• Title/Summary/Keyword: TiC Addition

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Study on Improvement of the Piezoelectric Properties of Acoustic Emission Sensor to be Used for Superconducting Application Systems (초전도 응용기기 안정성 진단을 위한 AE센서용 압전소자의 성능개선 연구)

  • Kim, K.J.;Kim, J.H.;Song, J.B.;Paik, J.H.;Jang, J.Y.;Ko, T.K.;Lee, H.G.
    • Progress in Superconductivity and Cryogenics
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    • v.12 no.3
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    • pp.44-48
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    • 2010
  • Acoustic emission (AE) signal from an HTS tape has a low signal to noise ratio, due to the large amount of noise caused by the boiling of the liquid cryogen or mechanical vibration from the cryo-cooler. In an attempt to improve the sensitivity of the AE sensor, $Pb(Zr_{0.54}Ti_{0.46})O_3$ + 0.2 wt% $Cr_2O_3$ + 1.0 wt.% $Nb_2O_5$ ceramics sintered at $1200^{\circ}C$ was synthesized. In addition, the resonance ($f_r$) and anti-resonance frequencies ($f_a$) were measured using the specimens with various thicknesses (1.0, 1.5, 2.0, 2.5 and 3.0 mm). According to the test results, large AE signals with high frequencies were obtained from the AE sensor fabricated using a piezoelectric disc with a thinner thickness.

Study on Preparation of Environment-Friendly Special Paper Using Functional Antibiotic Nano-Particle (I) (기능성 항균 나노입자를 이용한 친환경성 특수지 제조에 관한 연구(I))

  • Cho, Jun-Hyung;Lee, Yong-Won;Kim, Hyung-Jin;Lee, Jong-Man
    • Applied Chemistry for Engineering
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    • v.16 no.3
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    • pp.385-390
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    • 2005
  • In this study, nano sized colloidal Ag was made by using a seed sol method. Colloidal Ag solution was spouted on the surface of the inorganic pigment using the hybridizer system and spray nozzle. Then, the surface of the inorganic pigment was modified by $TiO_2$ to obtain the antibacterial ability. In the manufacturing process of nano sized colloidal Ag, it was confirmed that the size of particles increased by addition of $AgNO_3$ and increased the reaction time. The antibacterial measurement of the inorganic pigment showed that the growth of fungus decreased as the reaction time was increased. After the antibacterial ability appeared, in 5~7 h of the antibacterial inoculation experiment, it was measured that the antibacterial activity was excellent at a fixed time frame. The photodecomposition of benzene using $TiO_2$ as the photocatalyst showed 60~70% efficiency in about 80 min. reaction time. It was shown that more than 90% of this efficiency was achieved in the reaction time of about 30 min.

Electrochemical Properties of LiNi1-yMyO2(M=Zn2+, Al3+, and Ti4+) Synthesized by Milling and Solid-State Reaction Method (기계적 혼합과 고상법에 의해 합성한 LiNi1-yMyO2(M=Zn2+, Al3+, and Ti4+)의 전기화학적 특성)

  • Kim, Hunuk;Youn, SunDo;Lee, Jaecheon;Park, HyeRyoung;Song, Myoungyoup
    • Journal of the Korean Ceramic Society
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    • v.42 no.5 s.276
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    • pp.352-358
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    • 2005
  • By calcining at $750^{\circ}C$ for 30 h in $O_2$ stream after milling, $LiNi_{1-y}M_yO_2(M=Zn^{2+},\;Al^{3+}$, and $Ti^{4+}$, y = 0.005, 0.01, 0.025, 0.05, and 0.1) were synthesized and their electrochemical properties were investigated. All the samples had R3m structure. $LiNi_{1-y}Zn_yO_2$ (y = 0.025, 0.05, and 0.1) contained ZnO anuor $Li_2ZnO_2$ as impurities. Among the samples substituted with the same element, the samples with relatively large value of $I_{003}/I_{104}$ and the smallest R-factor had the largest first discharge capacity and good cycling performance. $LiNi_{0.975}A1_{0.025}O_2$ had the largest first discharge capacity (172.5 mAh/g) and good cycling performance (about $89.4\%$ of the first discharge capacity at the 20th cycle). This sample had the largest value of $I_{003}/I_{104}$ and the smallest R-factor among all the samples. In addition, the particles of this sample were finer and their size was more homogeneous than the other samples. $LiNi_{0.95}A1_{0.05}O_2$ had relatively large first discharge capacity 150.4 mAh/g and good cycling performance.

