• Title/Summary/Keyword: Thin multi-walled carbon nanotubes

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Synthesis of well-aligned thin multiwalled carbon nanotubes on the silicon substrate and their field emission properties

  • Yuan, Huajun;Shin, Dong-Hoon;Kim, Bawl;Lee, Cheol-Jin
    • Carbon letters
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    • v.12 no.4
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    • pp.218-222
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    • 2011
  • Well-aligned multi-walled carbon nanotubes (MWCNTs) were successfully synthesized by catalytic chemical vapor deposition using a hydrogen sulfide ($H_2S$) additive onto Al/Fe thin film deposited on Si wafers. Transmission electron microscopy images indicated that the as-grown carbon products were thin MWCNTs with small outer diameters of less than 10 nm. $H_2S$ plays a key role in synthesizing thin MWCNTs with a large inside hollow core. The well-aligned thin MWCNTs showed a low turn-on voltage of about 1.1 V/${\mu}m$ at a current density of 0.1 ${\mu}A/cm^2$ and a high emission current of about 1.0 mA/$cm^2$ at a bias field of 2.3 V/${\mu}m$. We suggest a possible growth mechanism for the well-aligned thin MWCNTs with a large inside hollow core.

Thin CNTs nanoliquid film development over a rough rotating disk

  • Swatilekha Nag;Susanta Maity;Sanjeev K. Metya
    • Advances in nano research
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    • v.15 no.2
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    • pp.91-104
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    • 2023
  • Development of thin carbon nanotubes (CNTs) nanoliquid film over the rough surface of a horizontal rotating disk is investigated by considering symmetric roughness either along the azimuthal or radial directions. The disk surface is either heated or cooled axisymmetrically from below. The effects of single-walled carbon nanotubes (SWCNTs), multi-walled carbon nanotubes (MWCNTs) are analyzed on the film thinning process with different types of base liquids. Closed form solutions for velocity and temperature field are obtained for small values of Reynolds number whereas the numerical solution is derived for moderate values of Reynolds number. It is found that fluid retention / depletion takes place when the roughness is symmetric along the azimuthal / radial directions. It is also seen that the film thinning rate enhances for MWCNTs compare to SWCNTs. Further it is found that two different heat transfer regions exits within the flow domain depending on the fact that heat is transferred from disk to liquid film and vice-versa.

DNA and DNA-CTMA composite thin films embedded with carboxyl group-modified multi-walled carbon nanotubes

  • Dugasani, Sreekantha Reddy;Gnapareddy, Bramaramba;Kesama, Mallikarjuna Reddy;Ha, Tai Hwan;Park, Sung Ha
    • Journal of Industrial and Engineering Chemistry
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    • v.68
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    • pp.79-86
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    • 2018
  • Although the intrinsic characteristics of DNA molecules and carbon nanotubes (CNT) are well known, fabrication methods and physical characteristics of CNT-embedded DNA thin films are rarely investigated. We report the construction and characterization of carboxyl (-COOH) group-modified multi-walled carbon nanotube (MWCNT-COOH)-embedded DNA and cetyltrimethyl-ammonium chloride-modified DNA (DNA-CTMA) composite thin films. Here, we examine the structural, compositional, chemical, spectroscopic, and electrical characteristics of DNA and DNA-CTMA thin films consisting of various concentrations of MWCNT-COOH. The MWCNT-COOH-embedded DNA and DNA-CTMA composite thin films may offer a platform for developing novel optoelectronics, energy harvesting, and sensing applications in physical, chemical, and biological sciences.

High-yield synthesis of thin multiwalled carbon nanotubes and their field emission characteristics

  • Jeong, Hee-Jin;Song, Young-Il;Choi, Ha-Kyu;Kim, Gil-Yong;Yu, Tong;Lim, Seong-Chu;Lee, Young-Hee
    • 한국정보디스플레이학회:학술대회논문집
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    • 2005.07b
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    • pp.1443-1446
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    • 2005
  • We have synthesized thin multi-walled carbon nanotubes (t-MWCNTs) using a catalytic chemical vapor deposition (CCVD) method with FeMoMgO catalyst. The number of tube walls were 2 ${\sim}$ 6 with the corresponding diameters of 3 ${\sim}$ 6 nm. We obtained high production yield of over 3000 wt% compared to the weight of the supplied catalyst. These t-MWCNTs revealed the intermediate structural characteristics between single- and multi-walled carbon nanotubes (SWCNTs and MWCNTs). We have also characterized the field emission properties such as turn-on field and emission current, and current degradation from these t-MWCNTs together with SWCNTs and MWCNTs.

