• Title/Summary/Keyword: Thermodynamic second law

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Basic Study on the Definition of the Second Law Efficiencies of Thermodynamic Cycles (열역학적 사이클의 제2법칙 효율의 정의에 대한 기본 연구)

  • Park, Kyoung Kuhn
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.24 no.11
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    • pp.792-798
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    • 2012
  • A general concept on the definition of the second law efficiencies of thermodynamic cycles is introduced. The efficiency is defined to be proportional to the entropy generation divided by the maximum possible entropy generation. This way of definition of the cycle efficiency is clear and concise and, moreover, follows faithfully the concept of the second law of thermodynamics. This definition is applied to heat engine, refrigerator and heat pump. The second law efficiencies of heat engine and refrigeration cycles are derived, which are the same as the existing ones, respectively. The second law efficiency of heat pump, however, finds to be different from the existing one. Discussion is given about the difference and its cause.

The Performance Analysis of Otto Cycle Engine by Thermodynamic Second Law (오토 사이클 기관의 열역학 제 2법칙적 성능 해석)

  • 김성수;노승탁
    • Transactions of the Korean Society of Automotive Engineers
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    • v.9 no.6
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    • pp.94-102
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    • 2001
  • The thermodynamic second law analysis, which means available energy or exergy analysis, for the indicated performance of Otto cycle engine has been carried out. Each operating process of the engine is simplified and modeled into the thermodynamic cycle. The calculation of the lost work and exergy through each process has been done with the thermodynamic relations and experimental data. The experimental data were measured from the test of single cylinder Otto cycle engine which operated at 2500 rpm, WOT(Wide Open Throttle) and MBT(Minimum advanced spark timing for Best Torque) condition with different fuels: gasoline, methanol and mixture of butane-methanol called M90. Experimental data such as cylinder pressure, air and fuel flow rate, exhaust gas temperature, inlet gas temperature and etc. were used for the analysis. The proposed model and procedure of the analysis are verified through the comparison of the work done in the study with experimental results. The calculated results show that the greatest lost work is generated during combustion process. And the lost work during expansion, exhaust, compression and induction process follows in order.

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A Comment on Presentation Order of Thermodynamic Laws for Undergraduate Mechanical-Engineering Education by Example Problems (예제를 통해 본 학부 기계공학 교육에서 열역학 법칙의 소개 순서에 대한 논평)

  • Park, Kyoung Kuhn
    • Journal of Engineering Education Research
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    • v.21 no.2
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    • pp.3-6
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    • 2018
  • A few thermodynamics texts are commonly found to have unrealistic example problems in which the process violates the second law of thermodynamics. This error would result from presentation order in the text which introduces first the first law for cycles, systems, and control volumes and then the second law later. In the presentation order, the example problems deal only with the first law without telling whether the process violates the second law. To correct this erroneous situation, it could be recommended to present the first law and the second law successively so that both laws could be applied simultaneously to the given example problems.

A Second-Law Analysis of the Energy Consumption in Heating and Cooling Systems (냉난방에 소비되는 에너지절약에 관한 열역학 연구)

  • Bae, Sun-Hun
    • The Magazine of the Society of Air-Conditioning and Refrigerating Engineers of Korea
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    • v.3 no.3
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    • pp.180-184
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    • 1974
  • From the point of view of the second law of thermodynamics, house heating and cooling systems were analysed for saving energy. The analysis provides a theoretical basis for the heat-pump application. Also the efficiency of energy use is defined more rigorously by comparing the thermodynamic availability actually consumed in heating and cooling with the minimum thermodynamic availability required to do the same heating and cooling. It was found that the present 'Ondol' heating system has a heating efficiency of around $8\%$ according to the definition described here. Several schemes to inprove the efficiency are presented.

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First and Second Law Analysis of Water-to-Water Heat Pump System (물-물 열펌프시스템에 관한 열역학 제1 및 제2 법칙 해석)

  • Lee, Se-Kyoun;Woo, Joung-Son;Ro, Jeong-Geun
    • Journal of the Korean Solar Energy Society
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    • v.27 no.4
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    • pp.87-95
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    • 2007
  • Thermodynamic analysis of water-to-water heat pump system based on the first and second law of thermodynamics is carried out in this study. This analysis shows the distribution of irreversibilities throughout the system components and informs us of a potential improvements with the temperature condition changes. Source water temperature($T_A$), utilization water temperature($T_D$) and temperature differences (${\Delta}T_{AB}$, ${\Delta}T_{CD}$) are important factors to affect system performances such as component irreversibilities, exergetic efficiency and COPH. Advantages and disadvantages with these factors are discussed. Second law optimization phenomena with $T_A$ and ${\Delta}T_{AB}$ are also indicated.

ICE GROSS HEAT RELEASE STRONGLY INFLUENCED BY SPECIFIC HEAT RATIO VALVES

  • Lanzafame, R.;Messina, M.
    • International Journal of Automotive Technology
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    • v.4 no.3
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    • pp.125-133
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    • 2003
  • Several models for the evaluation of Gross Heat Release from the internel combustion engine (ICE) are often used in literature. One of these is the First Law - Single Zone Model (FL-SZM), derived from the First Law of Thermodynamic. This model present a twice advantage: first it describes with accuracy the physic of the phenomenon (charge heat release during the combustion stroke and heat exchange between gas and cylinder wall); second it hat a great simplicity in the mathematical formulation. The evaluation of Heat Release with the FL-SZM is based on pressure experimental measurements inside the cylinder, and ell the assumption of several parameters as the specific heat ratio, wall temperature, polytropic exponent for the motored cycle evaluation, and many others. In this paper the influence of gases thermodynamic properties on Cross Heat Release has been esteemed. In particular the influence of an appropriate equation for k=k(T) (specific heat ratio vs. temperature) which describes the variations of gases thermodynamic properties with the mean temperature inside the cylinder has been evaluated. This equation has been calculated by new V order Logarithmic Polynomials (VoLP), fitting experimental gases properties through the least square methods.

