• Bulletin of the Korean Chemical Society
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• v.18 no.9
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• pp.1017-1021
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• 1997

Solvolyses of p-methoxyphenyl chloroformate in water, D2O, CH3OD, 50% D2O-CH3OD, and in aqueous binary mixtures of acetone, ethanol and methanol are investigated at 25.0 ℃. Product selectivities are reported at 25 ℃ for a wide range of ethanol-water and methanol-water solvent compositions. The Grunwald-Winstein plots of first-order rate constants for p-methoxyphenyl chloroformate with YCl (based on 1-adamantyl chloride) show marked dispersions into three separate curves for the three aqueous mixtures with a small m value and a rate maximum for aqueous alcohol solvents. Third-order rate constants, kww, kaw, kwa and kaa were calculated from the observed kww and kaa values together with kaw and kwa calculated from the intercept and slope of the plot of 1/S vs. [alcohol]/[water]. The calculated rate constants, kcalc and mol % of ester agree satisfactorily with those of the observed rate constants, kobs and mol % of ester, supporting the stoichiometric solvation effect analysis. The kinetic solvent isotope effects determined in water and methanol are consistent with the proposed mechanism of the general base catalyzed carbonyl addition-elimination.

• Geomechanics and Engineering
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• v.17 no.4
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• pp.385-392
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• 2019

The present fractional-order plasticity models for granular soil are mainly established under the triaxial compression condition, due to its difficult in analytically solving the fractional differentiation of the third stress invariant, e.g., Lode's angle. To solve this problem, a three dimensional fractional-order elastoplastic model based on the transformed stress method, which does not rely on the analytical solution of the Lode's angle, is proposed. A nonassociated plastic flow rule is derived by conducting the fractional derivative of the yielding function with respect to the stress tensor in the transformed stress space. All the model parameters can be easily determined by using laboratory test. The performance of this 3D model is then verified by simulating multi series of true triaxial test results of rockfill.

• Advances in concrete construction
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• v.6 no.6
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• pp.585-610
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• 2018

In this study, vibration analysis of a concrete foundation-reinforced by $SiO_2$ nanoparticles resting on soil bed is investigated. The soil medium is simulated with spring constants. Furthermore, the Mori-Tanaka low is used for obtaining the material properties of nano-composite structure and considering agglomeration effects. Using third order shear deformation theory or Reddy theory, the total potential energy of system is calculated and by means of the Hamilton's principle, the coupled motion equations are obtained. Also, based an analytical method, the frequency of system is calculated. The effects of volume percent and agglomeration of $SiO_2$ nanoparticles, soil medium and geometrical parameters of structure are shown on the frequency of system. Results show that with increasing the volume percent of $SiO_2$ nanoparticles, the frequency of structure is increased.

• Journal of the Korean Society for Industrial and Applied Mathematics
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• v.23 no.3
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• pp.211-236
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• 2019

This paper is devoted to the study and investigation of the Runge-Kutta discontinuous Galerkin method for a system of differential equations consisting of two hyperbolic conservation laws. The numerical coupling flux which is used at a given interface (x = 0) is the upwind flux. Moreover, in the linear case, we derive optimal convergence rates in the $L_2$-norm, showing an error estimate of order ${\mathcal{O}}(h^{k+1})$ in domains where the exact solution is smooth; here h is the mesh width and k is the degree of the (orthogonal Legendre) polynomial functions spanning the finite element subspace. The underlying temporal discretization scheme in time is the third-order total variation diminishing Runge-Kutta scheme. We justify the advantages of the Runge-Kutta discontinuous Galerkin method in a series of numerical examples.

• Structural Engineering and Mechanics
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• v.70 no.1
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• pp.97-112
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• 2019

Using the classical, first order and third order shear deformation plates theories the motion equations of an undrained porous FG circular plate which is located on visco-Pasternak elastic foundation have been derived and used for free vibration analysis thereof. Strains are related to displacements by Sanders relationship. Fluid has saturated the pores whose distribution varies through the thickness according to three physically probable given functions. The equations are discretized and numerically solved by the generalized differential quadrature method. The effect of porosity, pores distribution, fluid compressibility, viscoelastic foundation and aspect ratio of the plate on its vibration has been considered.

• Communications of the Korean Mathematical Society
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• v.37 no.4
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• pp.1009-1023
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• 2022

The main objective of this work is to investigate the study of the local and semi-local convergence of the contraharmonic-mean Newton's method (CHMN) for solving nonlinear equations in a Banach space. We have performed the semi-local convergence analysis by using generalized conditions. We examine the theoretical results by comparing the CHN method with the Newton's method and other third order methods by Weerakoon et al. using some test functions. The theoretical and numerical results are also supported by the basins of attraction for a selected test function.

• Advances in nano research
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• v.13 no.1
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• pp.47-61
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• 2022

The present research investigates the dynamic behavior of a rotating functionally graded (FG) nonlocal cylindrical beam. The cylindrical beam is mathematically modeled via third-order beam theory linked with nonlocal strain gradient theory. The tube structure is made of functionally graded materials composed of Aluminum oxide coated on the Nickel, which the mechanical properties vary in the tube radius direction according to the power law. The bending harmonic force is applied in the tube length middle. The nonlocal spinning equations of the tube are derived via the energy method of the Hamilton principle, and they are solved via a robust numerical procedure for different boundary conditions. The main application of the rotating nanostructures is for the production of small-scale motors and devices and the drug-delivery application, the presented results can help the researcher have a better view regarding the different conditions.

