• 한국재료학회지
• /
• 제10권4호
• /
• pp.257-263
• /
• 2000

0.05wt% $SbI_3$를 첨가한 n형 $ Bi_2(Te(_{0.95}Se_{0.05})_3$ 합금분말을 용해/분쇄법으로 제조하여 가압소결 후, 36시간까지의 열처리 시간에 따른 열전특성의 변화 거동을 분석하였다. 열처리 시간이 증가함에 따라 0.05wt% $SbI_3$를 첨가한 n형 $ Bi_2(Te(_{0.95}Se_{0.05})_3$ 가압소결체의 전자 농도가 감소하였다. 0.05wt% $SbI_3$를 첨가한 $Bi_2(Te(_{0.95}Se_{0.05})_3$ 가압소결체는 $2.1{\times}10^{-3}/K$의 성능지수를 나타내었으며 $500^{\circ}C$에서 3시간 열처리 시 $2.35{\times}10^{-3}/K$로 성능지수가 향상되었으나, 12시간 이상 열처리 시에는 전기비저항의 증가에 기인하여 성능지수의 현저한 감소가 발생하였다.

• 한국산학기술학회논문지
• /
• 제22권3호
• /
• pp.30-35
• /
• 2021

본 연구는 다양한 가이드 핀 구조와 경계 파라미터가 폐열 회수 열전발전용 열교환기의 열적 성능에 미치는 영향에 대하여 다룬다. 가이드 핀 구조의 영향을 확인하기 위하여 ANSYS 19.1 소프트웨어를 사용하여 핀이 없는 유형, 삼각형 핀, 원형 핀, 원형 핀과 삼각 핀 조합 열교환기의 열전달율 및 압력 강하 특성을 수치해석 하였다. 원형 핀과 삼각 핀 조합 열교환기는 핀이 없는 열교환기, 원형 핀 또는 삼각 핀이 있는 원형 핀 또는 삼각 핀 열교환기와 비교하여 각각 27.0%, 5.2% 및 1.5% 높은 열전달율을 나타내었다. 그리고 복합 핀 열교환기의 압력강하는 핀이 없는 열교환기와 비교하여 28.3% 높았지만, 복합 핀 열교환기와 비교하여 9.2% 및 10.5% 낮은 압력강하 특성을 나타내었다. 최적모델로서 복합 핀 열교환기는 최대 고온 가스 및 냉각수 질량 유량, 최고 고온 가스 온도 그리고 최저 냉각수 온도 조건에서 최대 열전달율 5664.9 W 및 최대 압력강하 1454.02 Pa을 나타내었다.

• 열처리공학회지
• /
• 제31권3호
• /
• pp.135-142
• /
• 2018

In this study, we have fabricated n-type $Bi_2Te_{2.85}Se_{0.15}$ compounds by different processing routes such as crushing, milling and mixing respectively. Subsequently, the obtained powders were consolidated by spark plasma sintering (SPS). The phase crystallinity of bulk samples were identified using X-ray diffraction technique. Powder morphology and fracture surface of bulk samples were observed using the scanning electron microscopy (SEM). The Seebeck coefficient and electrical conductivity values were significantly increased for the milling sample than crushing and mixing samples. As a result, the maximum power factor was obtained $2.4mW/mK^2$, which is thrice than that of crushing process. The maximum figure of merit (ZT) of 0.77 was achieved at 400 K for the milling sample. Furthermore, relatively high hardness and density values were noticed for the different processed samples.

• 마이크로전자및패키징학회지
• /
• 제15권3호
• /
• pp.1-8
• /
• 2008

환원분위기 열처리가 진공증착법으로 형성한 $(Bi,Sb)_{2}Te_3$박막의 열전특성에 미치는 영향을 연구하였다. 환원분위기(50% $H_2$ + 50% Ar)에서 $300^{\circ}C$의 온도로 2시간 유지하여 열처리함으로써 $(Bi,Sb)_{2}Te_3$박막의 결정성이 크게 향상되었으며 결정립 크기가 크게 증가하였다. 환원분위기 열처리에 의한 정공농도의 감소에 기인하여 $(Bi,Sb)_2Te_3$박막의 Seebeck계수가 열처리 전의 $\sim90{\mu}V/K$로부터 $\sim180{\mu}V/K$으로 증가하였다. 환원분위기 열처리에 의해 $(Bi,Sb)_{2}Te_3$ 박막의 출력인자(power factor)가 5배에서 16배 정도 향상되었으며, 환원분위기 열처리 후 $(Bi,Sb)_{2}Te_3$ 박막은 $18.6\times10^{-4}W/K^{2}-m$의 최대 출력인자를 나타내었다.

