• Title/Summary/Keyword: Time Dissociation

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Sperm Transfer and Sperm Activation in Tasar Silkmoth, Antheraea Mylitta

  • G. Ravikumar;H. Rajeswary;N.G. Ojha;S.S. Sinha
    • Journal of Sericultural and Entomological Science
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    • v.40 no.1
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    • pp.33-37
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    • 1998
  • Two types of sperm, apyrene and eupyrene, are identified in A. mylitta. The sperm in the adult moth are motionless in seminal vesicles. At the time of ejaculation they received a secretion from male ejaculatory duct that renders them motile. The dissociation of eupyrene bundles, eupyrene sperm motility and the sequence of events of sperm migration in both sexes are described in the present paper.

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GLOBAL STABILITY OF SOLUTIONS OF AN ELECTROCHEMISTRY MODEL WITH A SINGLE REACTION

  • Kim, Eu-Hee
    • Communications of the Korean Mathematical Society
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    • v.14 no.2
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    • pp.429-440
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    • 1999
  • In this paper an electrochemistry model which consists of three charged species is considered. A dissociation-association reaction is allowed to take place between these species. The species of ions diffuse owing to concentration gradients and migrate because of electric forces. We prove that any initial distribution of species concentrations will settle down to the unique steady state as time becomes large.

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Investigation of the Reaction Coordinate for Dissociation in $Cr(CO)_6$ Using Resonance Raman Spectroscopy

  • 유수창;고석범;J. B. Hopkins
    • Bulletin of the Korean Chemical Society
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    • v.16 no.11
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    • pp.1043-1045
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    • 1995
  • The overtone of the ν2 vibrational mode in Cr(CO)6 are observed for the first time in cyclohexane and methanol at both the 266 and 213 nm excitations. The appearance of the overtones due to the displacement of the electronic excited state with respect to the ground state along the ν2 vibrational mode is interpreted in terms of wavepacket concept and molecular orbital (MO) theory. Our Raman results suggest a new interpretation for the excited state potential.

Stabilization of Bioluminescence of Immobilized Photobacterium phosphoreum and Monitoring of Environmental Pollutants

  • Britz, Margaret L.;Nina Simonov;Chun, Uck-Han
    • Journal of Microbiology and Biotechnology
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    • v.7 no.4
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    • pp.242-249
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    • 1997
  • Stability of bioluminescence was investigated with Photobacterium phosphoreum immobilized on the strontium alginate in order to develope continuous real time monitoring of pollutants. The stability of bioluminescence emission was improved by prolonged aging time. The aging time of ${\geq}40$ min and the cell concentration of ${\leq}0.6\;of\;OD_660$ were selected for the immobilization of P. phosphoreum to give linearity between cell concentrations and bioluminescence intensity. In sensitivity tests using phenol, it was found that this compound quenched bioluminescence proportional to the concentration without lowering of cell growth. The lower value for maximum quenching ($q_s$) and higher dissociation constant ($K_s$) were observed with strontium-alginate immobilized cells compared to free cells. The response of bioluminescence to toxicants was evaluated with the immobilized luminescent bacteria. The sensitivity of the immobilized cells was found to be good in response to toxicants, 4-nitrophenol, salicylate and cadmium, when evaluated with a specific rate of bioluminescence quenching.

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Effects of Liquid Crystal Alignment on the Photopolymer based Poly[N-(phenyl)maleimide] (Poly[N-(phenyl)maleimide]계 광폴리머를 이용한 액정배향효과)

  • 황정연;서대식;김준영;이재호;김태호
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.14 no.10
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    • pp.845-849
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    • 2001
  • The new phto-alignment material PMI5CA, poly{N-(phenyl)maleimide-co-3-[4-(pentyloxy) cinamate]porpyl-2-hydroxy-1-methacrylate}, was synthesized and the electro-optical (EO)characteristics in the vertical-aligned(VA) liquid crystal display (LCD) photo-aligned on the photopolymer surface were studied. Excellent Voltage-transmittance(V-T) characteristics in the VA-LCD photoaligned with polarized UV exposure of oblique direction on the pohotopolymer surface for 1 min can be achieve. The transmittance of the VA-LCD photoaligned on the photopolymer surface decreased with increasing UV exposure time. We suggest that decrease of transmittance in the VA-LCD photoaligned on the photopolymer surface is attributed to the dissociation of the ester linkage in the photodimerized cinnamate structure with increasing UV exposure time.

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Properties of Sol-Gel Materials Containing Colloidal Silica Silane (콜로이드 실리카 실란을 함유한 졸겔반응 코팅제 특성연구)

  • Kang, Dong-Pil;Ahn, Myeong-Sang;Na, Moon-Kyong;Myung, In-Hye;Kang, Young-Taec
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.05b
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    • pp.33-36
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    • 2005
  • Colloidal Silica(CS)/silane sol solutions were prepared in variation with synthesizing parameters such as ratio of CS to silane and reaction time. In the case of LHSA CS/tetramethoxysilane(TMOS)/methyltrimethoxysilane(MTMS) CS/silane sol, coating film had stable contact angle with increasing reaction time excepting for 48hours. Also, the LHSA CS/TMOS/MTMS coating film had more enhanced flat surface with increasing the amount of MTMS and increasing reaction time. In the case of thermal stability, thermal dissociation of LHSA CS/MTMS sol did not occur up to $550^{\circ}C$.