• Cross-Cultural Studies
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• v.52
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• pp.277-312
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• 2018

First-order cybernetics during the 1940s and 1950s aimed for control of an observed system, while second-order cybernetics during the mid-1970s aspired to address the mechanism of an observing system. The former pursues an objective, subjectless, approach to a system, whereas the latter prefers a subjective, personal approach to a system. Second-order observation must be noted since a human observer is a living system that has its unique cognition. Maturana and Varela place the autopoiesis of this biological system at the core of second-order cybernetics. They contend that an autpoietic system maintains, transforms and produces itself. Technoscientific recreation of biological autopoiesis opens up to a new step in cybernetics: what I describe as third-order cybernetics. The formation of technoscientific autopoiesis overlaps with the Fourth Industrial Revolution or what Erik Brynjolfsson and Andrew McAfee call the Second Machine Age. It leads to a radical shift from human centrism to posthumanity whereby humanity is mechanized, and machinery is biologized. In two versions of the novel Demon Seed, American novelist Dean Koontz explores the significance of technoscientific autopoiesis. The 1973 version dramatizes two kinds of observers: the technophobic human observer and the technology-friendly machine observer Proteus. As the story concludes, the former dominates the latter with the result that an anthropocentric position still works. The 1997 version, however, reveals the victory of the techno-friendly narrator Proteus over the anthropocentric narrator. Losing his narrational position, the technophobic human narrator of the story disappears. In the 1997 version, Proteus becomes the subject of desire in luring divorcee Susan. He longs to flaunt his male egomaniac. His achievement of male identity is a sign of technological autopoiesis characteristic of third-order cybernetics. To display self-producing capabilities integral to the autonomy of machinery, Koontz's novel demonstrates that Proteus manipulates Susan's egg to produce a human-machine mixture. Koontz's demon child, problematically enough, implicates the future of eugenics in an era of technological autopoiesis. Proteus creates a crossbreed of humanity and machinery to engineer a perfect body and mind. He fixes incurable or intractable diseases through genetic modifications. Proteus transfers a vast amount of digital information to his offspring's brain, which enables the demon child to achieve state-of-the-art intelligence. His technological editing of human genes and consciousness leads to digital standardization through unanimous spread of the best qualities of humanity. He gathers distinguished human genes and mental status much like collecting luxury brands. Accordingly, Proteus's child-making project ultimately moves towards technologically-controlled eugenics. Pointedly, it disturbs the classical ideal of liberal humanism celebrating a human being as the master of his or her nature.

• Journal of the Korean Regional Science Association
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• v.9 no.1
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• pp.45-63
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• 1993

University enrollment has long been regarded as one of the major factors inducing population concentration in Seoul and the Capital Region of Korea. Consequently, since early 1980's increases in enrollment and new establishments of extention universities beyond the boundary of Seoul, has been promoted, while university enrollment quota in Seoul has been strictly controlled. The degree of actual population dispersal, however, resulting from such a university enrollment policy has not been empirically tested. This paper aims at: First, identifying the trend of population growth and evolution process of the university enrollment policy in the Capital Region; Second, comparing the degree of influence of university enrollment on population concetration factors; Third, measuring actual effect of the enrollment control on population dispersal out of Seoul and the Capital Region. Major findings are as follows: First, only a week correlation between population and university enrollment growth trends was found; Second, the relative degree of influence on population concentration in the Capital Region, were order, in the order of magnitude, the physical amenity factor, the socio-cultural amenity factor, the employment climate factor and the educational factor. Third, and most improtant, based on the comparison of spatial distribution of graduated high schools and current residence of the selected university students, the gap between the two distributions was revealed and the inter-regional student population movement was estimated. The result shows that in Seoul's case about one-half of and in Kyunggi Province's case about one-fifth of university enrollment size, contributes to population concentration into Seoul. Fourth, as to the universities outside of the Capital Region, little effect in the case of universities located within the commuting distance, and a little effect on population dispersal in the case of universities located beyond commuting distance, were found. In sum, it seems clear that university enrollment policy in the Capital Region, especially in Inchon/Kyunggi Province has not been effective on student population dispersal out of Seoul and the Capital Region. Therefore, it is strongly recommended that university enrollment policy be throughly re-examined from its goal to the implementation means.

• Journal of Korean Elementary Science Education
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• v.30 no.1
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• pp.102-112
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• 2011

The purpose of this study is to investigate how $3^{rd}$ and $4^{th}$ grade elementary students view about 'Science story', which is recently inserted in the new version of science text books. For the study, four hundred $4^{th}$ graders at four schools were considered in the area of Cheonan city, Chungnam province. The degree of student's preference, preferable science topics from the 'Science story', the reason for their preference, and their attitudes toward general science were examined. The study was initiated after student's reading of the 'Science story' (Advanced science, Science in the life, Science in the history, and Future science directions). The student attitudes toward general science were examined using questionnaire survey prior to others. The results of the study are summarized: First, the students who have more interests and affirmative attitudes about science subjects with high scores are more favored about 'Science story'. Second, generally the students prefer reading topics in the order of 1) Science in the life, 2) Advanced science, 3) Science in the history, and 4) Future science directions. However the order was flexible depending on student's gender, preference, and attitudes. Third, the student's interests about 'Science story' was mostly raised from the new scientific topics in the book. And it was also raised partly from their personal interests and usefulness for science learning. Based on the results of our study, we included some suggestions for the improved 'Science story' and their utilizations.