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Stability Analysis of Multi-wall Carbon Nanotubes Conveying Fluid (유체유동에 의한 다중벽 탄소나노튜브의 안정성 해석)

  • Song, Oh-Seop;Yun, Kyung-Jae
    • Transactions of the Korean Society for Noise and Vibration Engineering
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    • v.20 no.6
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    • pp.593-603
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    • 2010
  • In this paper, vibration and flow-induced flutter instability analysis of cantilever multi-wall carbon nanotubes conveying fluid and modelled as a thin-walled beam is investigated. Non-classical effects of transverse shear and rotary inertia and van der Waals forces between two walls are incorporated in this study. The governing equations and the associated boundary conditions are derived through Hamilton's principle. Numerical analysis is performed by using extend Galerkin method which enables us to obtain more exact solutions compared with conventional Galerkin method. Cantilevered carbon nanotubes are damped with decaying amplitude for flow velocity below a certain critical value, however, beyond this critical flow velocity, flutter instability may occur. Variations of critical flow velocity with both radius ratio and length of carbon nanotubes are investigated and pertinent conclusion is outlined.

Structural Analysis of Carboxylic Acid-functionalized Multi-walled Carbon Nanotubes (카복실산으로 표면개질된 다중층 탄소나노튜브의 구조분석)

  • Kim, Jung-Soo;Lee, Geon-Woong;Oh, Weon-Tae
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.20 no.10
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    • pp.878-882
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    • 2007
  • Carboxylated multi-walled carbon nanotubes (MWNTs) were in detail characterized by XRD, XPS, FTIR, and thermogravimetric measurements. Carboxylic acid groups were functionalized to MWNTs under aqueous acid condition. The changes of sonication and reflux conditions rarely influenced the degree of carboxylation on MWNTs, but decreased the thermal stability of the resultant carboxylated MWNTs. XRD results showed that the diffraction peaks (100), (101), and (102) of pristine MWNTs disappeared after acid treatment, but the diffraction peak (002) was Preserved in the carboxylated MWNTs. The introduction of carboxylic acid groups on MWNTs caused to improve the dispersibility of the resultant carboxylated MWNTs in water.

Structural Analysis of Carboxylic Acid-Functionalized Multi-walled Carbon Nanotubes

  • Oh, Weon-Tae;Kim, Jung-Soo;Lee, Geon-Woong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.63-63
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    • 2007
  • Carboxylated multi-walled carbon nanotubes (MWNTs) were in detail characterized by XRD, XPS, FTIR, and thermogravimetric measurements. Carboxylic acid groups were functionalized to MWNTs using aqueous acid solutions. The change. of sonication and reflux conditions rarely influenced the degree of carboxylation on MWNTs, but reduced the thermal stability of the resulting carboxylated MWNTs. The characteristic Bragg peaks of pristine and carboxylated MWNTs were analyzed by XRD measurements. After acid treatment the diffraction peaks (100), (101), and (102) of pristine MWNTs disappeared, but the diffraction peak (002) was preserved in the carboxylated MWNTs. The introduction of carboxylic acid groups on MWNTs caused to improve the dispersibility of the resulting carboxylated MWNTs in water.

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Vibration Stability Analysis of Multi wall Carbon Nanotubes Considering Conveying Fluid Effect (유체유동효과를 고려한 다중벽 탄소나노튜브의 진동 및 안정성 해석)

  • Yun, Kyung-Jae;Choi, Jong-Woon;Song, Oh-Seop
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2012.04a
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    • pp.219-224
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    • 2012
  • In this paper, vibration and flow-induced flutter instability analysis of cantilever multiwall carbon nanotubes conveying fluid and modelled as a thin-walled beam is investigated. Non-classical effects of transverse shear and rotary inertia are incorporated in this study. The governing equations and the associated boundary conditions are derived through Hamilton's principle. Numerical analysis is performed by using extend Galerkin method which enables us to obtain more exact solutions compared with conventional Galerkin method. Cantilevered carbon nanotubes are damped with decaying amplitude for flow velocity below a certain critical value, however, beyond this critical flow velocity, flutter instability may occur. Variations of critical flow velocity with both radius ratio and length of carbon nanotubes are investigated and pertinent conclusion is outlined.

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Flow-induced Instability of Multi-wall Carbon Nanotubes for Various Boundary Conditions (경계조건에 따른 다중벽 탄소나노튜브의 유체유발 불안정성 변화)

  • Yun, Kyung-Jae;Song, Oh-Seop
    • Transactions of the Korean Society for Noise and Vibration Engineering
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    • v.20 no.9
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    • pp.805-815
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    • 2010
  • This paper studies the influence of internal moving fluid and flow-induced structural instability of multi-wall carbon nanotubes conveying fluid. Detailed results are demonstrated for the variation of natural frequencies with flow velocity, and the flow-induced divergence and flutter instability characteristics of multi-wall carbon nanotubes conveying fluid and modelled as a thin-walled beam are investigated. Effects of various boundary conditions, Van der Waals forces, and non-classical transverse shear and rotary inertia are incorporated in this study. The governing equations and three different boundary conditions are derived through Hamilton's principle. Numerical analysis is performed by using extended Galerkin's method which enables us to obtain more exact solutions compared with conventional Galerkin's method. This paper also presents the comparison between the characteristics of single-wall and multi-wall carbon nanotubes considering the effect of van der Waals forces. Variations of critical flow velocity for different boundary conditions of two-wall carbon nanotubes are investigated and pertinent conclusion is outlined.