• 대한화학회지
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• 제11권2호
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• pp.70-76
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• 1967

Structural changes attending polyacrylonitrile(PAN) upon heating and treating with nucleophilic reagents have been studied for some time and a few authors have studied on the thermal degradation, particularly on the characterization of degradation products in PAN. It is the purpose of this paper to report the kinetic study on the thermal degradation above $250^{\circ}C$ and make some suggestions as to the degradation process and mechanism in PAN. The degradation process in PAN is considered that three reactions are combined in two steps. Random chain scission accompanying the naphthylidine-type ring formation is the first step and the degradation of naphthylidine-type ring occurred as the next step. The reactions in the first step are competitive so that the maximum weight loss on pyrolysis of PAN, under such a condition that the degradation of naphthylidine-type ring is negligible, is depended on the relative reaction rate of these two competitive reactions.

• 한국표면공학회지
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• 제53권4호
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• pp.144-152
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• 2020

In the manufacturing process of joining of aluminum alloy and polymer, the strength of the metal-polymer joining is greatly influenced by the nanostructure of the oxide film. In this study, we investigated the dependence of joining strength on the thickness, structure, pore formation and surface roughness of the formed film. After the two-step anodization process, the surface oxide layer became thinner and rougher resulting in higher joining strength with the polymer. More specifically, after the two-step anodization, the surface roughness, Ra increased from 2.3 to 3.2 ㎛ with pore of three-dimensional (3D) nanostructure, and the thickness of the oxide film was thinned from 350 to 250 nm. Accordingly, the joining strength of the aluminum alloy with polymer increased from 23 to 30 MPa.

• 대한전자공학회논문지TC
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• 제37권7호
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• pp.9-17
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• 2000

마이크로셀 구조에서 효율적으로 핸드오프와 채널 할당을 수행하기 위하여 이동체의 위치 및 속도를 추정 하는 것이 중요한 문제로 대두되고 있다. 이전 연구에서, 마이크로셀 환경에서 응용할 수 있는 이동체의 위치 추정 방법을 제안했다. 제안된 방법은 탐색 지역을 단계적으로 좁혀서 이동체가 위치한 지역을 결정하는 3단계 위치 추정 방법에 근거한다. 3단계 위치 추정 방법을 사용하여, 섹터 추정 단계에서 섹터를 추정하고, 트랙 추정 단계에서는 트랙을, 최종적으로 블럭 추정 단계에서 이동체가 위치한 블럭을 추정한다. 그러나 이 방법은 이동체가 섹터나 트랙의 경계 지점에 위치할 경우 추정의 정확도가 감소되는 문제점이 있다. 본 연구에서는 가상구역 개념을 이용하여, 경계 지역에 있는 이동체에 대한 추정 오류율을 줄일 수 있는 위치추정 방법을 제안한다.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2008년도 추계학술대회 논문집 Vol.21
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• pp.152-152
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• 2008

Micro probe with Ni-Co tip was designed. Unit processes for fabricating the micro probe were developed. We are investigated the micro probe tip using by Ni-Co alloy. One-step and three-step needle was fabricated by plating process, CMP, and photolithography process. The plating thickness was varied by current density and time. Futher data will be extract by different process conditions.

• Journal of Photoscience
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• 제9권2호
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• pp.130-133
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• 2002

The last step in the photocycle of photoactive yellow protein (PYP) is a spontaneous recovery of the dark state from the active state in which the p-coumaric acid chromophore is thermally isomerized, concomitantly with the deprotona- tion of the chtomophore and the refolding of the protein moicty. For the purpose of understanding the mechanism of the thermal back-isomerization, we have investigated the rate-determining step by analyzing mutant PYPs of Met100, which was previously shown to play a major role in facilitating the reaction (1). The mutation to Lys, Leu, Ala, or Glu decelerated the dark state recovery by 1 to 3 three orders of magnitude. By evaluating temperature-dependence and pH-dependence of the kinetics of the dark state recovery, it was found that the retardation by mutations resulted from elevation of the activation enthalpy ( H$\^$┿/) and that the pKa of the chromophore, which was affected by the mutation, is in a linier correlation with the amplitude of the rate constants. It was, therefore, deduced from the correlation that the free energy for crossing the activated state in the dark recovery process is proportional to the free energy for the deprotonation of the chromophore, identifying the rate-determining step as the deprotonation of the chromophore. (1) Devanathan, S. Genick, U. K. Canestrelli, I. L. Meyer, T. E. Cusanovich, M. A. Getzoff, E. D. Tollin, G., Biochemistry 1998, 37, 11563 - 11568

• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 2000년도 춘계학술대회 논문집
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• pp.944-947
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• 2000

Sculptured surface machining plays a vital role in the process of bring new products to the market place. A great variety of products rely on this technology for the production of the dies and moulds used in manufacturing. And, the use of CNC machines and CAD/CAM system has become a vital parts of product development process. The propose of this study is to investigate the effect of cutting parameters on the machinability such as surface roughness and cusp generated in the machining of sculptured surface on a three-axis CNC machining center using the CAD/CAM system. Experimental result showed that: In step down cutting, as the inclined angle of surface became smaller, the cusp height appeared higher. On the other hand, in step over cutting, as the inclined angle of surface became larger, the cusp height appeared higher. In the point of precision machining, step over cutting was more effective. For the minimization of cusp height, step down cutting was effective in larger inclined surface, but step over cutting in smaller inclined surface.

• 한국염색가공학회지
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• 제10권3호
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• pp.10-19
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• 1998

This paper investigates the change of mechanical properties and thermal shrinkage in commercial multi-filament PET(polyethylene terephthalate) , namely, regular yarn, POY, DTY and composite yarn. To determine changing the effects of processing steps, these were examined at three steps process simulation conditions. The first step is sizing simulation$(S-1\;step\;:\;130^\circ{C}\times2\;min$., hot air treatment under 0.1 gf/d load), the second step is scouring simulation$(S-2\;step\;:\;100^\circ{C}\times20\;min$., boiling water treatment under free tension)and final step is setting simulation$(S-3\;step\;:\;180^\circ{C}\times2\;min$., hot air treatment under free tension). Regular yarn in multi-step treatment showed higher shrinkage at S-3 step and DTY showed higher in at S-1 step. While POY was relaxed at S-1 step, composite yarn showed different shrinkage properties depending on composite yarn type. Mechanical properties showed good relationship with shrinkage : high shrinkage makes initial modulus decrease and bleating strain increase. It also makes decreasing yield strain and yield stress decrease.

• 한국전자거래학회지
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• 제3권1호
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• pp.1-22
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• 1998

SDAI (Standard Data Access Interface) is an interface specification of accessing various storage systems such as file systems and database management systems for STEP data. Using SDAI, both application program developers and CAD/CAM system developers can be relieved from dealing with STEP physical file or system dependent DBMS operations. In this paper, we present implementations of SDAI on different data models, i.e., relational, extended relational, and object-oriented. In order to implement SDAI, we need to translate the EXPRESS information model into target data models. The schema translation process for three different data models are compared and other implementation issues are discussed.

• 한국정밀공학회지
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• 제21권4호
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• pp.109-119
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• 2004

Rapid prototyping (RP) technologies have been widely used to reduce the lead-time and development cost of new products. $VLM-_{ST}$ process has been developed to overcome the currently developed RP technologies such as a large building time, a high building cost, an additional post-processing and a large apparatus cost. $VLM-_{ST}$ process requires an additional human interaction due to the manual stacking and bonding. Hence, building time, building cost and the part quality are dependent on the skill of labor. A novel RP process, fully automated $VLM-_{ST}$ process ($VLM-_{ST}$), has been developed to improve building efficiency of the process and the human dependency of the part. The objective of this work is to propose a $VLM-_{ST}$ process and to develop an apparatus for implementation of the process. $VLM-_{ST}$ process and its apparatus have various technical novelties such as two step cutting using a rotating table, an automatic stacking method using two pilot holes and two reference shapes, a concept of automatic unit shape layer (AUSL), and an automatic bonding using the bonding roller and building magazine. In order to examine the efficiency and the applicability of the proposed process, various three-dimensional shapes, such as a piston, a human head shape and a human bust shape, were fabricated on the apparatus.

• 한국경영과학회:학술대회논문집
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• 한국경영과학회 2006년도 추계학술대회
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• pp.373-376
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• 2006

In general, there are three kinds of methods in analyzing dynamic robust design experiment: loss model approach, response function approach, and response model approach. In this talk, we review the three modeling approaches in terms of several criteria in comparison. This talk also generalizes the response model approach based on a generalized linear model. We develop a generalized two-step optimization procedure to substantially reduce the process variance by dampening the effect of both explicit and hidden noise variables. The proposed method provides more reliable results through iterative modeling of the residuals from the fitted response model. The method is compared with three existing approaches in practical examples.