Copolymerization of Ethylene and Norbornene via Polymethylene Bridged Dinuclear Constrained Geometry Catalysts

  • Zhu, Yin-Bang;Jeong, Eung-Yeong;Lee, Bae-Wook;Kim, Bong-Shik;Noh, Seok-Kyun;Lyoo, Won-Seok;Lee, Dong-Ho;Kim, Yong-Man
    • Macromolecular Research
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    • v.15 no.5
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    • pp.430-436
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    • 2007
  • The dinuclear half-sandwich CGCs (constrained geometry catalyst) with a polymethylene bridge, $[Ti({\eta}^5 : {\eta}^1-indenyl)SiMe_2NCMe_3]_2(CH_2)_n]$[n = 6 (1) and 12 (2)], have been employed in the copolymerization of ethylene and norbornene (NBE). To compare the mononuclear metallocene catalysts; $Ti({\eta}^5 : {\eta}^1-2-hexylindenyl)SiMe_2NCMe_3$ (3), $(Cp^* SiMe_2NCMe_3)$Ti (Dow CGC) (4) and ansa-$Et(Ind)_2ZrCI_2$ (5), were also studied for the copolymerization of ethylene and NBE. It was found that the activity increased in the order: 1 < 2 < 3 < 5 < 4, indicating that the presence of the bridge between two the CGC units contributed to depressing the polymerization activity of the CGCs. This result strongly suggests that the implication of steric disturbance due to the presence of the bridge may playa significant role in slowing the activity. Dinuclear CGCs have been found to be very efficient for the incorporation of NBE onto the polyethylene backbone. The NBE contents in the copolymers formed ranged from 10 to 42%, depending on the polymerization conditions. Strong chemical shifts were observed at ${\delta}$42.0 and 47.8 of the isotactic alternating NBE sequences, NENEN, in the copolymers with high NBE contents. In addition, a resonance at 47.1 ppm for the sequences of the isolated NBE, EENEE, was observed in the $^{13}C-NMR$ spectra of the copolymers with low NBE contents. The absence of signals for isotactic dyad at 48.1 and 49.1 ppm illustrated there were no isotactic or microblock (NBE-NBE) sequences in the copolymers. This result indicated that the dinuclear CGCs were effective for making randomly distributed ethylene-NBE copolymers.

A Study on the Improvement of Tool's Life by Applying DLC Sacrificial Layer on Nitride Hard Coated Drill Tools (드릴공구의 이종질화막상 DLC 희생층 적용을 통한 공구 수명 개선 연구)

  • Kang, Yong-Jin;Kim, Do Hyun;Jang, Young-Jun;Kim, Jongkuk
    • Journal of the Korean institute of surface engineering
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    • v.53 no.6
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    • pp.271-279
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    • 2020
  • Non-ferrous metals, widely used in the mechanical industry, are difficult to machine, particularly by drilling and tapping. Since non-ferrous metals have a strong tendency to adhere to the cutting tool, the tool life is greatly deteriorated. Diamond-like carbon (DLC) is one of the promising candidates to improve the performance and life of cutting tool due to their low frictional property. In this study, a sacrificial DLC layer is applied on the hard nitride coated drill tool to improve the durability. The DLC coatings are fabricated by controlling the acceleration voltage of the linear ion source in the range of 0.6~1.8 kV. As a result, the optimized hardness(20 GPa) and wear resistance(1.4 x 10-8 ㎣/N·m) were obtained at the 1.4 kV. Then, the optimized DLC coating is applied as an sacrificial layer on the hard nitride coating to evaluate the performance and life of cutting tool. The Vickers hardness of the composite coatings were similar to those of the nitride coatings (AlCrN, AlTiSiN), but the friction coefficients were significantly reduced to 0.13 compared to 0.63 of nitride coatings. The drilling test were performed on S55C plate using a drilling machine at rotation speed of 2,500 rpm and penetration rate of 0.25 m/rev. The result showed that the wear width of the composite coated drills were 200 % lower than those of the AlCrN, AlTiSiN coated drills. In addition, the cutting forces of the composite coated drills were 13 and 15 % lower than that of AlCrN, AlTiSiN coated drills, respectively, as it reduced the aluminum clogging. Finally, the application of the DLC sacrificial layer prevents initial chipping through its low friction property and improves drilling quality with efficient chip removal.

