• 설비공학논문집
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• 제24권11호
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• pp.792-798
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• 2012

A general concept on the definition of the second law efficiencies of thermodynamic cycles is introduced. The efficiency is defined to be proportional to the entropy generation divided by the maximum possible entropy generation. This way of definition of the cycle efficiency is clear and concise and, moreover, follows faithfully the concept of the second law of thermodynamics. This definition is applied to heat engine, refrigerator and heat pump. The second law efficiencies of heat engine and refrigeration cycles are derived, which are the same as the existing ones, respectively. The second law efficiency of heat pump, however, finds to be different from the existing one. Discussion is given about the difference and its cause.

• 한국자동차공학회논문집
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• 제9권6호
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• pp.94-102
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• 2001

The thermodynamic second law analysis, which means available energy or exergy analysis, for the indicated performance of Otto cycle engine has been carried out. Each operating process of the engine is simplified and modeled into the thermodynamic cycle. The calculation of the lost work and exergy through each process has been done with the thermodynamic relations and experimental data. The experimental data were measured from the test of single cylinder Otto cycle engine which operated at 2500 rpm, WOT(Wide Open Throttle) and MBT(Minimum advanced spark timing for Best Torque) condition with different fuels: gasoline, methanol and mixture of butane-methanol called M90. Experimental data such as cylinder pressure, air and fuel flow rate, exhaust gas temperature, inlet gas temperature and etc. were used for the analysis. The proposed model and procedure of the analysis are verified through the comparison of the work done in the study with experimental results. The calculated results show that the greatest lost work is generated during combustion process. And the lost work during expansion, exhaust, compression and induction process follows in order.

• 공학교육연구
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• 제21권2호
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• pp.3-6
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• 2018

A few thermodynamics texts are commonly found to have unrealistic example problems in which the process violates the second law of thermodynamics. This error would result from presentation order in the text which introduces first the first law for cycles, systems, and control volumes and then the second law later. In the presentation order, the example problems deal only with the first law without telling whether the process violates the second law. To correct this erroneous situation, it could be recommended to present the first law and the second law successively so that both laws could be applied simultaneously to the given example problems.

• 대한설비공학회지:설비저널
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• 제3권3호
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• pp.180-184
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• 1974

From the point of view of the second law of thermodynamics, house heating and cooling systems were analysed for saving energy. The analysis provides a theoretical basis for the heat-pump application. Also the efficiency of energy use is defined more rigorously by comparing the thermodynamic availability actually consumed in heating and cooling with the minimum thermodynamic availability required to do the same heating and cooling. It was found that the present 'Ondol' heating system has a heating efficiency of around $8\%$ according to the definition described here. Several schemes to inprove the efficiency are presented.

• 한국태양에너지학회 논문집
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• 제27권4호
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• pp.87-95
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• 2007

Thermodynamic analysis of water-to-water heat pump system based on the first and second law of thermodynamics is carried out in this study. This analysis shows the distribution of irreversibilities throughout the system components and informs us of a potential improvements with the temperature condition changes. Source water temperature($T_A$), utilization water temperature($T_D$) and temperature differences (${\Delta}T_{AB}$, ${\Delta}T_{CD}$) are important factors to affect system performances such as component irreversibilities, exergetic efficiency and COPH. Advantages and disadvantages with these factors are discussed. Second law optimization phenomena with $T_A$ and ${\Delta}T_{AB}$ are also indicated.

• International Journal of Automotive Technology
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• 제4권3호
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• pp.125-133
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• 2003

Several models for the evaluation of Gross Heat Release from the internel combustion engine (ICE) are often used in literature. One of these is the First Law - Single Zone Model (FL-SZM), derived from the First Law of Thermodynamic. This model present a twice advantage: first it describes with accuracy the physic of the phenomenon (charge heat release during the combustion stroke and heat exchange between gas and cylinder wall); second it hat a great simplicity in the mathematical formulation. The evaluation of Heat Release with the FL-SZM is based on pressure experimental measurements inside the cylinder, and ell the assumption of several parameters as the specific heat ratio, wall temperature, polytropic exponent for the motored cycle evaluation, and many others. In this paper the influence of gases thermodynamic properties on Cross Heat Release has been esteemed. In particular the influence of an appropriate equation for k=k(T) (specific heat ratio vs. temperature) which describes the variations of gases thermodynamic properties with the mean temperature inside the cylinder has been evaluated. This equation has been calculated by new V order Logarithmic Polynomials (VoLP), fitting experimental gases properties through the least square methods.

