation of log $({\frac{dw}{dt}})$ = a log(t) + log(b) was found to be valid between the sorption rate and storage time with respect to storage humidities. In sucrose-NaCl mixture, the slope showed a increasing tendency as the percentage of NaCl increased in the mixture, while that of glucose-NaCl mixture failed to show a definite trend. Plateaus were obtained when the amount of water absorbed was plotted on the X axis and the percent composition of mixture on the Y axis at different storage time. The shape of plateau was varied with respect to the kind of sugar-NaCl mixture, composition of the mixture and relative humidities. A linearity was found between log(1-Aw) and the amount of water absorbed over the Aw range 0.73-0.92 and the slope was affected by the kind and composition of sugar-NaCl mixtures.

  • PDF

Control Efficacy of the Mixture of Fluxapyroxad Plus Pyraclostrobin against Pear Scab Caused by Venturia nashicola (배 검은별무늬병에 대한 Fluxapyroxad/Pyraclostrobin 합제의 방제 효과)

  • Min, Kwang-Hyun;Ryu, Jeong-Pil;Kim, Ju-Mi;Kim, Sun-Hwa;Yim, Sun Hee;Choi, Jang Jeon;Cho, Baik Ho;Yang, Kwang-Yeol
    • The Korean Journal of Pesticide Science
    • /
    • v.18 no.4
    • /
    • pp.434-438
    • /
    • 2014
  • The mixture of fluxapyroxad plus pyraclostrobin or the 9 time-spray schedule with various fungicides was evaluated for their efficacy in controlling pear scab in field trials. It showed sufficient condition to evaluate the efficacy of fungicides for the control of pear scab since disease incidence of the untreated control plot was 58.4% or 100% on leaves or fruits, respectively. Pear scab on leaves was occurred by 6.3% at treated plot with the mixture of fluxapyroxad plus pyraclostrobin, resulting in the 89.2% of control value. Incidence of the fruit disease was 16.7% at treated plot with the mixture of fluxapyroxad plus pyraclostrobin, showing 83.3% of control value. When the 9 time-spray schedule was tested, pear scab was occurred by 5% or 13.3% on leaves or fruits, respectively. Their control values were the 91.4% on leaves or 86.7% on fruits. Although the 9 time-spray schedule showed slightly lower disease incidence than the mixture of fluxapyroxad plus pyraclostrobin, but there is no statistically significant difference. These results suggest that the mixture of fluxapyroxad plus pyraclostrobin can control effectively the pear scab.

Model-based Clustering of DOA Data Using von Mises Mixture Model for Sound Source Localization

  • Dinh, Quang Nguyen;Lee, Chang-Hoon
    • International Journal of Fuzzy Logic and Intelligent Systems
    • /
    • v.13 no.1
    • /
    • pp.59-66
    • /
    • 2013
  • In this paper, we propose a probabilistic framework for model-based clustering of direction of arrival (DOA) data to obtain stable sound source localization (SSL) estimates. Model-based clustering has been shown capable of handling highly overlapped and noisy datasets, such as those involved in DOA detection. Although the Gaussian mixture model is commonly used for model-based clustering, we propose use of the von Mises mixture model as more befitting circular DOA data than a Gaussian distribution. The EM framework for the von Mises mixture model in a unit hyper sphere is degenerated for the 2D case and used as such in the proposed method. We also use a histogram of the dataset to initialize the number of clusters and the initial values of parameters, thereby saving calculation time and improving the efficiency. Experiments using simulated and real-world datasets demonstrate the performance of the proposed method.

Combustion Characteristics of Methane-Air Mixture in a Constant Volume Combustion Chamber(1): Homogeneous Charge (정적연소기에서의 메탄-공기 혼합기의 연소특성(1) : 균질급기)

  • 최승환;전충환;장연준
    • Transactions of the Korean Society of Automotive Engineers
    • /
    • v.11 no.3
    • /
    • pp.48-57
    • /
    • 2003
  • A cylindrical constant volume combustion chamber was used to investigate the flow characteristics at spark plug and the combustion characteristics of homogeneous charge methane-air mixture under various initial pressure, excess air ratio and ignition times in quiescent mixture. The flow characteristics such as mean velocity and turbulence intensity was analyzed by hot wire anemometer. Combustion pressure development measured by piezoelectric pressure transducer and flame propagation acquired by ICCD camera were used to investigate the effect of initial pressure, excess air ratio and ignition times on pressure, combustion duration, flame speed and burning velocity. Mean velocity and turbulence intensity had the maximum value at 200 or 300ms and then decreased to near 0 value gradually after 3 seconds. Combustion duration, flame speed and burning velocity were observed to be promoted with excess air ratio of 1.1, lower initial pressure and ignition time of 300ms.

A Study on the Morphology of Carbon Nanomaterials prepared by Thermal CVD on the Mechanochemical Treated Catalysts

  • Ryu, Ho-Jin;Yi, Hyung-Kyun;Saito, Fumio;Lee, Byuung-Il;Chang, Ho-Jung
    • Proceedings of the Korean Society Of Semiconductor Equipment Technology
    • /
    • 2002.11a
    • /
    • pp.75-78
    • /
    • 2002
  • CNTs have been grown by the thermal CVD process in which $C_{2}H_{2}$ gas was deposited on the Fe - $Al(OH)_3$ mixture pretreated by mechanochemical treatment with a high energy mixer mill. As the duration time of grinding fer $Fe-(Al(OH)_3$ mixture by the mixer mill increased, amorphous $Al(OH)_3$ and more smaller Fe particles agglomerated into spheres. With unground and ground mixtures of $Fe-Al(OH)_3$, CNTs were grown at $700^{\circ}C$. As a result, CNTs grown on ground mixtures have more uniform diameter and morphology than those of unground mixture. The characterization of $Fe-Al(OH)_3$ mixture and as-grown CNTs were done by XRD, SEM and TEM.

  • PDF