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http://dx.doi.org/10.5012/bkcs.2004.25.12.1829

Development of Femtosecond Stimulated Raman Spectroscopy: Stimulated Raman Gain via Elimination of Cross Phase Modulation  

Jin, Seung-Min (School of Chemistry, Seoul National University)
Lee, Young-Jong (Department of Chemistry and Biochemistry, University of Texas)
Yu, Jong-Wan (School of Chemistry, Seoul National University)
Kim, Seong-Keun (School of Chemistry, Seoul National University)
Publication Information
Bulletin of the Korean Chemical Society / v.25, no.12, 2004 , pp. 1829-1832 More about this Journal
Abstract
We have developed a new femtosecond probe technique by using stimulated Raman spectroscopy. The cross phase modulation in femtosecond time scale associated with off-resonant interaction was shown to be eliminated by integrating the transient gain/loss signal over the time delay between the Raman pump pulse and the continuum pulse. The stimulated Raman gain of neat cyclohexane was obtained to demonstrate the feasibility of the technique. Spectral and temporal widths of stimulated Raman spectra were controlled by using a narrow band pass filter. Femtosecond stimulated Raman spectroscopy was proposed as a highly useful probe in time-resolved vibrational spectroscopy.
Keywords
Stimulated Raman; Raman gain; Cross phase modulation; Femtochemistry;
Citations & Related Records
Times Cited By KSCI : 2  (Citation Analysis)
Times Cited By Web Of Science : 15  (Related Records In Web of Science)
Times Cited By SCOPUS : 14
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