• Title/Summary/Keyword: Thin-film Ag electrode

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The Influence of Ag Thickness on the Electrical and Optical Properties of ZnO/Ag/SnO2 Tri-layer Films

  • Park, Yun-Je;Choi, Jin-Young;Choe, Su-Hyeon;Kim, Yu-Sung;Cha, Byung-Chul;Kim, Daeil
    • Journal of the Korean institute of surface engineering
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    • v.52 no.3
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    • pp.145-149
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    • 2019
  • Transparent and conductive ZnO/Ag/SnO2 (ZAS) tri-layer films were deposited onto glass substrates at room temperature by using radio frequency (RF) and direct current (DC) magnetron sputtering. The thickness values of the ZnO and $SnO_2$ thin films were kept constant at 50 nm and the value for Ag interlayer was varied as 5, 10, 15, and 20 nm. In the XRD pattern the diffraction peaks were identified as the (002) and (103) planes of ZnO, while the (111), (200), (220), and (311) planes could be attributed to the Ag interlayer. The optical transmittance and electrical resistivity were dependent on the thickness of the Ag interlayer. The ZAS films with a 10 nm thick Ag interlayer exhibited a higher figure of merit than the other ZAS films prepared in this study. From the observed results, a ZAS film with a 10 nm thick Ag interlayer was believed to be an alternative transparent electrode candidate for various opto-electrical devices.

Amperometric Determination of Anthracycline Antibiotics with the Mercury Film Thin Layer Flow Cell (수은피막 박막흐름전지를 이용한 Anthracycline계 항생제의 전류법 정량)

  • Kim, Kyung Eun;Hahn, Younghee
    • Analytical Science and Technology
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    • v.17 no.6
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    • pp.470-475
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    • 2004
  • The mercury film thin layer flow cell (MFTLFC) which yielded the highest sensitivity for the electrochemical reduction of doxorubicin was constructed by coating the glassy carbon working electrode (GCE; $A=0.208cm^2$) with $5{\mu}L$ of HgO coating solution (0.5% HgO + 0.25% polystyrene/cyclohexanone) and subsequently followed by applying a potential of -0.40 V for 300 sec in the flow stream of an acetate buffer of pH 4.5. The voltammogram of doxorubicin reached the diffusion current plateau at -0.53 V vs. a Ag/AgCl (3 M NaCl) in the MFTLFC. The diffusion current (Id) of doxorubicin at the MFTLFC was 1.7 times greater than the Id obtained at the TLFC employing a bare glassy carbon working electrode. When the peak areas (electric charge) were plotted vs. concentrations of standard anthracyclines, the calibration factors of doxorubicin and daunorubicin were $1.12{\times}10^8{\mu}C/M$ (coefficient of determination; $R^2$: 0.969) and $0.98{\times}10^8{\mu}C/M$> ($R^2$: 0.999), respectively in the concentration range between $1.0{\times}10^{-8}M$ and $1.0{\times}10^{-6}M$.

Fabrication of Ag Grid Patterned PET Substrates by Thermal Roll-Imprinting for Flexible Organic Solar Cells (가열롤 임프린팅 방법을 이용한 유연 유기태양전지용 Ag 그리드 패턴 PET 기판 제작)

  • Cho, Jung Min;Jo, Jeongdai;Kim, Taeil;Kim, Dong Soo
    • Journal of the Korean Society for Precision Engineering
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    • v.31 no.11
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    • pp.993-998
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    • 2014
  • Silver (Ag) grid patterned PET substrates were manufactured by thermal roll-imprinting methods. We coated highly conductive layer (HCL) as a supply electrode on the Ag grid patterned PET in the three kinds of conditions. One was no-HCL without conductive PEDOT:PSS on the Ag grid patterned PET substrate, another was thin-HCL coated with ~50 nm thickness of conductive PEDOT:PSS on the Ag grid PET, and the other was thick-HCL coated with ~95 nm thickness of conductive PEDOT:PSS. These three HCLs in order showed 73.8%, 71.9%, and 64.7% each in transmittance, while indicating $3.84{\Omega}/{\Box}$, $3.29{\Omega}/{\Box}$, and $2.65{\Omega}/{\Box}$ each in sheet resistance. Fabrication of organic solar cells (OSCs) with HCL Ag grid patterned PET substrates showed high power conversion efficiency (PCE) on the thin-HCL device. The thick-HCL device decreased efficiency due to low open circuit voltage ($V_{OC}$). And the Ag grid pattern device without HCL had the lowest energy efficiency caused by quite low short current density ($J_{SC}$).