The Electrode Characteristics of the Sintered AB5-type Metal Hydrogen Storage Alloy for Ni-MH Secondary Battery (Ni-MH 2차전지용 AB5계 수소저장합금의 소결에 따른 전극 특성)

  • Chang, Sang-Min;Park, Won;Choi, Seung-Jun;Noh, Hak;Choi, Jeon;Park, Choong-Nyeon
    • Transactions of the Korean hydrogen and new energy society
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    • v.7 no.2
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    • pp.157-164
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    • 1996
  • The AB5-type metal hydride electrodes using $(LM)Ni_{4.49}Co_{0.1}Mn_{0.205}Al_{0.205}$(LM : Lanthaniumrich Mischmetal) alloy powders(${\leq}200$mesh) which were coated with 25wt% copper in an acidic bath were prepared with or without addition of 10wt% PTFE as a binder. Prior to electrochemical measurements, the electrodes were sintered at $40^{\circ}C$ for 1 and 2hrs in vacuum with Mm(mischmetal) and sponge type Ti getters. The properties such as maximum capacity, cycle life and mechanical strength of the negative electrode have been investigated. The surface analysis of the electrode was also obtained before and after charge-discharge cycling using scanning electron microscope(SEM). From the observations of electrochemical behavior, it was found that the sintered electrode shows a lower maximum discharge capacity compared with non-sintered electrode but it shows a better cycle life. For the both electrodes with or without addition of PTFE binder, the values of mechanical strength were obtained, and their values increased with increasing sintering time. However, there is little difference of discharge capacity for both electrodes.

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Implementation of an Optimal SIMD-based Many-core Processor for Sound Synthesis of Guitar (기타 음 합성을 위한 최적의 SIMD기반 매니코어 프로세서 구현)

  • Choi, Ji-Won;Kang, Myeong-Su;Kim, Jong-Myon
    • Journal of the Korea Society of Computer and Information
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    • v.17 no.1
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    • pp.1-10
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    • 2012
  • Improving operating frequency of processors is no longer today's issues; a multiprocessor technique which integrates many processors has received increasing attention. Currently, high-performance processors that integrate 64 or 128 cores are developing for large data processing over 2, 4, or 8 processor cores. This paper proposes an optimal many-core processor for synthesizing guitar sounds. Unlike the previous research in which a processing element (PE) was assigned to support one of guitar strings, this paper evaluates the impacts of mapping different numbers of PEs to one guitar string in terms of performance and both area and energy efficiencies using architectural and workload simulations. Experimental results show that the maximum area energy efficiencies were achieved at PEs=24 and 96, respectively, for synthesizing guitar sounds with sampling rate of 44.1kHz and 16-bit quantization. The synthesized sounds were very similar to original guitar sounds in their spectra. In addition, the proposed many-core processor was 1,235 and 22 times better than TI TMS320C6416 in area and energy efficiencies, respectively.

