• Transactions of the Korean hydrogen and new energy society
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• v.14 no.4
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• pp.327-334
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• 2003

경수소와 중수소를 사용하여 Ti1.0Mn0.9V1.1합금의 경우 313K와 353 K에서, $Ti_{1.0}Cr1.5V_{1.1}$합금의 경우 313 K와 338K에서 각각 수소 동위체 효과를 조사하였다. 합금의 결정구조, 각 상의 존재량, 격자상수 등은 Rietveld method에 의해 결정되었다. 두 합금 모두 용도에 관계 없이 중수소의 흡장량이 경수소에 비하여 많았고, 이들 합금의 수소 동위체 효과는 LaNis 합금에 비하여 대단히 크게 나타났다. 실험 온도 범위에서 $Ti_{1.0}Mn_{0.9}V_{1.1}$합금의 경수소화물은 중수소화물에 비하여 안정하였고, Ti1.0Cr1.5V1.7합금에 있어서는 중수소화물이 더욱 안정하였다. 또한 $Ti_{1.0}Cr_{1.5}V_{1.7}$합금이 $Ti_{1.0}Mn_{0.9}V_{1.1}$합금보다 많은 량의 경수소와 중수소를 흡장하였다.

• Transactions of the Korean hydrogen and new energy society
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• v.9 no.1
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• pp.31-37
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• 1998

The crystal structures, the lattice parameters and the characteristics of hydrogen storage at 303K has been investigated in the ternary alloys of Ti-Cr-V system. All of these alloys, in the range of this study, have shown a bcc structure. The hydrogen storage capacities and the effective hydrogen storage capacities of the alloys were strongly dependant on the composition ratio of Ti/Cr, showing their maximum values at the Ti/Cr ratio of about 0.75. It was also found that the lattice parameters of the alloys increased linearly with an increase of the Ti/Cr ratio. The differences in affinities to hydrogen and lattice parameters of pure metal states of the three elements have been adopted in oder to explain the Ti/Cr ratio dependance of the lattice parameter and hydrogen storage capacity of the alloys.

• Korean Journal of Materials Research
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• v.4 no.6
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• pp.669-680
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• 1994

Oxidation behaviour of TiAl intermetallic compounds with the addition of Cr, V, Si, Mo, or Nb was investigated at 900~$1100^{\circ}C$ under the atmospheric environment. The reaction products were examined by XRD, SEM equipped with WDX. The weight gain by continuous oxidation increased with the addition of Cr or V, but there was less weight gain when Mo, Si or Nb was added individually. he oxidation rate of Cr- or V-added TiAl was always larger than that of TiAI. However, oxidation rate of Si-, Mo- or Nb-added TiAl was almost same or smaller than that of TiAI. Thus, it is concluded that the addition of Cr or V did not improve the oxidation resistance, whereas the addition of Si, Mo or Nb improved the oxidation resistance. Oxides formed on TiAl with Mo, Si, and Nb were found to be more protective, resulting from the decrease in diffusion rate of the alloying elements and oxygen. Nb strengthened the tendency to form $AI_{2}O_{3}$ in the early stage of oxidation, due to the continuous $AI_{2}O_{3}$ layer formation and dense $Tio_{2}+AI_{2}O_{3}$ layer. According to the Pt-marker test of TiAI- 5wt%Nb, oxygen diffused mainly inward while oxides were formed on the substrate surface. Upon thermal cyclic oxidation at $900^{\circ}C$, it is shown that the addition of Cr or Nb improved the adherence of oxide scale to the substrate.

• Transactions of the Korean hydrogen and new energy society
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• v.9 no.3
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• pp.101-110
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• 1998

The change of hydrogen storage characteristics by substituting zirconium for a portion of titanium in Ti-Cr-V alloys has been studied. The zirconium substitution decreased the plateau pressure and hysteresis of the PC isotherm. However, it decreased the hydrogen storage capacity and increased slopping in PC isotherm by forming $Cr_2Zr$ phase. By modifying the composition ratio of titanium to chromium, thereby suppressing the formation of $Cr_2Zr$ phase, we got an alloy having very high hydrogen storage capacity. The heat treatment of the alloys improved the flatness of plateau very much without a decrease in the maximum and the effective hydrogen storage capacities.

• Transactions of the Korean hydrogen and new energy society
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• v.16 no.2
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• pp.122-129
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• 2005

The characteristics of hydrogen storage have been investigated in the Ti-Cr-Mo and Ti-Cr-V ternary alloys with bcc structure. The alloys were melted by arc furnace and remelted 4-5 times for homogeneity. The lattice parameters, microstructures and phases of the alloys were examined by SEM, EDX and XRD, and the Pressure-Composition isotherms of the alloys were measured. From these data the relationship of the maximum and effective hydrogen storage capacities vs. chemical composition, lattice parameter and the radius of tetrahedral site were analyzed and discussed. The results showed that all of these alloy, in the range of the this study, had mainly bcc solid solutions with small amount of Ti segregation due to a lower melting point of Ti compared with other elements. Lattice parameters of the alloys were very near to the atomic average values of lattice parameters of the constituent elements. It was also found that maximum hydrogen storage capacities of the Ti-Cr-Mo alloys increased with increasing Ti content and the radius of tetrahedral site but the effective hydrogen storage capacities decreased after showing the maximum. The hydrogen storage capacities of the Ti-Cr-V alloys were almost same even though the V contens were quite different from alloy to alloy and this could be attributed to the almost same Ti/Cr ratio of the alloys. The maximum effective hydrogen storage capacity of the Ti-Cr-Mo alloys was revealed at Ti content of about 40${\sim}$50 at% and radius of tetrahedral site of 0.43${\sim}$0.45 nm. The Ti-Cr-V alloys showed the hydrogen storage capacities of 3.0 wt% and effective hydrogen storage capacities of 1.5 wt%.

