• 대한화학회지
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• 제55권3호
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• pp.364-372
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• 2011

다양한 억제제의 농도, 온도, 유속에서 중량 분석과 변전위 분극법을 이용하여 0.25 M 황산 용액상에 있는 연강철에 대한 imatinib mesylate (IMT)의 부식 억제를 연구하였다. 억제제의 농도가 증가함에 따라 억제 효과가 증가한다는 결과를 얻었다. 연강철 표면 위의 흡착 과정은 Langmuir 흡착 등온선을 따른다. 얻어진 흡착 깁스 자유 에너지의 값은 연강철 위의 IMT의 흡착 과정이 화학흡착이라는 것을 보여준다. 열역학 변수들이 계산되고, 논의되었다. IMT의 HOMO와 LUMO의 전자궤도 밀도 분포는 억제 메커니즘을 논의하는데 이용되었다. FT-IR 분광학과 SEM 이미지는 필름에 흡착된 표면을 분석하기 위해 사용되었다.

• 유체기계공업학회:학술대회논문집
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• 유체기계공업학회 1998년도 유체기계 연구개발 발표회 논문집
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• pp.209-214
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• 1998

A thermodynamic simulation method is developed for the process design and the performance evaluation of the gas turbine in IGCC power plant. The present study adopts four clean coal gases derived from four different coal gasification and gas clean-up processes as IGCC gas turbine fuel, and considers the integration design condition of the gas turbine with ASU(Air Separation Unit). In addition, the present simulation method includes compressor performance map and expander choking models for considering the off-design effects due to coal gas firing and ASU integration. The present prediction results show that the efficiency and the net power of the IGCC gas turbines are seperior to those of the natural gas fired one but they are decreased with the air extraction from gas turbine to ASU. The operation point of the IGCC gas turbine compressor is shifted to the higher pressure ratio condition far from the design point by reducing the air extraction ratio. The exhaust gas of the IGCC gas turbine has more abundant wast heat for the heat recovery steam generator than that of the natural gas fired gas turbine.

• Journal of Advanced Marine Engineering and Technology
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• 제35권4호
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• pp.388-396
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• 2011

온실가스 및 대기오염물질 배출 규제는 고효율 및 친환경에 적합한 새로운 선박용 동력장치의 필요성을 제기하고 있다. 최근 이와 같은 문제들을 근본적으로 해결하기 위한 지속가능한 방법으로서 연료전지를 선박의 동력발생장치로 도입하고자 하는 검토가 진행되고 있다. 본 논문은 선박용 연료전지시스템에 사용될 수 있는 최적의 연료를 파악하기 위하여 다양한 탄화수소계 및 알코올계 연료의 수증기 개질특성을 열역학적으로 검토하고 있다.

• 한국자동차공학회논문집
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• 제2권1호
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• pp.38-50
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• 1994

To improve the efficiency of internal combustion engines, it is necessary to understand mixed air-fuel in-cylinder flow processes accurately at intake and compression strokes. There is experimental and numerical methods to analyse in-cylinder flow process. In numerical method, standard $k-{\varepsilon}$ model with wall function was mostly adopted in in-cylinder flow process. But this type model was not efficiently predicted in the near wall region. Therefore in the present study, low Reynolds number $k-{\varepsilon}$ model was adopted near the cylinder wall and standard $k-{\varepsilon}$ model in other region. Also QUICK scheme was used for convective difference scheme. This study takes axisymmetric reciprocating model engine motored at 200rpm with a centrally located valve, incorporated 60 degree seat angie, and flat piston surface excluding inlet port. Because in-cylinder flow processes are undergoing unsteady and compressible, averaged cylinder pressure and inlet velocity at arbitrary crank angle are determined from thermodynamic analytic method and incylinder states at that crank angle are iteratively determined from the numerical analytic method.

• International Journal of Air-Conditioning and Refrigeration
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• 제7권
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• pp.55-68
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• 1999

In this study, computer simulation programs were developed for single-stage, two-stage, and three-stage condensation heat pumps and their performance with CFC11, HCFC123, HCFC141b was examined under the same external conditions. The results showed that the coefficient of performance(COP) of an optimized 'non-split type' three-stage condensation heat pump is 25-42% higher than that of a conventional single-stage heat pump. The increase in COP, however, differed among the fluids tested. The improvement in COP is largely due to the decrease in average LMTDs in condensers, which results in the decrease in thermodynamic irreversibility in heat exchange process. For the three-stage heat pump, the highest COP is achieved when the total condenser area is evenly distributed among the three condensers. For the two-stage heat pump, however, the optimum distribution of the total condenser area varies with an individual working fluid. For the three-stage system, 'splitting the condenser cooling water'for the use of intermediate and high pressure subcoolers helps increase the COP further. When the individual cooling water entering the intermediate and high pressure subcoolers is roughly 10% of the total condenser cooling water, the maximum COP is achieved showing roughly an 11% increase in COP as compared to that of the 'non-split type' heat pump.