• 센서학회지
• /
• 제3권1호
• /
• pp.61-67
• /
• 1994

R형 열전대의 열기전력에 미치는 열처리효과에 대하여 살펴보기 위하여 알루미늄 및 은 금속 응고점 셀에서 깊이에 따른 열기전력의 변화를 조사하였다. 사용전 열처리 방법에 따라 최대기전력 차이는 $660.323^{\circ}C$ 에서 $17.1{\mu}V$, $961.78^{\circ}C$ 에서 $18.1{\mu}V$ 를 보였다. 또한 충분한 열처리를 거치지 않은 열전대는 동일한 온도로 유지되고 있는 응고점 셀내에서도 삽입깊이에 따라 기전력 차이를 나타냈으며, 그 정도는 알루미늄 응고점에서 최대 $7.8{\mu}V$은 응고점에서 $18.9{\mu}V$를 보였다. 따라서 열전대를 사용하여 정확한 온도를 측정하기 위해서는 충분한 열처리를 거쳐야 함을 알 수 있었으며, 본 논문에서 얻어진 실험결과를 바탕으로 R형 열전대의 열처리방법을 제시하였다.

• 한국환경보건학회지
• /
• 제42권3호
• /
• pp.213-223
• /
• 2016

Objectives: This study was designed to assess the level of physical exposure to heavy metals among residents who live around a Chungcheongnam-do Province industrial complex and to provide baseline data on the effects and harms of heavy metals on the human body by comparing their exposure levels to those of people from control regions. Methods: We measured blood lead and cadmium levels and urine mercury and chromium levels and conducted a survey among 559 residents from the affected area and 347 residents of other areas. Results: Blood lead and cadmium levels and urine mercury levels were significantly higher in the case region than among those in the control region (p=0.013, p<0.001, p<0.001, respectively). In the thermoelectric power plant area, blood cadmium and urine mercury levels were significantly higher than in the control region (p<0.001, p<0.001, respectively). In the steel mill and petrochemical industry areas, blood cadmium level was significantly higher than that in the control region (p<0.001). Dividing groups by the reference level of blood cadmium ($2{\mu}g/L$), the odds ratios between the case and control regions were 2.56 (95% CI=1.83-3.58), 3.11 (95% CI=2.06-4.71) for the thermoelectric power plant area, 1.78 (95% CI=1.19-2.65) for the steel mill area and 4.07 (95% CI=2.40-6.89) for petrochemical industry area. Conclusion: This study showed that the levels of exposure to heavy metals among residents living near a Chungcheongnam-do Province industrial complex were significantly higher than those in the control region. This seems to be attributable to exposure to heavy metals emissions from the industrial complex. Further research and safety measures are required to protect residents' health.

