• 한국분말재료학회지
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• 제18권5호
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• pp.401-405
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• 2011

Half-heusler phase ZrNiSn is one of the potential thermoelectric materials for high temperature application. In an attempt to investigate the effect of Sb doping on thermoelectric properties, half-heusler phase $ZrNiSn_{1-x}Sb_x$ ($0{\leq}x{\leq}0.08$) was synthesized by mechanical alloying of stoichiometric elemental powder compositions, and consolidated by vacuum hot pressing. Phase transformations during mechanical alloying and hot consolidation were investigated using XRD. Sb doped ZrNiSn was successfully produced in all doping ranges by vacuum hot pressing using as-milled powders without subsequent annealing. Thermoelectric properties as functions of temperature and Sb contents were evaluated for the hot pressed specimens. Sb doping up to x=0.04 in $ZrNiSn_{1-x}Sb_x$ was shown to be effective on thermoelectric properties and the figure of merit (ZT) was shown to reach to the maximum at x=0.02 in this study.

• 에너지공학
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• 제25권4호
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• pp.184-189
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• 2016

$CO_2$ 배출 규제와 에너지 소비 절감의 요구가 늘어남에 따라, 버려지는 열을 수확하여 전기를 생산하기 위한 열전발전 연구가 최근 활발히 이루어지고 있다. 본 연구에서는 폐열 에너지 회수장치로 사용하기 위한 열전모듈의 발전 특성을 분석하였다. Bismuth telluride로 제작된 열전모듈에 다양한 온도 조건을 부여하며 이에 따른 열전 거동을 분석하였다. 또한 다양한 온도 조건에서의 열전모듈의 발전 효율을 실험 및 이론에 의해 분석하였다. 이로 부터, 열전모듈로 열에너지를 보다 효율적으로 회수하기 위한 최적의 작동조건을 제시하였다.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2007년도 춘계학술대회A
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• pp.1459-1462
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• 2007

In general a thermoelectric cooler (TEC) consists of a series of P type and N type thermoelectric materials sandwiched between two wafers. When a DC current passes through these materials, three different effects take place; Peltier effect, Joule heating effect and heat transfer by conduction due to temperature difference between hot and cold plates. In this study we have developed a micro TEC using $Bi_2Te_3$ (N type) and $Bi_{0.5}Sb_{1.5}Te_3$ (P type) thin films. In order to improve that performance of a micro TEC, we made 10 um height TE legs using special PR only for lift-off. We measured COP (coefficient of performance) and temperature difference between hot and cold connectors with current.

• 설비공학논문집
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• 제18권1호
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• pp.66-72
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• 2006

This article presents the optimal operation of an air conditioner using thermoelectric modules. A prototype of air conditioner using four thermoelectric modules has been designed and built. The system performance with evaporative cooling for hot side of the module are studied in detail for several operating parameters, such as input power to the thermoelectric module, fans and pump. It is found that the optimal input voltage to the thermoelectric module and pump is selected for the best system performance based on the cooling capacity and the COP at a given operating condition. It is also found that both the cooling capacity and COP of a system is increased with an increase in the input power to fans. The cooling performance could be improved when the ambient temperature is increased and the relative humidity is decreased since the evaporative cooling at the hot side has been increased.

• 한국재료학회지
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• 제16권5호
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• pp.292-296
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• 2006

Effects of rapid thermal annealing of bismuth telluride thin films on their thermoelectric properties were investigated. Films with four different compositions were elaborated by co-sputtering of Bi and Te targets. Rapid thermal treatments in range of $300{\sim}400^{\circ}C$ were carried out during 10 minutes under the reducing atmosphere (Ar with 10% $H_2$). As the temperature of thermal treatment increased, carrier concentrations of films decreased while their mobilities increased. These changes were clearly observed for the films close to the stoichiometric composition. Rapid thermal treatment was found to be effective in improving the thermoelectric properties of $Bi_2Te_3$ films. Recrystallization of $Bi_2Te_3$ phase has caused the enhancement of thermoelectric properties, along with the decrease of the carrier concentration. Maximum values of Seebeck coefficient and power factor were obtained for the films treated at $400^{\circ}C$ (about $-128{\mu}V/K$ and $9{\times}10^{-4}\;W/K^2m$, respectively). With further higher temperature ($500^{\circ}C$), thermoelectric properties deteriorated due to the evaporation of Te element and subsequent disruption of film's structure.

