• Title/Summary/Keyword: Through Pore

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The Pore-filling Effect of Bulk Graphite According to Viscosity of Impregnant (함침재의 점도에 따른 벌크흑연의 기공 채움 효과)

  • Lee, Sang-Min;Lee, Sang-Hye;Roh, Jae-Seung
    • Korean Journal of Materials Research
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    • v.31 no.2
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    • pp.101-107
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    • 2021
  • Pores produced by carbonization in bulk graphite process degrade the mechanical and electrical properties of bulk graphite. Therefore, the pores of bulk graphite must be reduced and an impregnation process needs to be performed for this reason. In this study, bulk graphite is impregnated by varying the viscosity of the impregnant. The pore volume and pore size distribution, according to the viscosity of the impregnant, are analyzed using a porosimeter. The total pore volume of bulk graphite is analyzed from the cumulative amount of mercury penetrated. The volume for a specific pore size is interpreted as the amount of mercury penetrating into that pore size. This decreases the cumulative amount of mercury penetrating into the recarbonized bulk graphite after impregnation because the viscosity of the impregnant is lower. The cumulative amount of mercury penetrating into bulk graphite before impregnation and after three times of impregnation with 5.1cP are 0.144 mL/g and 0.125 mL/gm, respectively. Therefore, it is confirmed that the impregnant filled the pores of the bulk graphite well. In this study, the impregnant with 5.1 cP, which is the lowest viscosity, shows the best effect for reducing the total pore volume. In addition, it is confirmed by Raman analysis that the impregnant is filled inside the pores. It is confirmed that phenolic resin, the impregnant, exists inside the pores through micro-Raman analysis from the inside of the pore to the outside.

Behavior of Cadmium, Zinc, and Copper in Soils -II. Effect of Organic Matter Treatment on Mobility of Cadmium, Zinc, and Copper in Soils- (토양내(土壤內) 카드뮴 아연(亞鉛) 및 구리의 행동(行動)에 관한 연구(硏究) -II. 토양내(土壤內) 카드뮴 아연(亞鉛) 및 구리의 이동(移動)에 미치는 유기물처리(有機物處理)의 영향(影響)-)

  • Yoo, Sun-Ho;Hyun, Hae-Nam
    • Applied Biological Chemistry
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    • v.28 no.2
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    • pp.76-81
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    • 1985
  • Miscible displacement techniques were used to investigate the influence of the organic matter treatment on the mobility of Cd, Zn, and Cu through soil columns. The heavy metals moved most readily through the Bonryang soil (Typic Udifluvents) of relatively low in CEC, pH, and organic matter content. Most parts of Cd and Zn eluted within 7 pore volumes, but Cu eluted between 5 and 15 pore volumes. Although the Gangseo soil (Aquatic Eutrochrepts) had lower in CEC and organic matter content than the Gyorae soil (Typic Distrandepts), the heavy metals moved faster through the Gyorae soil than through the Gangseo soil. Cu eluted more slowly and in smaller quantities than Cd and Zn from the Bonryang soil, but did not eluted from the Gangseo and the Gyorae soils at all during the experimental period. The motility of the heavy metals from the Bonryang and the Gangseo soils was in the order of Cd>Zn>Cu, but that of the Gyorae soil was in the order of Zn>Cd>Cu. Cd and Zn eluted after 5 and 20 pore volumes respectively, from the Bonryang soil treated with 3% compost but Cu did not elute even after 30 pore volumes were collected. By 7% compost treatment only small amountssof Cd eluted after 20 pore volumes. The liming of the Bonryang soil retarded the mobility of Cd, Zn, and Cu. Humic acid treatment did not reduce the motility of the Cd and Zn to the extent observed in the Bonryang soil with compost, but reduced a little motility of Cu.

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A Study on the Drinking Water Treatment by Precoat Filtration and Activated Carbon Adsorption Process (규조토여과 및 활성탄흡착 공정을 이용한 용수처리에 관한 연구)

  • Shin Dae-Yewn;Kim Ji-Yeoul;Ji Sung-Nam
    • Journal of Environmental Health Sciences
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    • v.30 no.5 s.81
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    • pp.402-409
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    • 2004
  • I performed the research about the drinking water treatment by precoat filtration and activated carbon adsorption process in the D water treatment plant at Gwangju. D water treatment plant inlet water is supplied from Juam lake in Jeollanamdo. The results are as follows; 1. Element disk used in this experiment are R(pore size $10{\mu}m$), B(pore size $20{\mu}m$). And diatomaceous earth are A(cake pore size $3.5{\mu}m$), B(cake pore size $7{\mu}m$) and C(cake pore size $17{\mu}m$) 2. Filtrate of precoat filter during 30 min are B-C 10.2 > BB 5.7 > R-A 5.4 ($m^3/m^2$). 3. The water quality through B-C+AC and R-A+AC are DOC 1.76 mg/1, 1.288 m/l respectively. 4. total THMs produced by chlorination are $84.2{\mu}g/l$(B-C+AC), $66.11{\mu}g/l$ (R-A+AC), $97{\mu}g/l$ (rapid sand filtration water) respectively. 5. The R-A+AC and B-C+AC process can be substitute of CWTS.

