• 공업화학
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• 제20권3호
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• pp.322-328
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• 2009

Octamethylcyclotetrasiloxane (OMCTS)을 에멀젼 상태에서 초음파를 조사하여 polydimethylsiloxane (PDMS)을 중합하였다. 중합에 활용된 초음파 반응기는 주파수가 20 KHz의 horn 유형과 40 KHz의 bath 유형이었으며, horn과 bath를 혼용한 경우의 중합 공정의 특성도 평가해 보았다. 고려된 주요 변수들은 반응 온도와 초음파 조사 시간 이었으며, 중합물에 대하여 각 시료의 고유 점도와 전환율 측정을 통하여 각 중합공정의 효율성과 특성을 조사하고, 최적의 공정 조건을 도출해 보고자 하였다. Horn 유형의 반응기에서는 수 분 이내에 80% 이상의 전환율이 달성되고 높은 점도의 PDMS를 얻을 수 있었으나, 조사 시간에 따라 전환율과 점도는 최대값을 보인 이후에 감소하는 경향을 나타내었다. 초음파의 강도가 상대적으로 약하게 유지되는 bath 유형의 반응기에서는 1 h 이상의 조사가 필요하였으며, horn 유형과 달리 전환율과 점도가 조사 시간에 따라 지속적으로 증가하는 경향이 지배적이었다. Horn유형과 bath유형을 조합한 혼합형 반응기에서는 다른 반응기와는 매우 다른 결과들이 나타났으며, 각 반응기의 특성은 전산 모사를 이용한 반응기 내의 음파 해석을 바탕으로 설명되었다.

• 방사성폐기물학회지
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• 제16권4호
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• pp.411-420
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• 2018

공기 분위기하 $UO_2$의 독특한 산화거동을 모사하기 위해 기존 Crackling Core Model (CCM)을 개선하였다. $UO_2$가 $U_3O_8$으로 전환될 때 시간-전환율 곡선에서 나타나는 실험적 sigmoid 거동을 근사하게 재현할 수 있도록 모델 개선에 파편화 효과로 인한 반응 표면적 증대 및 결정립 가변 전환시간 개념을 고려하였다. $UO_2$는 $U_3O_7$을 거쳐 $U_3O_8$으로 전환되며 최종 결정립 산화소요 시간은 초기 결정립 산화 소요 시간의 10배에 해당한다는 가정을 도입했을 때, 개선된 모델은 599 - 674 K에서의 $UO_2$ 구형 입자의 실험적 산화거동과 근사한 계산결과를 나타내었으며 핵종성장모델(Nucleation and Growth Model) 및 자촉매반응모델(AutoCatalytic Reaction Model)과 비교할 때 가장 작은 오차를 보여주었다. 개선된 모델을 통해 $U_3O_8$으로의 100% 전환시 계산된 활성화에너지값은 $57.6kJ{\cdot}mol^{-1}$로 자촉매반응모델로 계산된 값인 $48.6kJ{\cdot}mol^{-1}$보다 크며, 외삽에 의해 결정된 실험값에 더 근사함이 밝혀졌다.

• Journal of Microbiology and Biotechnology
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• 제10권4호
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• pp.529-531
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• 2000

Giardia lamblia, a waterborne parasitic protozoa causing diarrhea and gastroenteritis, is transmitted to humans from untreated and treated water in the form of cysts. The ingestion of G. lamblia cysts is followed by the excystation of the cysts to trophozoites and subsequent colonization of the upper small intestine. In this study, the in vitro conditions for upper small intestine. In this study, the in vitro conditions for G. lamblia encystation were investigated to enhance the efficiency of cyst conversion and the resulting cyst density. The trophozoite of G. lamblia was cultivated to the late exponential growth phase, resulting in a high density of over $6{\times}10^7{\;}cells/ml$. The effects of pH, bile content, and induction time were evaluated; A cyst conversion of over 25% and 107 time were evaluated; A cyst conversion of over 25% and 107 cysts/ml were routinely obtained using the optimized encystation conditions including a slightly slkaline pH, 10 to 15 mg/ml of bile concentration, and 48-50 h of induction time.

