• Title/Summary/Keyword: Time Resolved

검색결과 894건 처리시간 0.033초

Control of Block Copolymer Microdomain: In-Situ and Real-Time SANS Studies of Polymerization-Induced Self-assembly of Block Copolymer Microdomain Structure

  • Koizumi, Satoshi;Yamauchi, Kazuhiro;Hasegawa, Hirokazu;Tanaka, Hirokazu;Motokawa, Ryuhei;Hashimoto, Takeji
    • Proceedings of the Polymer Society of Korea Conference
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    • 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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    • pp.71-72
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    • 2006
  • We investigated a simultaneous living anionic polymerization process of isoprene (I) and 4styrene-d_8$ (S) in $benzene-d_6$ as a solvent with sec-buthyllithium as an initiator into polyisoprene(PI)-block-poly($styrene-d_8$)(PS) and the polymerization-induced molecular self-assembling process. This process was observed in-situ by time-resolved small-angle neutron scattering (SANS) experiment. The SANS profiles measured exhibited three time regions, where (i) the selective growth of PI chains occurs; (ii) the living chain ends switch from isoprenyllithium to styryllithium, and (iii) the SANS exhibited the polymerization induced disorder-to-order transition and order-to-order transition.

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A dynamic game approach to robust stabilization of time-varying discrete linear systems via receding horizon control strategy

  • Lee, Jae-Won;Kwon, Wook-Hyun
    • 제어로봇시스템학회:학술대회논문집
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    • 제어로봇시스템학회 1995년도 Proceedings of the Korea Automation Control Conference, 10th (KACC); Seoul, Korea; 23-25 Oct. 1995
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    • pp.424-427
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    • 1995
  • In this paper, a control law based on the receding horizon concept which robustly stabilizes time-varying discrete linear systems, is proposed. A dynamic game problem minimizing the worst case performance, is adopted as an optimization problem which should be resolved at every current time. The objective of the proposed control law is to guarantee the closed loop stability and the infinite horizon $H^{\infty}$ norm bound. It is shown that the objective can be achieved by selecting the proper terminal weighting matrices which satisfy the inequality conditions proposed in this paper. An example is included to illustrate the results..

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Shear Layer and Wave Structure Over Partially Spanning Cavities

  • Das, Rajarshi;Kim, Heuy Dong;Kurian, Job
    • Journal of the Korean Society of Visualization
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    • 제11권2호
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    • pp.46-54
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    • 2013
  • Study of the wave structure and shear layer in the vicinity of a wall mounted cavity is done by time averaged colour schlieren and time resolved instantaneous shadowgraph technique in an M=1.7 flowfield. Effect of change of cavity width on flow structure is investigated by using constant length to depth (L/D) ratio cavity models with varying length to width (L/W) ratio of 0.83 to 4. The time averaged shock wave structure was observed to change with change in cavity width. Dependence of the shock angle at the leading edge on the shear layer width is also evident from the images obtained. Unsteadiness in the flow field in terms of shear layer dynamics and quasi steady nature of shock waves was evident from the images obtained during instantaneous shadowgraph experiments. Apart from the leading and trailing edge shocks, several other waves and flow features were observed. These flow features and the associated physical phenomena are discussed in details and presented in the paper.

Development of Femtosecond Stimulated Raman Spectroscopy: Stimulated Raman Gain via Elimination of Cross Phase Modulation

  • Jin, Seung-Min;Lee, Young-Jong;Yu, Jong-Wan;Kim, Seong-Keun
    • Bulletin of the Korean Chemical Society
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    • 제25권12호
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    • pp.1829-1832
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    • 2004
  • We have developed a new femtosecond probe technique by using stimulated Raman spectroscopy. The cross phase modulation in femtosecond time scale associated with off-resonant interaction was shown to be eliminated by integrating the transient gain/loss signal over the time delay between the Raman pump pulse and the continuum pulse. The stimulated Raman gain of neat cyclohexane was obtained to demonstrate the feasibility of the technique. Spectral and temporal widths of stimulated Raman spectra were controlled by using a narrow band pass filter. Femtosecond stimulated Raman spectroscopy was proposed as a highly useful probe in time-resolved vibrational spectroscopy.

Analysis of Turbulence Scales and Energy Spectrum for Engine Flows (엔진 난류의 크기척도 및 에너지 스펙트럼 해석)

  • Kang, Kern-Yong;Lee, Jin-Wook;Park, Seung-Chul
    • Transactions of the Korean Society of Mechanical Engineers B
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    • 제22권9호
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    • pp.1307-1316
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    • 1998
  • Engine turbulences obtained by LDV measurement near the compression TDC was analyzed by the classic turbulence theory. Turbulences were quantified by a cycle resolved analysis and processed to reveal integral time scale and length scale. Three different definitions were applied to obtain the turbulence time scales and then compared each others. The classic turbulence theory with the several assumptions for engine application proven to be very efficient for understanding engine turbulence in this study. It was found that the integral length scale is strongly affected and increased by tumble flow.