• 한국분말재료학회지
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• 제17권2호
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• pp.136-141
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• 2010

Bismuth-telluride based $(Bi_{0.2}Sb_{0.8})_2Te_3$ thermoelectric powders were fabricated by two-step planetary milling process which produces bimodal size distribution ranging $400\;nm\;{\sim}\;2\;{\mu}m$. The powders were reduced in hydrogen atmosphere to minimize oxygen contents which cause degradation of thermoelectric performance by decreasing electrical conductivity. Oxygen contents were decreased from 0.48% to 0.25% by the reduction process. In this study, both the as-synthesized and the reduced powders were consolidated by the spark plasma sintering process at $350^{\circ}C$ for 10 min at the heating rate of $100^{\circ}C/min$ and then their thermoelectric properties were investigated. The sintered samples using the reduced p-type thermoelectric powders show 15% lower specific electrical resistivity ($0.8\;m{\Omega}{\cdot}cm$) than those of the as-synthesized powders while Seebeck coefficient and thermal conductivity do not change a lot. The results confirmed that ZT value of thermoelectric performance at room temperature was improved by 15% due to high electric conductivity caused by the controlled oxygen contents present at bismuth telluride materials.

• 한국분말재료학회지
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• 제17권6호
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• pp.494-498
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• 2010

The p-type thermoelectric compounds of $Bi_2Te_3$ based doped with 3wt% Te were fabricated by a combination of rapid solidification and spark plasma sintering (SPS) process. The effect of holding time during spark plasma sintering (SPS) on the microstructure and thermoelectric properties were investigated using scanning electron microscope (SEM), X-ray diffraction (XRD) and thermoelectric properties. The powders as solidified consisted of homogeneous thermoelectric phases. The thermoelectric figure of merit measured to be maximum ($3.41{\times}10^{-3}/K$) at the SPS temperature of $430^{\circ}C$.

• 한국분말재료학회지
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• 제14권4호
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• pp.272-276
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• 2007

P-type thermoelectric material $Si_{0.8}Ge_{0.2}$ was sintered by Hot Press process (HP) and the effect of boron ($0.25{\sim}2$ at%) addition on the thermoelectric properties were reported. To enhance the thermoelectric performances, the $Si_{0.8}Ge_{0.2}$, alloys were fabricated by mechanical alloying (MA) and HP. The carrier of p-type SiGe alloy was controlled by B-doping. The effect of sintering condition and thermoelectric properties were investigated. B-doped SiGe alloys exhibited positive seebeck coefficient. The electrical conductivity and thermal conductivity were increased at the small amount of boron content ($0.25{\sim}0.5$ at%). However, they were decreased over 0.5 at% boron content. As a result, the small addition of boron improved the Z value. The Z value of 0.5 at% B doped $Si_{0.8}Ge_{0.2}$ B alloy was $0.9{\times}10{-4}/K$, the highest value among the prepared alloys.

• 한국태양에너지학회 논문집
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• 제39권1호
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• pp.21-32
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• 2019

Solar hot water system produces hot water using solar energy. If it is not used effectively, overheating occurs during the summer. Therefore, a lot of research is being done to solve this. This study develops thermoelectric power module applicable to solar hot water system. A thermoelectric material can directly convert thermal energy into electrical energy without additional power generation devices. If there is a temperature difference between high and low temperature, it generate power by Seebeck effect. The thermoelectric module generates electricity using temperature differences through the heat exchange of hot and cold water. The water used for cooling is heated and stored as hot water as it passes through the module. It can prevent overheating of Solar hot water system while producing power. The thermoelectric module consists of one absorption and two radiation part. There path is designed in the form of a water jacket. As a result, a temperature of the absorption part was $134.2^{\circ}C$ and the radiation part was $48.6^{\circ}C$. The temperature difference between the absorption and radiation was $85.6^{\circ}C$. Also, The Thermoelectric module produced about 122 W of irradiation at $708W/m^2$. At this time, power generation efficiency was 2.62% and hot water conversion efficiency was 62.46%.

• Transactions on Electrical and Electronic Materials
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• 제18권2호
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• pp.66-69
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• 2017

The internal temperature of human-tissue transfers must be steadily maintained regardless of the external environmental changes. An ice pack and dry ice are the coolants for the transfer containers for which heat-insulating materials such as EPP (expended polypeopylene and EPS (expended polystrene) are used; however, changes of the external temperature/pressure and the melting of the coolants that is due to a long carriage result in changes of the internal temperature, and this makes it difficult to maintain the temperature. Accordingly, the thermoelectric element was used to design/manufacture a transfer container to maintain the internal temperature regardless of the external environmental changes. As a result of the measurement of the changes of the internal temperatures of the manufactured thermoelectric-element container and the EPS container over time, the internal temperature of the EPS container was increased, whereas the internal temperature of the thermoelectric-element container was maintained. The temperature of the distilled water that was poured into the containers indicated a pattern identical to that of the internal temperature.