Performance analysis of an organic Rankine cycle for ocean thermal energy conversion system according to pinch point temperature difference (핀치포인트온도차에 따른 해양온도차발전용 유기랭킨사이클의 성능분석)

  • Kim, Jun-Seong;Kim, Do-Yeop;Kang, Ho-Keun;Kim, You-Taek
    • Journal of Advanced Marine Engineering and Technology
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    • v.40 no.6
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    • pp.476-483
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    • 2016
  • An organic Rankine cycle for ocean thermal energy conversion system is a generating cycle using the temperature difference between surface water and deep water of the ocean. The working fluid is an important factor in the thermodynamic performance of an organic Rankine cycle. There is pinch point analysis as thermodynamic analysis of an organic Rankine cycle. This study performed a thermodynamic performance analysis according to variation in the pinch point temperature difference in heat exchangers and variation of outlet temperature of heat source and heat sink. It analyzed the thermodynamic performance by applying seven types of simple working fluids in a simple Rankine cycle for ocean thermal energy conversion that was designed according to pinch point analysis. As a result of the performance analysis, cycle irreversibility and total exergy destruction factor more decreased, and second law efficiency more increased in the lower pinch point temperature difference and temperature variation of heat source and heat sink in heat exchangers. In addition, the irreversibility changed greatly at a point that occurred in the thermodynamic variation. Among the selected working fluids, RE245fa2 showed the best thermodynamic performance, and the performance of all working fluids was observed to be similar. It needs a strict theoretical basis about diverse factors with thermodynamic performances in selecting heat exchangers and working fluids.

Characteristics of Thermodynamic Performance of Heat Exchanger in Organic Rankine Cycle Depending on Pinch Temperature Difference (유기랭킨사이클에서 핀치온도차의 변화에 따른 열교환기의 열역학적 성능특성)

  • KIM, KYOUNG HOON;JUNG, YOUNG GUAN;PARK, SANG HEE
    • Transactions of the Korean hydrogen and new energy society
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    • v.26 no.6
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    • pp.590-599
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    • 2015
  • In this paper a performance analysis is carried out based on the first and second laws of thermodynamics for heat exchanger in organic Rankine cycle (ORC) for the recovery of low-temperature finite thermal energy source. In the analysis, effects of the selection of working fluid and pinch temperature difference are investigated on the performance of the heat exchanger including the effectiveness of the heat exchanger, exergy destruction, second-law efficiency, number of transfer unit (NTU), and pinch point. The temperature distribution are shown depending on the working fluids and the pinch temperature difference. The results show that the performance of the heat exchanger depends on the pinch temperature difference sensitively. As the pinch temperature increases, the exergy destruction in the evaporator increases but the effectiveness, second law efficiency and NTU decreases.

Exergy Analysis of Regenerative Ammonia-Water Rankine Cycle for Use of Low-Temperature Heat Source (저온열원 활용을 위한 암모니아-물 재생 랭킨사이클의 엑서지 해석)

  • Kim, Kyoung-Hoon;Ko, Hyung-Jong;Kim, Se-Woong
    • Transactions of the Korean hydrogen and new energy society
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    • v.23 no.1
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    • pp.65-72
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    • 2012
  • Rankine cycle using ammonia-water mixture as a working fluid has attracted much attention, since it may be a very useful device to extract power from low-temperature heat source. In this work, the thermodynamic performance of regenerative ammonia-water Rankine cycle is thoroughly investigated based on the second law of thermodynamics and exergy analysis, when the energy source is low-temperature heat source in the form of sensible energy. In analyzing the power cycle, several key system parameters such as ammonia mass concentration in the mixture and turbine inlet pressure are studied to examine their effects on the system performance including exergy destructions or anergies of system components, efficiencies based on the first and second laws of thermodynamics. The results show that as the ammonia concentration increases, exergy exhaust increases but exergy destruction at the heat exchanger increases. The second-law efficiency has an optimum value with respect to the ammonia concentration.

Availability of Energy and Reconstruction of Thermodynamics(I) Thermodydamics of the Reversible World (에너지의 가용성과 열역학의 재구성 (I) 가역세계 열역학)

  • 정평석;노승탁
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.17 no.5
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    • pp.1227-1236
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    • 1993
  • In conventional thermodynamics, energy is regarded as a physical quantity transferring from one system to another, but in present study, the real energy is regarded as a physical quantity coming out from one interaction and absorbing into another interaction between two systems. To reconstruct thermodynamics with such a point of view, available work is distinguished from half work in conventional work concepts, and a special space named reversible world is proposed in which every process is reversible and the only measurable quantity is available work and just the equality between the intensities of two systems can be verified. As results, thermodynamic laws are arranged into two principles in the reversible world-conservations of energy elements and conservation of available energy. It means the exsistences of state properties corresponding to transferring energy elements and the available work. The former are extensive properties and the later is named potential work which is a property of the composite system and a kind of mathematical distance. The conventional available energy (exergy) and internal energy can be explained as the special cases of potential work, and the conventional first law of thermodynamics can be derived from the principle of the conservation of available energy. With these new concepts, the description of thermodynamic processes is more comprehensive. The second law of thermodynamics is no longer needed in the reversible world.