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Liquid Crystal Aligning Capabilities on the Photopolymer Based Maleimide (Maleimide계 폴리머를 이용한 액정배향특성)

  • 이윤건;황정연;서대식;김준영;이재호;김태호
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11a
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    • pp.358-361
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    • 2001
  • A new photoalignment material PM15CA, poly{N-(phenyl)maleimide-co-3-[4-(pentyloxy) cinnamate]propyl-2-hydroxy-1-methacrylate}, was synthesized and the electro-optical (EO) characteristics in the vertical-aligned (VA) liquid crystal display (LCD) photo-aligned on the photopolymer surface were studied. Excellent voltage-transmittance(V-T) characteristics in the VA-LCD photoaligned with polarized UV exposure of oblique direction on the pohotopolymer surfaces for 1 min can be achieved. The transmittance of the VA-LCD photoaligned on the photopolymer surface decreased with increasing UV exposure time. We suggest that the decrease of transmittance in the VA-LCD photoaligned on the photopolymer surface is attributed to the dissociation of the ester linkage in the photodimerized cinnamate structure with increasing UV exposure time

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Experimental Study on Ultra-Violet Resistance of FRP composites used in Strengthening RC members (FRP 복합체의 자외선 저항성에 관한 실험적 연구)

  • Song, Tae-Hyeob;Choi, Ki-Sun;You, Young-Chan;Kim, Keung-Hwan
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.05b
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    • pp.333-336
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    • 2006
  • In general, polymer materials undergo degradation when exposed to ultraviolet radiation, which can cause dissociation of chemical bonds. FRP composites which are used in strengthening existing structure are usually adhered on the concrete surface, its mechanical properties as well as appearance such as color, surface conditions are affected by sunlight and expecially ultraviolet light. In this study, variations of tensile strength after exposure for certain period of time through accelerated exposure by Xe arc methods specified in KS F 2274 are measured in order to examine strength degradation characteristics of FRP composite. As a result of ultraviolet light test for FRP composite after accelerated exposure for 0, 500, 1000, 1500 hour, discoloration of FRP composite occurs according to the passage of time. But, few strength degradations of FRP composite are observed due to exposure of ultraviolet ray with an small variation of tensile strength.

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Homogeneous Catalysis (IV). Hydrogenation of Acrylonitrile with trans-Chlorocarbonylbis(triphenylphosphine)rhodium(I)

  • Woo, Jin-Chun;Chin, Chong-Shik
    • Bulletin of the Korean Chemical Society
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    • v.4 no.4
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    • pp.169-171
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    • 1983
  • It has been found that the acrylonitrile solution of trans-$RhCl(CO)(Ph_3P)_2$ produces propionitrile catalytically at $90^{\circ}C$ under $P_{H_2}$=3 atm. This catalytic hydrogenation proceeds only for a certain period of time producing ca. 50 moles of propionitrile per mole of the rhodium complex. The hydrogenation with trans-$RhCl(CO)(Ph_3P)_2$ in the presence of formaldehyde is much faster than in the absence of formaldehyde, and continues without a decrease in the rate for a prolonged period of time. It is suggested that the hydrogenation with trans-$RhCl(CO)(Ph_3P)_2$ proceeds through the unsaturated route initiated by the dissociation of CO from trans- $RhCl(CO)(Ph_3P)_2$ to give coordinatively unsaturated $RhCl(Ph_3P)_2$.

The morphological and immunohistochemical changes of endocrine pancreas by pancreatic duct ligation in chicken (췌관을 결찰한 닭 췌장 내분비부의 형태학적 및 면역조직화학적 변화)

  • Ku, Sae-kwang;Lee, Jae-hyun;Lee, Hyeung-sik
    • Korean Journal of Veterinary Research
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    • v.37 no.2
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    • pp.253-262
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    • 1997
  • To investigate morphological changes in the endocrine pancreas of chicken after pancreatic duct ligation, experimental animals were subdivided to control, 12 hours, 1 day, 2 days, 4 days, 7 days and 10 days groupes and all of three pancreatic ducts of chicken were ligated by surgical procedure and then the morphological changes were observed. In pancreatic islets, the vacuolation and invasion of connective tissue were occurred in all experimental groups and dissociation of pancreatic islets was detected in 4 days after pancreatic duct ligation and hold out to 10 days. The peak of the morphological changes in pancreatic islets was detected in 4 days after pancreatic duct ligation. In the results of immunohistochemical methods against glucagon, insulin, somatostatin and bovine pancreatic polypeptide(BPP), the number of immunoreactive pancreatic islets were decreased but the size increased with time, so the number of immunoreactive cells in each pancreatic islets were increased. Glucagon-immunoreactive cells were not changed but insulin-immunoreactive cells were decreased with time(p<0.05). BPP-immunoreactive cells were increased in 2 days after pancreatic duct ligation and then decreased with time(p<0.05). Somatostatin-immunoreactive cells were increased with time(p<0.05) in dark islets.

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