Printing Technologies for the Gate and Source/Drain Electrodes of OTFTs

  • Lee, Myung-Won;Lee, Mi-Young;Song, Chung-Kun
    • Journal of Information Display
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    • v.10 no.3
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    • pp.131-136
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    • 2009
  • This is a report on the fabrication of a flexible OTFT backplane for electrophoretic display (EPD) using a printing technology. A practical printing technology for a polycarbonate substrate was developed by combining the conventional screen and inkjet printing technologies with the wet etching and oxygen plasma processes. For the gate electrode, the screen printing technology with Ag ink was developed to define the minimum line width of ${\sim}5{\mu}m$ and the thickness of ${\sim}70nm$ with the resistivity of ${\sim}10^{-6}{\Omega}{\cdot}cm$, which are suitable for displays with SVGA resolution. For the source and drain (S/D) electrodes, PEDOT:PSS, whose conductivity was drastically enhanced to 450 S/cm by adding 10 wt% glycerol, was adopted. In addition, the modified PEDOT:PSS could be neatly confined in the specific S/D electrode area that had been pretreated with oxygen. The OTFTs that made use of the developed printing technology produced a mobility of ${\sim}0.13cm^2/Vs.ec$ and an on/off current ratio of ${\sim}10^6$, which are comparable to those using thermally evaporated Au for the S/D electrode.

A Study on the Characteristics of ITO Thin Film for Top Emission OLED (Top Emission OLED를 위한 ITO 박막 특성에 대한 연구)

  • Kim, Dong-Sup;Shin, Sang-Hoon;Cho, Min-Joo;Choi, Dong-Hoon;Kim, Tae-Geun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.06a
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    • pp.450-450
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    • 2006
  • Organic light-emitting diodes (OLED) as pixels for flat panel displays are being actively pursued because of their relatively simple structure, high brightness, and self-emitting nature [1, 2]. The top-emitting diode structure is preferred because of their geometrical advantage allowing high pixel resolution [3]. To enhance the performance of TOLEDs, it is important to deposit transparent top cathode films, such as transparent conducting oxides (TCOs), which have high transparency as well as low resistance. In this work, we report on investigation of the characteristics of an indium tin oxide (ITO) cathode electrode, which was deposited on organic films by using a radio-frequency magnetron sputtering method, for use in top-emitting organic light emitting diodes (TOLED). The cathode electrode composed of a very thin layer of Mg-Ag and an overlaying ITO film. The Mg-Ag reduces the contact resistivity and plasma damage to the underlying organic layer during the ITO sputtering process. Transfer length method (TLM) patterns were defined by the standard shadow mask for measuring specific contact resistances. The spacing between the TLM pads varied from 30 to $75\;{\mu}m$. The electrical properties of ITO as a function of the deposition and annealing conditions were investigated. The surface roughness as a function of the plasma conditions was determined by Atomic Force Microscopes (AFM).

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Micromachined pH Sensor Using Open Well Structures (개방형 우물 구조를 이용한 마이크로머신형 pH 센서)

  • Kim, Heung-Rak;Kim, Young-Deog;Jeong, Woo-Cheol;Kim, Kwang-Il;Kim, Dong-Su
    • Journal of the Korean Society for Nondestructive Testing
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    • v.22 no.4
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    • pp.347-353
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    • 2002
  • A structure of a glass electrode-type pH sensor for measuring any concentration of $H^+$ in an aqueous solution was embodied with bulk micromachining technology. Two open well structures were formed, and a reference electrode was secured by the Ag/AgCl thin film in the sloped side of the etched structure. A sensitive membrane of an indicator electrode for generating a potential by an exchange reaction to $H^+$ was made with a glass containing Na 20% or more finely so that its thickness might be $100{\mu}m$ or so, and then it was bonded to one pyramidal structure. A liquid junction for a current path was formed by filling an agar in the anisotropically etched part of the Si wafer, which had a size of $50{\mu}m{\times}50{\mu}m$, and then bonded it to the other. After complete fabrication of each part, it was filled with a 2M KCl reference solution and encapsulated the sensor structure with a cold expoxy. The potential value of fabricated pH sensor was about 90mV/pH in the standard pH solutions.

