• Journal of the Korean Chemical Society
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• v.54 no.2
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• pp.192-197
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• 2010

The spinel compound was obtained by the thermal decomposition of Zn-Co and Zn-Ni gel prepared by sol-gel method using oxalic acid as a chelating agent. The formation of spinel compound has been comfirmed by thermogravimetric analysis (TGA), x-ray powder diffraction (XRD) and infrared spectroscopy (IR). The particle size of 13 nm~16 nm was calculated by Scherrer's equation. The sol-gel method provides a practicable and effective route for the synthesis of the spinel compound at low temperature ($350^{\circ}C$). The kinetic parameters such as activation energy (Ea) and pre-exponential factor (A) for each compound were found by means of the Kissinger method and Arrhenius equation. The decomposition of spinel compound has an activation energy about 155 kJ/mol. Finally, the thermodynamic parameters (${\Delta}G^{\varphi}$, ${\Delta}H^{\varphi}$, ${\Delta}S^{\varphi}$) for decomposition of spinel compound was determined.

• Journal of the Korean Chemical Society
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• v.21 no.6
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• pp.395-403
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• 1977

Significant structure theory was applied to some liquid mixture systems ranging from simple monatomic molecule systems to polyatomic molecule systems, and the activity coefficients ${\gamma}$ of the liquid mixture systems were calculated over whole mole fractions using the following thermodynamic relation $RTln_{{\gamma}i} = (\frac{{\partial A}^E}{{\partial N}_i})_{T,V,N_i} $ where $A^E$ represents the excess Helmholtz free energy, and $N_i$ is the number of molecules of component i. The activity coefficients of the solutions such as monatomic molecule systems (Ar-Kr, Kr-Xe) and diatomic molecule systems $(Ar-O_2,\;N_2-CO)$ and $CH_4-Kr$ systems whose components have similar shapes for intermolecular potential curves were calculated successfully only with the ${\delta}E_s$, correction parameter for energy $E_s$, for mixture systems. For other systems such as $Ar-N_2,\;O_2-N_2\;and\;CH_4-C_3H_8$ whose components have dissimilar intermolecular potential curve shapes an additional correction parameters ${\delta}$V and even one more parameter ${\delta}$n were necessary [see Eqs.(10)∼(12)].

• Journal of the Korean Society for Marine Environment & Energy
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• v.12 no.3
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• pp.217-226
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• 2009

Marine geological storage of $CO_2$ is regarded as one of the most promising options to response climate change. Marine geological storage of $CO_2$ is to capture $CO_2$ from major point sources, to transport to the storage sites and to store $CO_2$ into the marine geological structure such as deep sea saline aquifer. Up to now, process design for this $CO_2$ marine geological storage has been carried out mainly on pure $CO_2$. Unfortunately the captured $CO_2$ mixture contains many impurities such as $N_2$, $O_2$, Ar, $H_2O$, $SO_x$, $H_2S$. A small amount of impurities can change the thermodynamic properties and then significantly affect the compression, purification and transport processes. In order to design a reliable $CO_2$ marine geological storage system, it is necessary to perform numerical process simulation using thermodynamic equation of state. The purpose of the present paper is to compare and analyse the relevant equations of state including PR, PRBM, RKS and SRK equation of state for $CO_2-N_2$ mixture. To evaluate the predictive accuracy of the equation of the state, we compared numerical calculation results with reference experimental data. In addition, optimum binary parameter to consider the interaction of $CO_2$ and $N_2$ molecules was suggested based on the mean absolute percent error. In conclusion, we suggest the most reliable equation of state and relevant binary parameter in designing the $CO_2-N_2$ mixture marine geological storage process.

• Bulletin of the Korean Chemical Society
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• v.34 no.12
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• pp.3727-3732
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• 2013

The interaction between metalloporphyrins and diazine tautomers was investigated using quantum chemistry method. The results showed that the metal atom in the metalloporphyrin was not coplanar with porphin ring, and zinc porphyrin has the most extent of its non-coplanar nature. The most stable complex in nine complexes was iron porphyrin. NBO analysis indicated that the interaction between the lone pair of electrons on the nitrogen atom and the unoccupied lone pair orbital of metal contributes significantly to the stability of the complexes. Through the conceptual DFT parameter and Fukui dual descriptor, the thermodynamic stability and reactivity of complexes were analyzed. The density difference function (DDF) analyzes were performed to explore the rearrangement of electronic density after the coordination interaction. NICS calculation indicated that metalloporphyrin aromaticity was reduced after the coordination interaction, and aromaticity of diazine tautomer was increased along direction vector of the coordination interaction force.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.26 no.7
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• pp.919-926
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• 2002