• 한국수소및신에너지학회논문집
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• 제23권2호
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• pp.173-182
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• 2012

Effects of temperature, pressure, and gas residence time on methane combustion characteristics of mass produced oxygen carrier particle (OCN706-1100) were investigated in a pressurized fluidized bed reactor using methane and air as reactants for reduction and oxidation, respectively. The oxygen carrier showed high fuel conversion, high $CO_2$ selectivity, and low CO concentration at reduction condition and very low NO emission at oxidation condition. Moreover OCN706-1100 particle showed good regeneration ability during successive reduction-oxidation cyclic tests up to the 10th cycle. Fuel conversion and $CO_2$ selectivity decreased and CO emission increased as temperature increased. These results can be explained by trend of calculated equilibrium CO concentration. However, $CO_2$ selectivity increased as pressure increased and fuel conversion increased as gas residence time increased.

• Transactions on Electrical and Electronic Materials
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• 제8권6호
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• pp.250-254
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• 2007

Applying the moving photo-carrier grating(MPG) technique and time-of-flight(TOF) measurements, we studied the transport properties of stabilized amorphous selenium typical of the material used in direct conversion X-ray imaging devices. For MPG measurement, we obtained electron and hole mobility and the recombination lifetime of $\alpha-Se$ films with arsenic(As) additions. We found an apparent increase in hole drift mobility and recombination lifetime, especially when 0.3 % As was added into $\alpha-Se$ film, whereas electron mobility decreased with the addition of As due to the defect density. For TOF measurement, a laser beam with pulse duration of 5 ns and wavelength of 350 nm was illuminated on the surface of $\alpha-Se$ with a thickness of 400 ${\mu}m$. The measured hole and electron transit times were about 8.73 ${\mu}s$ and 229.17 ${\mu}s$, respectively.

• Macromolecular Research
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• 제17권8호
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• pp.575-579
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• 2009

Copolymerization of L-lactide and s-caprolactone initiated by tin (II) octoate (Sn(Oct)$_2$) was carried out in supercritical chlorodifluoromethane (R22) with varying reaction conditions (time and temperature) and amounts of monomer and catalyst, under a pressure of 250 bar. The optimum conditions were a reaction time of 10 h and a temperature of 130 $^{\circ}C$, which is similar to the temperature used in bulk copolymerization system. The conversion increased from 56% to 76% by increasing the reaction time from 1 to 10 h. The molecular weight also increased to 75,900 g.mol$^{-1}$ over the same period, while the increased monomer concentration resulted in a high molecular weight of 86,400 g.mol$^{-1}$ and a monomer conversion of 84%. Raising the reaction temperature from 90 to 130 $^{\circ}C$ increased the monomer conversion as well as the poly-L-lactide-co-${\varepsilon}$-caprolactone (PLCL) molecular weight. The variation on the stannous octoate catalyst suggested that less catalyst would decrease the caprolactone content of the polymer.

• 신재생에너지
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• 제19권4호
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• pp.11-19
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• 2023

Levulinic acid (LA) derived from cellulosic biomass, serves a crucial intermediate that can be used in various chemical conversions. This study focused on optimizing the production of LA using two types of pretreated rice husk (de-ashed and delignificated cellulosic biomass) in a batch reaction system through catalytic conversion with sulfuric acid. To determine the optimal conditions, the conversions of glucose and α-cellulose were examined to compare the effects of pretreatment on the rice husk. The experimental parameters covered a broad spectrum, including temperatures ranging from 140℃ to 200℃, a reaction time was up to 600 minutes, and a substrate to catalyst (acid solution) ratio of 100 g/L. The highest LA yield was 44.8%, achieved from de-ashed rice husk with 3.0 wt.% of sulfuric acid at 180℃ and with a reaction time of 180 minutes. In the case of the delignificated rice husk, a LA yield of 43.6% was obtained with 3.0 wt.% of sulfuric acid at 200℃ and with reaction time of 30 minutes.