Characteristics of Ag/AgCl Thin Film Reference Electrode in Urea Sensors (요소센서를 위한 은/염화은 박막 기준전극의 특성)

  • Jin, Joon-Hyung;Kang, Chul-Goo;Kang, Moon-Sik;Min, Nam-Ki;Hong, Suk-In
    • Proceedings of the KIEE Conference
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    • 2001.07c
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    • pp.1911-1913
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    • 2001
  • 전위차 측정형 바이오 센서는 기준전극에 대한 센서 전극의 전기화학적 전위를 정확하게 측정하여야 하므로 기준전극의 안정성이 매우 중요하다. 기준전극의 전위는 전해질 용액 내의 염소 음이온 농도에 영향을 받으나 다행히도 혈액 내의 염소 음이온 농도는 거의 변화가 없으므로 혈액 속에서의 은/염화은 기준전극의 전위도 거의 변화가 없다. 본 연구에서는, 사진석판 (Photolithography) 공정을 이용하여 실리콘 표면 및 다공질 실리콘 표면에 은/염화은 박막 기준전극을 제작하고 시료 용액에서의 drift, 안정성, 재현성 등에 대한 특성을 고찰하였고, SEM, AES, EDX 스펙트럼 등을 이용하여 전극의 표면을 분석하였다. 시료 용액의 염소 음이온 농도를 $10^{-4}$M에서 1M까지 변화시켜가며 기준 전극의 전위를 측정한 결과 약 50mV/pCl의 기울기를 얻었으며 이것은 Nernst식을 잘 따르는 결과이다.

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A Study on Water Tree Degradation Using Image Measurement in Underground Power Cables (화상계측에 의한 지중 전력케이블의 수트리 열화에 관한 연구)

  • Kim, Duck-Keun;Lim, Jang-Seub;Lee, Jin
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.13 no.12
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    • pp.1063-1068
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    • 2000
  • Water treeing in underground distribution power cable is not easy to observe by nondestructive method and it has very complex patterns. This study describes the principles and practices of a continuous observation of initiation and growth of tree in polymeric insulation material using an image measurement technique. Using this technique we could observe water tree and the growing process of electrical tree due to the water tree and the growing process of electrical tree due to the water tree. All of these growing process is analyzed quantitatively by image measurement program composed of borland c++. We fabricated the thin film type specimen to observe water tree easier and also the needle electrode was prepared by etching method using electrolytes. Initiation and the growth of three was observed somewhat different depending on the applied voltage and the water electrode. AgNO$_3$solution electrode accelerates the initiation and the growth of water tree, compared to those of distilled water electrode. The water and the electrical tree occurred by water tree has discontinuous growth characteristic.

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Electro-optical characterization of heterostructure organic electroluminescent devices (2층 구조 유기 박막 EL 소자의 전기-광학적특성)

  • Kim, Min-Soo;Park, Se-Kwang
    • Journal of Sensor Science and Technology
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    • v.4 no.4
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    • pp.10-15
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    • 1995
  • Organic thin film electroluminescent(EL) cells were fabricated. Their output characteristics and luminance versus voltage characteristics were measured with different work function metal electrodes. The EL structure was Indium-Tin-Oxide(ITO)/hole transport layer/emission layer(electron transport layer)/metal electrode. PMMA+TPD(0.5 wt%), MC homopolymer+TPD(0.005 wt%) and (MC/MMA) copolymer+TPD(0.005 wt%) were used as hole transport layer. Ca, Mg, Mg:Ag(10:l) and Al were used as metal electrode. I-V output showed exponential feature, and the threshold voltage of 5 volts and the luminance of over 700 $Cd/m^{2}$ at 10 volts were observed.

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Dielectric $Bi_3NbO_7$ thin film grown on flexible substrates by Nano Cluster Deposition

  • Lee, Hyun-Woo;Yoon, Soon-Gil
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.11a
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    • pp.10-10
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    • 2009
  • Transparent BNO thin films were grown on Al-doped ZnO (AZO)/Ag/AZO/polyethersulfon (PES) (abbreviated as AAAP) transparent electrodes at a low temperature by the NCD technique. The BNO films grown on the crystallized AZO/Ag/AZO (AAA) electrodes exhibit an amorphous phase with a root mean square (rms) roughness of approximately 2 nm in the range of deposition temperature. The capacitors (Pt/BNO/AAAP) with BNO films grown at $100^{\circ}C$ show a dielectric constant of 24 and dissipation factor of 8% at 100 kHz, a leakage current density of about $8{\times}10^{-6}A/cm^2$ at an applied voltage of 1.0V. The optical transmittances of the BNO/AAAP exhibited above 80% at wavelength of 550nm at all of deposition temperature. The mechanical stability of the BNO/AAA as well as AAA electrode with the PES substrates through the bending was ensured for flexible electronic device applications. The transparent BNO capacitors grown on AAAP are powerful candidate for integration with the transparent solar cells.

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