• Journal of Dental Rehabilitation and Applied Science
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• v.32 no.3
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• pp.194-201
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• 2016

Purpose: The purpose of this study was to evaluate of Zirconium Nitride (ZrN) coating on shear bond strength with denture base resin in Co-Cr and Ti-6Al-4V alloy. Materials and Methods: Co-Cr and Ti-6Al-4V alloy disks (10 mm in diameter, 2.5 mm in thickness; each other: n = 14) were prepared and divided with 2 groups each other by ZrN coating. After primer was applied to disks surface, denture base resin with diameter 6 mm, height 5 mm was bonded on metal disk surface. After surface roughness was measured by Profiler, shear bond strength was determined with Universal testing machine and analyzed with two-way ANOVA. The specimen surfaces and failure mode were examined using a scanning electron microscope. Results: ZrN coated groups showed significantly higher rough surface than non-coated groups (P < 0.05). Irrespective of alloy materials, shear bond strength of ZrN coated groups were lower than non-coated groups (P < 0.001). The scanning electron microscope (SEM) of ZrN coated groups showed mixed and adhesive fractures. Conclusion: ZrN coating weakened bonding strength between denture base resin and Co-Cr, Ti-6Al-4V alloy.

• Transactions of the Korean hydrogen and new energy society
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• v.18 no.3
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• pp.250-255
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• 2007

Hydrogen storage properties of $Ti_{0.32}Cr_{0.43-X}V_{0.25}M_X$($0{\leq}X{\leq}0.1$, M=Fe, Mn, Si) have been investigated. With varing of Mn content, the lattice parameter of the alloy was unchanged and similar to that of $Ti_{0.32}Cr_{0.43}V_{0.25}$ alloy. With increase of Fe, Si content, the lattice parameters of the BCC phases decreased. When the Fe content was 8 at%, the desorption plateau pressure increased to several atmospheres without decrease of the effective hydrogen storage capacity of the alloy. When the Mn content was 8 at%, the effective hydrogen storage capacity showed approximately 2.5 wt% without change in the desorption plateau pressure. With increase of Si content, hysteresis increased and hydrogen storage capacity decreased rapidly. A study was also made on how desorption temperature affected the usable hydrogen of the $Ti_{0.32}Cr_{0.35}V_{0.25}Mn_{0.08}$ alloy. The temperature was varied from 293 to 413 K, and the pressure from 5 to 0.002 MPa. The usable hydrogen of the alloy was 2.7 wt% when absorbed and desorbed at 293 K and 373 K., respectively. The heat of hydride formation of the alloy was approximately -35.5 kJ/mol $H_2$.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2015.05a
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• pp.78-79
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• 2015

PVD 공정에서 다성분으로 이루어진 나노복합 코팅을 형성하는 것은 원소들간의 합금화 문제로 인해 어렵다. 따라서 일반적으로 두 개 이상의 원소타겟 또는 멀티타겟을 이용한 PVD+PECVD 의 융합공정에 의해 제조된다. 하지만 멀티타겟을 사용한 공정은 공정의 복잡화가 뒤따르며 신뢰성이 떨어진다. 본 연구에서는 멀티타겟의 단점을 보완하기 위해 Ti-Al-X(Cr, Si, B, V) 단일 합금 타겟을 제작하여 나노복합 코팅을 형성하고자 하였다. 기계적 합금화법을 통해 합금분말을 제조하였으며, 방전플라즈마소결법으로 합금 타겟을 제작하였다. 제작된 타겟을 이용하여 스퍼터링 장치를 통해 박막을 형성 하였다. 그 결과 분말은 밀링 시간 20시간에서 정상상태에 도달하였으며, 더 이상 분말의 입자는 줄어들지 않았다. 이때 분말의 입자크기는 $5{\sim}6{\mu}m$ 이었으며 결정립의 크기는 16~20nm 이었다. 소결을 통해 99% 이상의 진밀도를 갖는 합금타겟을 제작하였으며, 이때 결정립의 크기는 매우 미세하였다. 박막의 경우 모두 30GPa 이상의 고경도 특성을 나타냈다.

• Transactions of the Korean hydrogen and new energy society
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• v.18 no.1
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• pp.52-59
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• 2007

We investigated the effects of the addition of Mn and $AB_5$ type alloy on the electrochemical characteristics of Ti-Cr-V BCC type alloys as anode materials for Ni-MH battery. The activation behavior and discharge capacity of the BCC type alloys were significantly improved by ball-milling with the $LmNi_{4.1}Al_{0.25}Mn_{0.3}Co_{0.65}$ alloy, because the $AB_5$ type alloy acted as hydrogen path on the surface of the BCC type alloy. Among the Mn substituted alloys($Mn=0.03%{\sim}0.08%$), the $Ti_{0.32}Cr_{0.38}Mn_{0.05}V_{0.25}$ alloy ball-milled with $AB_5$ type alloy exhibited the greatest discharge capacity of $336\;mAh{\cdot}g^{-1}$. In addition, Mn substituted alloys exhibited the lower plateau pressure in P-C- T curve, the better hydrogen storage capacity and faster surface activation compared with the alloy without Mn.

• Proceedings of the Materials Research Society of Korea Conference
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• 2002.05a
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• pp.19-19
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• 2002