Coupled analysis for the influence of blasting-induced vibration on adjacent dam (발파하중이 인접 댐에 미치는 진동영향에 대한 연계해석적 검토)

  • Park, Inn-Joon;Kim, Sung-In;Nam, Kee-Chun;Kwak, Chang-Won
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.6 no.1
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    • pp.41-50
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    • 2004
  • The numerical investigation for the effects of blasting-induced vibration on adjacent dam and pore water pressure fluctuation was conducted through solid-water coupled analysis under dynamic loading. The stability of dam was examined by peak particle velocity of core. Pore water pressure distributions were calculated by steady state flow analysis using coupled analysis on ground water and blasting-induced vibration. The influence of pore water pressure and the effective stress distribution in the ground were also investigated. Furthermore, effective stress alteration was examined by applying Finn & Byrne Model to monitor the generation and dissipation of pore water pressure.

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Characteristics of failure surfaces induced by embankments on soft ground

  • Hong, Eun-Soo;Song, Ki-Il;Yoon, Yeo-Won;Hu, Jong-Wan
    • Geomechanics and Engineering
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    • v.6 no.1
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    • pp.17-31
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    • 2014
  • This paper investigates the development of failure surfaces induced by an embankment on soft marine clay deposits and the characteristics of such surfaces through numerical simulations and its comparative study with monitoring results. It is well known that the factor of safety of embankment slopes is closely related to the vertical loading, including the height of the embankment. That is, an increase in the embankment height reduces the factor of safety. However, few studies have examined the relationship between the lateral movement of soft soil beneath the embankment and the factor of safety. In addition, no study has investigated the distribution of the pore pressure coefficient B value along the failure surface. This paper conducts a continuum analysis using finite difference methods to characterize the development of failure surfaces during embankment construction on soft marine clay deposits. The results of the continuum analysis for failure surfaces, stress, displacement, and the factor of safety can be used for the management of embankment construction. In failure mechanism, it has been validated that a large shear displacement causes change of stress and pore pressure along the failure surface. In addition, the pore pressure coefficient B value decreases along the failure surface as the embankment height increases. This means that the rate of change in stress is higher than that in pore pressure.

Fabrication of Nanoporous Alumina Membrane by High- Field Anodization (고전계 전기산화에 의한 나노다공성 알루미나 멤브레인의 제조)

  • Kim, Min-Woo;Hyun, Sang-Cheol;Ha, Yoon-Cheol
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.03b
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    • pp.45-45
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    • 2010
  • Nanoporous anodic alumina membranes (NAAM) with high aspect ratio, self-ordered pore array were fabricated by high-field 2-step anodization method. High voltages of 80, 100, 120 and 140 V as well as 40 V for comparison were applied to an aluminum anode with respect to a Pt cathode immersed both in 0.3M oxalic acid solution in order to investigate the self-ordering characteristics of the nanoporous structure. The pore structures, including interpore distance, pore size, pore density, and porosity as well as the ordering characteristic were analyzed using field-enhanced scanning electron microscopy (FE-SEM) and the corresponding Fourier-transformed images. The nanoporous structure could be produced for all the voltage conditions, but the well-ordered through-hole pore without a branched structure seemed to occur only at 40 and 140 V. It turned out that the growth rate under 140 V high-field anodization was about 40 times higher than under conventional 40 V mild anodization, which enabled the fast fabrication of self-ordered, high aspect ratio NAAMs.