• Journal of Advanced Marine Engineering and Technology
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• 제40권6호
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• pp.476-483
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• 2016

해양온도차발전용 유기랭킨사이클은 해양의 표층수와 심층수사이의 온도차를 이용하여 발전하는 사이클이다. 작동유체는 유기랭킨사이클의 열역학적 성능에 있어 중요한 요소이다. 유기랭킨사이클의 열역학적 분석방법으로 핀치포인트분석이 있다. 본 연구는 열교환기내 핀치포인트온도차의 변화와 열원 및 열침의 출구온도의 변화에 따른 열역학적 성능분석을 수행하였다. 핀치포인트분석법에 따라 설계한 해양온도차발전용 단순랭킨사이클에 7종의 단일 작동유체를 적용하여 열역학적 성능을 분석하였다. 성능분석결과 열교환기에서 핀치포인트온도차와 열원 및 열침의 온도변화가 작을수록 사이클 총 비가역성 및 총 엑서지 파괴인자가 감소하였으며, 제2법칙 효율은 상승하였다. 또한 비가역성은 열역학적 변화가 발생한 곳에서 크게 변화하였다. RE245fa2는 선정한 작동유체 중에서 가장 우수한 열역학적 성능을 보여주었으며, 모든 작동유체의 성능은 유사하였다. 열교환기 및 작동유체 선정에 있어 열역학적 성능과 함께 다양한 요소들에 대해서도 엄밀한 이론적 근거가 필요하다.

• 한국수소및신에너지학회논문집
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• 제26권6호
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• pp.590-599
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• 2015

In this paper a performance analysis is carried out based on the first and second laws of thermodynamics for heat exchanger in organic Rankine cycle (ORC) for the recovery of low-temperature finite thermal energy source. In the analysis, effects of the selection of working fluid and pinch temperature difference are investigated on the performance of the heat exchanger including the effectiveness of the heat exchanger, exergy destruction, second-law efficiency, number of transfer unit (NTU), and pinch point. The temperature distribution are shown depending on the working fluids and the pinch temperature difference. The results show that the performance of the heat exchanger depends on the pinch temperature difference sensitively. As the pinch temperature increases, the exergy destruction in the evaporator increases but the effectiveness, second law efficiency and NTU decreases.

• 한국수소및신에너지학회논문집
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• 제23권1호
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• pp.65-72
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• 2012

Rankine cycle using ammonia-water mixture as a working fluid has attracted much attention, since it may be a very useful device to extract power from low-temperature heat source. In this work, the thermodynamic performance of regenerative ammonia-water Rankine cycle is thoroughly investigated based on the second law of thermodynamics and exergy analysis, when the energy source is low-temperature heat source in the form of sensible energy. In analyzing the power cycle, several key system parameters such as ammonia mass concentration in the mixture and turbine inlet pressure are studied to examine their effects on the system performance including exergy destructions or anergies of system components, efficiencies based on the first and second laws of thermodynamics. The results show that as the ammonia concentration increases, exergy exhaust increases but exergy destruction at the heat exchanger increases. The second-law efficiency has an optimum value with respect to the ammonia concentration.

• 대한기계학회논문집
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• 제17권5호
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• pp.1227-1236
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• 1993

본 연구에서는 또하나의 새로운 서술방식을 제시하게 되는데, 먼저 에너지 이동현상으로서의 일중에서 가용일을 분리하고, 가역과정만이 가능한 세계 즉 가역세 계 안에서 측정과 산정이 가능하도록 열역학의 가장 중요한 물리량인 온도와 엔트로피, 열 등을, 가용일의 가측성을 이용하여 정의한 다음, 그러한 제한조건하에서 기존 열역 학의 기본 법칙들이 어떻게 표시되는가 살펴보고, 이것을 비가역과정에 확장하는 식의 순서에 따라 열역학의 기존원리들에 대한 서술을 재구성하고자 한다.