Down scaled combustor undergoes increased heat loss that results in incomplete combustion or quenching of the flame as a consequence. Therefore, effect of enhanced heat loss should be understood to design a MEMS scale combustion devices. Existing combustion models are inadequate for micro combustors because they were developed for analysis of regular scale combustor where heat loss can be ignored during the flame propagation. In this research a combustion model is proposed in order to estimate the heat loss and predict quenching limit of flame in a down scaled combustor. Heat loss in the burned region is expressed in a convective form as a product of wall surface area, heat transfer coefficient and temperature difference. Comparison to the measurements showed satisfactory agreement of the pressure and temperature drop. Quenching is accounted for by introducing a correlation of quenching parameter and heat loss. The present model predicted burnt fraction of gases with reasonable accuracy and proved to be applicable in thermal design of a micro combustor.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.22 no.11
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• pp.1635-1646
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• 1998

The present study investigated the effects of geometric parameters considered on the performance of an automotive scroll compressor by assuming ideal, semi-real and real gases for R-134a. The geometric parameters were center thickness of scroll, height of scroll and the size of discharge port. Fourth-order Runge-Kutta method was applied to solve the thermodynamic equations, leaking rate equation and the equation of motion of discharge valve for ideal, semi-real, and real gases. The volumetric and adiabatic efficiencies for semi-real and real gases differed little, but those for ideal gas differed by 18% and 25% compared with those for real gas at 2,000rpm. The volumetric efficiency changed little as the design angle of scroll (${\gamma}$) changed, but the adiabatic efficiency at ${\gamma}$ of $34^{\circ}$ was higher by 2.4% than that of $147^{\circ}$ for 2,000rpm. The volumetric and adiabatic efficiencies at scroll height of 29.8mm were higher by 1.7% and 2.8% than those of 65.8mm. The volumetric efficiency changed little as the size of discharge port changed, but the adiabatic efficiency increased a little as the size of discharge port decreased.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.23 no.11
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• pp.718-725
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• 2011

Characteristics of flow boiling heat transfer in microchannels were investigated experimentally. The microchannels consisted of 9 parallel trapezoidal channels with each channel having 205 ${\mu}m$ of bottom width, 800 ${\mu}m$ of depth, $3.6^{\circ}$ of sidewall angle, and 7 cm of length. Tests were performed with R113 over a mass velocity range of 150~920 $kg/m^2s$, heat flux of 10~100 $kW/m^2$ and inlet pressures of 105~195 kPa. Flow boiling heat transfer coefficient in microchannels was found to be dominated by heat-flux. However the effect of mass velocity was not significant. Contrary to macrochannel trends, the heat transfer coefficient was shown to decrease with increasing thermodynamic equilibrium quality. A new correlation suitable for predicting flow boiling heat transfer coefficient was developed based on the laminar single-phase heat transfer coefficient and the nucleate boiling dominant equation. Comparison with the experimental data showed good agreement.

• Transactions of the Korean hydrogen and new energy society
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• v.23 no.4
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• pp.404-411
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• 2012

This research numerically analyses the effects of the damping device on the operation characteristics of a free piston linear engine. In this paper, the free piston linear engine uses spring as a damping device. The investigated parameter is spring hardness which is varied at 0.5, 1, 2.9, and 14.7 N/mm. The effects of spring hardness on the dynamic characteristic, thermodynamic characteristic and electric power of the engine are investigated. Beside, the equivalent ratio is also changed to provide more information for this study. The simulation results show that, by increasing spring hardness from 0.5 to 14.7 N/mm, all of parameters related to dynamic characteristic such as piston velocity, acceleration, displacement, and frequency increase accordingly. Beside, the peak pressure in the cylinder and electric power are also increased when increasing spring hardness. The tendency is also observed at varied equivalent ratios.

• Journal of the Korean Chemical Society
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• v.36 no.3
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• pp.376-382
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• 1992

Liquid helium is an exciting subject for the study of thermodynamic and transport properties because of its remarkable properties. The viscosity of liquid helium exhibits the abnormal behavior compared to other ordinary liquid. Below the $\lambda$ point liquid $^4He$ becomes superfluid, and it is obviously quite a different phenomenon from the change of liquid $^3He$. The brake theory of viscosity proposed by authors is successfully applied to liquid $^3He$, liquid $^4He$, dense gas and 4He with adjustable parameter $V_s$. The calculation results are satisfactory compared with the observed values.

• Journal of the Korean Chemical Society
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• v.41 no.4
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• pp.198-204
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• 1997

The rate constants for the hydrolysis of N-(2,4-dinitrophenyl)benzhydrazonyl bromide and its derivatives were determined by ultraviolet visible spectrophotometry at 20$^{\circ}C$ and a rate equation which could be applied over a wide pH range was obtained. On the basis of rate equations derived and judging from the solvent effect, substituent effect, salt effect, thermodynamic parameter, plausible mechanisms of hydrolysis have been proposed. It may be concluded that the hydrolysis through SN1 mechanism via carbonium ion intermdiate to pH 3.0, and pH 10.0, the hydrolysis proceeds through 1,3-dipolar or SN2 mechanism.