Multi-Core Processor for Real-Time Sound Synthesis of Gayageum (가야금의 실시간 음 합성을 위한 멀티코어 프로세서 구현)

  • Choi, Ji-Won;Cho, Sang-Jin;Kim, Cheol-Hong;Kim, Jong-Myon;Chong, Ui-Pil
    • The KIPS Transactions:PartA
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    • v.18A no.1
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    • pp.1-10
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    • 2011
  • Physical modeling has been widely used for sound synthesis since it synthesizes high quality sound which is similar to real-sound for musical instruments. However, physical modeling requires a lot of parameters to synthesize a large number of sounds simultaneously for the musical instrument, preventing its real-time processing. To solve this problem, this paper proposes a single instruction, multiple data (SIMD) based multi-core processor that supports real-time processing of sound synthesis of gayageum which is a representative Korean traditional musical instrument. The proposed SIMD-base multi-core processor consists of 12 processing elements (PE) to control 12 strings of gayageum in which each PE supports modeling of the corresponding string. The proposed SIMD-based multi-core processor can generate synthesized sounds of 12 strings simultaneously after receiving excitation signals and parameters of each string as an input. Experimental results using a sampling reate 44.1 kHz and 16 bits quantization show that synthesis sound using the proposed multi-core processor was very similar to the original sound. In addition, the proposed multi-core processor outperforms commercial processors(TI's TMS320C6416, ARM926EJ-S, ARM1020E) in terms of execution time ($5.6{\sim}11.4{\times}$ better) and energy efficiency (about $553{\sim}1,424{\times}$ better).

Implementation of Multi-Core Processor for Beamforming Algorithm of Mobile Ultrasound Image Signals (모바일 초음파 영상신호의 빔포밍 알고리즘을 위한 멀티코어 프로세서 구현)

  • Choi, Byong-Kook;Kim, Jong-Myon
    • The KIPS Transactions:PartA
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    • v.18A no.2
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    • pp.45-52
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    • 2011
  • In the past, a patient went to the room where an ultrasound image diagnosis device was set, and then he or she was examined by a doctor. However, currently a doctor can go and examine the patient with a handheld ultrasound device who stays in a room. However, it was implemented with only fundamental functions, and can not meet the high performance required by the focusing algorithm of ultrasound beam which determines the quality of ultrasound image. In addition, low energy consumption was satisfied for the mobile ultrasound device. To satisfy these requirements, this paper proposes a high-performance and low-power single instruction, multiple data (SIMD) based multi-core processor that supports a representative beamforming algorithm out of several focusing methods of mobile ultrasound image signals. The proposed SIMD multi-core processor, which consists of 16 processing elements (PEs), satisfies the high-performance required by the beamforming algorithm by exploiting considerable data-level parallelism inherent in the echo image data of ultrasound. Experimental results showed that the proposed multi-core processor outperforms a commercial high-performance processor, TI DSP C6416, in terms of execution time (15.8 times better), energy efficiency (6.9 times better), and area efficiency (10 times better).

Implementation of Parallel Processor for Sound Synthesis of Guitar (기타의 음 합성을 위한 병렬 프로세서 구현)

  • Choi, Ji-Won;Kim, Yong-Min;Cho, Sang-Jin;Kim, Jong-Myon;Chong, Ui-Pil
    • The Journal of the Acoustical Society of Korea
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    • v.29 no.3
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    • pp.191-199
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    • 2010
  • Physical modeling is a synthesis method of high quality sound which is similar to real sound for musical instruments. However, since physical modeling requires a lot of parameters to synthesize sound of a musical instrument, it prevents real-time processing for the musical instrument which supports a large number of sounds simultaneously. To solve this problem, this paper proposes a single instruction multiple data (SIMD) parallel processor that supports real-time processing of sound synthesis of guitar, a representative plucked string musical instrument. To control six strings of guitar, we used a SIMD parallel processor which consists of six processing elements (PEs). Each PE supports modeling of the corresponding string. The proposed SIMD processor can generate synthesized sounds of six strings simultaneously when a parallel synthesis algorithm receives excitation signals and parameters of each string as an input. Experimental results using a sampling rate 44.1 kHz and 16 bits quantization indicate that synthesis sounds using the proposed parallel processor were very similar to original sound. In addition, the proposed parallel processor outperforms commercial TI's TMS320C6416 in terms of execution time (8.9x better) and energy efficiency (39.8x better).