• 한국환경과학회지
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• 제17권2호
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• pp.211-224
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• 2008

Characteristics of the esterification reaction between free fatty acid in rice bran oil and methanol was investigated in the presence of catalysts, such as PTS(p-toluene sulfonic acid), Amberlyst 15 dry and SCX(silica gel based strong cation exchange resin). While reaction temperature was kept constant at $65^{\circ}C$, initial feed content of free fatty acid was varied from 100% to 1% by addition of pure free fatty acid which was previously made from rice bran oil. Also, the effect of mole ratio of methanol to fatty acid on the final conversion was examined. When esterification of pure free fatty acid was catalyzed by several acids, final conversions were increased in order of Amberlyst 15 dry, SCX and PTS. Using PTS catalyst, initially the reaction proceeded in homogeneous 2nd oder reaction mechanism. However, phase of reaction mixture changed from homogeneous to heterogeneous along the reaction time and then reaction rate was retarded by mass transfer resistance of methanol. Final conversion of free fatty acid in reaction mixture was depended on initial feed content of free fatty acid, and had maximum value at 30% of initial feed free fatty acid content for all kinds of catalysts used. And the final conversion was increased with mole ratio of methanol by the improvement of reaction rate. When initial feed free fatty acid content below 10% and the reaction was catalyzed by PTS, concentration of free fatty acid in reaction mixture was increased in the middle of reaction time by hydrolysis of triglyceride in reaction mixture. Also, if silica gel was added into the reaction mixture which had initial feed free fatty acid content below 50%, final conversion was increased by the adsorption of moisture produced. The SCX catalyst made the esterification reaction of free fatty acid to progress like in case of PTS catalyst. However, when initial feed free fatty acid content below 10%, concentration of free fatty acid in. reaction mixture was decreased monotonically and not increased in the middle of reaction time on the contrary to the case of PTS. Thus, SCX catalyst accomplished more high value of final conversion than PTS catalyst for the initial feed fatty acid content range from 50% to 5% In case of initial feed free fatty acid content of 1% and mole ratio of methanol was 2, concentration of free fatty acid in reaction mixture increased over the initial feed free fatty acid content for all kind of catalysts used. Although SCX catalyst was added into reaction mixture which had 1% of initial feed fatty acid content, final conversion was hardly raised by mole ratio of methanol.

• 지능정보연구
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• 제4권2호
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• pp.23-34
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• 1998

Travel time forecasting, especially public bus travel time forecasting in urban areas, is a difficult and complex problem which requires a prohibitively large computation time and years of experience. As the network of target area grows with addition of streets and lanes, computational burden of the forecasting systems exponentially increases. Even though the travel time between two neighboring intersections is known a priori, it is still difficult, if not impossible, to compute the travel time between every two intersections. For the reason, previous approaches frequently have oversimplified the transportation network to show feasibilities of the problem solving algorithms. In this paper, forecasting of the travel time between every two intersections is attempted based on travel time data between two neighboring intersections. The time stamps data of public buses which recorded arrival time at predetermined bus stops was extensively collected and forecast. At first, the time stamp data was categorized to eliminate white noise, uncontrollable in forecasting, based on wavelet conversion. Then, the radial basis neural networks was applied to remaining data, which showed relatively accurate results. The success of the attempt was confirmed by the drastically reduced relative error when the nodes between the target intersections increases. In general, as the number of the nodes between target intersections increases, the relative error shows the tendency of sharp increase. The experimental results of the novel approaches, based on wavelet conversion and neural network teaming mechanism, showed the forecasting methodology is very promising.

• 한국산업정보학회:학술대회논문집
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• 한국산업정보학회 2003년도 추계공동학술대회
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• pp.145-156
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• 2003

This paper for real time object tracking in this treatise detect histogram analysis that is accumulation value of binary conversion density and edge information and body that move by real time use of difference Image techniques and proposed method to object tracking. Firstly, we extract edge that can reduce quantity of data keeping information about form of input image in object detection. Object is extracted by performing difference image and binarization in edge image. Area of detected object is determined by threshold value that divide sum of horizontal accumulation value about binary conversion density by value that add horizontalityㆍverticality maximum accumulation value. Object is tracked by comparing similarity with object that is detected in previous frame and present frame. As experiment result, proposed algorithm could improve the object detection speed, and could track object by real time and could track local movement.