• The Korean Journal of Ceramics
• /
• 제2권1호
• /
• pp.11-18
• /
• 1996

The variation of electrical conductively and Seebeck coefficient of FeSi2 according to the density of the specimen has been observed over the temperature range 50 to $700^{\circ}C$. A conventional pressureless sintering method with various sintering time (0, 0.5, 1, 5h) at $1190^{\circ}C$ and/or various sintering temperatures(1160, 1175, 1190, $1200^{\circ}C$) for 2 h was carried out to prepare $FeSi_2$ specimens having various densities. The relationship between the electrical conductivity and Seebeck coefficient was investigated after two steps of annealing (at $865^{\circ}C$ and then $800^{\circ}C$ for total 160h) and thermoelectric measurement. The electrical conductivity for the specimens showed a typical tendency of semiconductor, the average activation energy of which in the intrinsic region (above $300^{\circ}C$) was observed approximately as 0.452 eV, and increased slightly with density. On the other hand, the specimen of the lower density showed the higher value of Seebeck coefficient in the intrinsic region. As the temperature fell into the non-degenerate region, the highly densified specimen which had relatively little residual metal phase showed the higher value of Seeback coefficient. The power factor of all specimens showed the optimum value at $200^{\circ}C$. However, the power factor of the specimen of the lower density increased again from $400^{\circ}C$ and that of the higher dense specimen increased from $500^{\circ}C$. The power factor was more affected by Seebeck coefficient than electrical conductivity over all temperature range.

• Composites Research
• /
• 제29권4호
• /
• pp.156-160
• /
• 2016

유리상 탄소는 열적으로 안정하고, 화학적 반응성이 매우 낮으며, 다양한 크기로 제작이 가능하고, 전기적 저항 또한 낮아서 다양한 극한 환경에서 사용 가능하다. 이 논문에서는 전자빔 조사가 유리상 탄소 박막의 구조 변화에 미치는 영향과 그에 따른 열전효과 변화에 대해 연구하였다. 라만 분광 특성 분석을 바탕으로 유리상 탄소 박막에 전자빔 조사에 따라 결정화 또는 비정질화가 일어나는 것을 확인하였다. 또한, 이러한 결정변화가 유리상 탄소 박막의 자유전자 도핑 농도의 변화시키며 그에 따른 제백 상수나 전기적 전도도의 변화도 확인하였다. 전자빔 조사로 인하여 유리상 탄소의 열전파워 펙터가 최대 200%까지 향상되는 것을 보여 주었다.

• Ocean and Polar Research
• /
• 제40권2호
• /
• pp.59-67
• /
• 2018

This study was conducted to understand the distribution and changes of macrobenthos on rocky intertidal areas around Taean thermoelectric power plant, Also, the purpose of this study was to produce a base-line data on the changes in water temperature due to the operation of the power plant and to understand its thermal impact on the macrobenthic community on intertidal rocky bottoms. A field survey was seasonally conducted at 3 rocky intertidal sites around the Taean thermal power plant. There was no seasonal difference in the community parameters such as number of species, mean density, biomass and species diversity during the study period. The major dominant species were Chthamalus challenger, Littorina brevicula, Crassostrea gigas. In comparison with previous study, thermal discharge in the study area did not significantly affect the distribution of dominant species. The structure of the macrobenthic community revealed that there were showed 3 different faunal groups depending on the difference in the mean density of major dominant species. The result of SIMPER analyses to determine which species were the main contributors to the differences between each community, C. challenger, Lottia spp. And Mytilus galloprovincialis, etc., revealed that there was showed a significant difference between each group. The abundance of M. galloprovincialis, showed a significant difference between faunal groups.

• 한국분말재료학회지
• /
• 제28권3호
• /
• pp.239-245
• /
• 2021

The SnSe single crystal shows an outstanding figure of merit (ZT) of 2.6 at 973 K; thus, it is considered to be a promising thermoelectric material. However, the mass production of SnSe single crystals is difficult, and their mechanical properties are poor. Alternatively, we can use polycrystalline SnSe powder, which has better mechanical properties. In this study, surface modification by atomic layer deposition (ALD) is chosen to increase the ZT value of SnSe polycrystalline powder. SnSe powder is ground by a ball mill. An ALD coating process using a rotary-type reactor is adopted. ZnO thin films are grown by 100 ALD cycles using diethylzinc and H₂O as precursors at 100℃. ALD is performed at rotation speeds of 30, 40, 50, and 60 rpm to examine the effects of rotation speed on the thin film characteristics. The physical and chemical properties of ALD-coated SnSe powders are characterized by scanning and tunneling electron microscopy combined with energy-dispersive spectroscopy. The results reveal that a smooth oxygen-rich ZnO layer is grown on SnSe at a rotation speed of 30 rpm. This result can be applied for the uniform coating of a ZnO layer on various powder materials.