A New GPS Receiver Correlator for the Deeply Coupled GPS/INS Integration System

  • Kim, Jeong-Won;Hwang, Dong-Hwan;Lee, Sang-Jeong
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
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    • 한국항해항만학회 2006년도 International Symposium on GPS/GNSS Vol.1
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    • pp.121-125
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    • 2006
  • A new GPS receiver correlator for the deeply-coupled GPS/INS integration system is proposed in order to the computation time problem of the Kalman filter. The proposed correlator consists of two early, prompt and late arm pairs. One pair is for detecting data bit transition boundary and another is for the correlator value calculation between input and replica signal. By detecting the data bit transition boundary, the measurement calculation time can be made longer than data bit period. As a result of this, the computational time problem of the integrated Kalman filter can be resolved. The validity of the proposed method is given through computer simulations.

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Ultrafast Investigation of Vibrational Relaxation and Solvent Coordination Following Photodissociation of Cr$(CO)_6$

  • Seok-Beum Ko;Soo-Chang Yu;J. B. Hopkins
    • Bulletin of the Korean Chemical Society
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    • 제15권9호
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    • pp.762-765
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    • 1994
  • Picosecond time-resolved resonance Raman spectroscopy has been used to study the photochemistry of Cr(CO$)_6$ in cyclohexane following photoexcitation at 266 nm. Photodissociative loss of CO is found to occur within our pulse width of ${\leq}$5 ps by probing the 533 c$m^{-1}$ vibrational mode of ground state Cr(CO$)_6$. The subsequent dynamics after photodissociation are interpreted in terms of solvation, vibrational and electronic relaxations. The vibrational relaxation time of 100 ps and 83 ps are observed by monitoring v=O and v=l of the 381 c$m^{-1}$ transient mode, respectively. No evidence was found for solvation and electronic relaxation occurring on a time scale of ${\leq}$5 ps.

Direct Time-domain Phase Correction of Dual-comb Interferograms for Comb-resolved Spectroscopy

  • Lee, Joohyung
    • Current Optics and Photonics
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    • 제5권3호
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    • pp.289-297
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    • 2021
  • We describe a comb-mode resolving spectroscopic technique by direct time-domain phase correction of unstable interferograms obtained from loosely locked two femtosecond lasers. A low-cost continuous wave laser and conventional repetition rate stabilization method were exploited for locking carrier and envelope phase of interferograms, respectively. We intentionally set the servo control at low bandwidth, resulting in severe interferograms' fluctuation to demonstrate the capability of the proposed correction method. The envelope phase of each interferogram was estimated by a quadratic fit of carrier peaks to correct timing fluctuation of interferograms in the time domain. After envelope phase correction on individual interferograms, we successfully demonstrated 1 Hz linewidth of RF comb-mode over 200 GHz optical spectral-bandwidth with 10-times signal-to-noise ratio (SNR) enhancement compared to the spectrum without correction. Besides, the group delay difference between two femtosecond pulses is successfully estimated through a linear slope of phase information.

Fast Real-Time Cardiac MRI: a Review of Current Techniques and Future Directions

  • Wang, Xiaoqing;Uecker, Martin;Feng, Li
    • Investigative Magnetic Resonance Imaging
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    • 제25권4호
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    • pp.252-265
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    • 2021
  • Cardiac magnetic resonance imaging (MRI) serves as a clinical gold-standard non-invasive imaging technique for the assessment of global and regional cardiac function. Conventional cardiac MRI is limited by the long acquisition time, the need for ECG gating and/or long breathhold, and insufficient spatiotemporal resolution. Real-time cardiac cine MRI refers to high spatiotemporal cardiac imaging using data acquired continuously without synchronization or binning, and therefore of potential interest in overcoming the limitations of conventional cardiac MRI. Novel acquisition and reconstruction techniques must be employed to facilitate real-time cardiac MRI. The goal of this study is to discuss methods that have been developed for real-time cardiac MRI. In particular, we classified existing techniques into two categories based on the use of non-iterative and iterative reconstruction. In addition, we present several research trends in this direction, including deep learning-based image reconstruction and other advanced real-time cardiac MRI strategies that reconstruct images acquired from real-time free-breathing techniques.

Study on Barkhausen Avalanches in Fe Thin Film (Fe 박막에서의 박하우젠 현상 연구)

  • Lee, Hun-Sung;Ryu, Kwang-Su;Shin, Sung-Chul;Kang, Im-Seok
    • Journal of the Korean Magnetics Society
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    • 제19권5호
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    • pp.176-179
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    • 2009
  • We report a direct observation of Barkhausen avalanches in 50-nm Fe film, using a magneto-optical microscope magnetometer, capable of time-resolved domain observation. The time-resolved domain-evolution patterns exhibit that the occurrence of Barkhausen jump is random with respect to interval, size, and location. From the repetitive measurements more than 1000 times, we found that the probability distribution of Barkhausen jump size follows a power-law distribution and the critical exponent reveals the value of 1.14 $\pm$ 0.03.