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Dehydration and pore swelling effects on the transfer of PEG through NF membranes

  • Escoda, Aurelie;Bouranene, Saliha;Fievet, Patrick;Deon, Sebastien;Szymczyk, Anthony
    • Membrane and Water Treatment
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    • v.4 no.2
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    • pp.127-142
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    • 2013
  • In order to investigate the significance of "salting-out" and "pore swelling" effects on the nanofiltration of neutral solutes, rejection properties of two NF ceramic and polymeric membranes were studied with single polyethyleneglycol (PEG) solution and mixed PEG/inorganic electrolyte solutions. For both membranes, the rejection rate of PEG was found to decrease significantly in the presence of ions. In the case of the ceramic membrane (rigid pores), this phenomenon was imputed to the sole partial dehydration of PEG molecules induced by the surrounding ions. This assumption was confirmed by the lowering of the PEG rejection rates which followed the Hofmeister series. Experimental data were used to compute the resulting decrease in the Stokes radius of PEG molecules in the presence of the various salts. Concerning the polymeric membrane, the decrease in the rejection rate was found to be systematically higher than for the ceramic membrane. The additional decrease was then ascribed to the swelling of the pores. The experimental data of rejection rates were then used to compute the variation in the mean pore radius in the presence of the various salts. The pore swelling phenomenon due to accumulation of counterions inside pores was supported by electrokinetic charge density measurements.

Effect of Water and Aluminum Sulfate Mole Ratio on Pore Characteristics in Synthesis of AlO(OH) Nano Gel by Homogeneous Precipitation (균일침전에 의한 AlO(OH) 나노 겔 합성에서 물/황산알루미늄의 몰 비가 세공특성에 미치는 영향)

  • Choe, Dong-Uk;Park, Byung-Ki;Lee, Jung-Min
    • Journal of the Korean Ceramic Society
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    • v.43 no.9 s.292
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    • pp.564-568
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    • 2006
  • AlO(OH) nano gel is used in precursor of ceramic material, coating material and catalyst. For use of these, not only physiochemical control for particle morphology, pore characteristic and peptization but also studies of synthetic method for preparation of advanced application products were required. In this study, AlO(OH) nano gel was prepared through the aging and drying process of aluminum hydroxides gel precipitated by the hydrolysis reaction of dilute NaOH solution and aluminum sulfate solution. In this process, optimum synthetic condition of AlO(OH) nano gel having excellent pore volume as studying the effect of water and aluminum sulfate mole ratio on gel precipitates has been studied. Water and aluminum sulfate mole ratio brought about numerous changes on crystal morphology, surface area, pore volume and pore size. Physiochemical properties were investigated as using XRD, TEM, TG/DTA, FT-IR, and $N_2$ BET method.

Staged Finite Element Modeling with Coupled Seepage and Stress Analysis

  • Lee, Jae-Young
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.23 no.6
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    • pp.703-714
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    • 2010
  • This paper proposes an approach for staged finite element modeling with coupled seepage and stress analysis. The stage modeling is based on the predefined inter-relationship between the base model and the unit stage models. A unit stage constitutes a complete finite element model, of which the geometries and attributes are subject to changes from stage to stage. The seepage analysis precedes the mechanical stress analysis at every stage. Division of the wet and dry zone and the pore pressures are evaluated from the seepage analysis and used in determining input data for the stress analysis. The results of the stress analysis may also be associated with the pore water pressures. For consolidation analysis, the pore pressure and the displacement variables are mixed in a coupled matrix equation. The time marching solution produces the dissipation of excess pore pressure and variation of stresses with passage of time. For undrained analysis, the excess pore pressures are computed from the stress increment due to loading applied in the unit stage and are used in revising the hydraulic head. The solution results of a unit stage are inherited and accumulated to the subsequent stages through the relationship of the base model and the individual unit stages. Implementation of the proposed approach is outlined on the basis of the core procedures, and numerical examples are presented for demonstration of its application.

An Experimental Study on the Characteristics of Microporous Structure Formation by Curing Condition of Cement and Blast Furnace Slag Composite (시멘트 및 고로슬래그 경화체의 양생환경에 따른 미세 공극구조 형성 특성에 관한 실험적 연구)

  • Park, Cheol;Jung, Yeon-Sik;Seo, Chee-Ho
    • Journal of the Architectural Institute of Korea Structure & Construction
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    • v.33 no.12
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    • pp.63-70
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    • 2017
  • When industrial by-products like slag and fly ash are using in concrete with cement, it improves strength and durability against external deterioration factors by densifying the structure through potential hydraulic and pozzolanic reaction. But it has been pointed out that high dependence on the quality variation and the curing condition using a admixure material for concrete. In this study, the characteristics of internal micropore structure according to curing condition were analyzed for pastes and mortar specimens under using blast furnace slag powder. As a result, the variation of compressive strength and the internal microstructure were observed according to curing conditions by binder type. Particularly, using blast furnace slag powder, decrease in compressive strength were clearly observed in indoor and carbonation curing compared with water curing. The pore structure analysis also clearly observed the decrease of the gel pore existing in the CSH hydrate layer and the increase of the capillary pore in indoor and carbonation curing compared with water curing condition.