• 한국태양에너지학회:학술대회논문집
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• 한국태양에너지학회 2009년도 춘계학술발표대회 논문집
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• pp.8-12
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• 2009

The Knowledge of the solar radiation components are essential for modeling many solar energy systems. This is particularly the case for applications that concentrate the incident energy to attain high thermodynamic efficiency achievable only at the higher temperatures. In order to estimate the performance of concentrating thermal systems, it is necessary to know the intensity of the beam radiation, as only this component can be concentrated. The Korea Institute of Energy Research(KIER) has began collecting solar radiation component data since August, 2002. KIER's component data will be extensively used by concentrating system users or designers as well as by research institutes. The Result of analysis shows that the annual-average daily diffuse radiation on the horizontal surface is $1,458cal/m^2$ and daily direct radiation on the horizontal surface is $1,632cal/m^2$ for all over the 16 areas in Korea.

• 한국수소및신에너지학회논문집
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• 제23권1호
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• pp.65-72
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• 2012

Rankine cycle using ammonia-water mixture as a working fluid has attracted much attention, since it may be a very useful device to extract power from low-temperature heat source. In this work, the thermodynamic performance of regenerative ammonia-water Rankine cycle is thoroughly investigated based on the second law of thermodynamics and exergy analysis, when the energy source is low-temperature heat source in the form of sensible energy. In analyzing the power cycle, several key system parameters such as ammonia mass concentration in the mixture and turbine inlet pressure are studied to examine their effects on the system performance including exergy destructions or anergies of system components, efficiencies based on the first and second laws of thermodynamics. The results show that as the ammonia concentration increases, exergy exhaust increases but exergy destruction at the heat exchanger increases. The second-law efficiency has an optimum value with respect to the ammonia concentration.

• 한국수소및신에너지학회논문집
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• 제29권2호
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• pp.148-154
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• 2018

This paper presents a comparative analysis of thermodynamic performance of ammonia-water Rankine cycles with and without regeneration and Kalina cycle for recovery of low-temperature heat source. Special attention is paid to the effect of system parameters such as ammonia mass fraction and turbine inlet pressure on the characteristics of the system. Results show that maximum net power can be obtained in the regenerative Rankine cycle for high turbine inlet pressures. However, Kalina cycle shows better net power and thermal efficiency for low turbine inlet pressures, and the optimum ammonia mass fractions of Kalina cycle are lower than Rankine cycles.

• 한국전산유체공학회:학술대회논문집
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• 한국전산유체공학회 2007년도 추계 학술대회논문집
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• pp.249-257
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• 2007

A high resolution numerical method aimed at solving gas-liquid two-phase flow is proposed and applied to gas-liquid two-phase shock tube problem. The present method employs a finite-difference 4th-order Runge-Kutta method and Roe's flux difference splitting approximation with the MUSCL TVD scheme. By applying the homogeneous equilibrium cavitation model, the present density-based numerical method permits simple treatment of the whole gas-liquid two-phase flow field, including wave propagation and large density changes. The speed of sound for gas-liquid two-phase media is derived on the basis of thermodynamic relations and compared with that by eigenvalues. By this method, a Riemann problem for Euler equations of one dimensional shock tube was computed. Numerical results such as detailed observations of shock and expansion wave propagations through the gas-liquid two-phase media and some data related to computational efficiency are made. Comparisons of predicted results and exact solutions are provided and discussed.

• 한국전산유체공학회지
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• 제12권2호
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• pp.53-62
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• 2007

A high resolution numerical method aimed at solving cavitating flow is proposed and applied to gas-liquid two-phase shock tube problem. The present method employs a finite-difference 4th-order Runge-Kutta method and Roe's flux difference splitting approximation with the MUSCL TVD scheme. By applying the homogeneous equilibrium cavitation model, the present density-based numerical method permits simple treatment of the whole gas-liquid two-phase flow field, including wave propagation and large density changes. The speed of sound for gas-liquid two-phase media is derived on the basis of thermodynamic relations and compared with that by eigenvalues. By this method, a Riemann problem for Euler equations of one dimensional shock tube was computed. Numerical results such as detailed observations of shock and expansion wave propagations through the gas-liquid two-phase media at isothermal condition and some data related to computational efficiency are made. Comparisons of predicted results and exact solutions are provided and discussed.