• Proceedings of the SAREK Conference
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• 2008.06a
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• pp.136-141
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• 2008

Due to environmental concerns $CO_2$ has been reintroduced as a potential candidate to replace HFCs in refrigeration systems since 1990s. In a refrigeration cycle, oil is utilized in lubricating a compressor. However, although oil separators are installed after a compressor oil is prone to leak to the whole system. The mixing of $CO_2$ and oil, even a small amount of oil, the heat transfer performance in heat exchanger deteriorated and the pressure drop inside tube increases. Therefore, it is needed to precisely estimate the mixture thermodynamic properties of $CO_2$-lubricant oil to correctly design a $CO_2$ refrigeration system. The commonly used method in estimating the mixture properties is the mole based weighting model. However, the accuracy of the method can not be assured. In the present study, $CO_2$-lubricant oil mixture properties including viscosity and density were estimated by using the mixture models, based on the equation of state (EOS).

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.12 no.10
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• pp.901-907
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• 2000

The conceptual determination of mixed-refrigerant (MR) for a closed Joule-Thomson cryocooler is described in this paper. The thermodynamic cycle design was mainly considered to develop a cryocooler by using a compressor of domestic air-conditioning unit. The target cooling performance of the designed cryocooler is 10 W around 70 K with less than 5 kJ/kg enthalpy rise. The systematic approach of choosing a proper refrigerant among 20 different kinds of mixture for such cryogenic temperature was introduced in detail. The main components of the cryocooler are compressor, evaporator, oil separator, after-cooler, counterflow heat exchanger, and J-T expansion device. Due to the limitation of the compressor operation range, the temperature after the compression was limited below $117^{\circ}C$ (390 K) and the temperature before compression was restricted above $5^{\circ}C$ (278 K). 20 atm of discharging pressure (high pressure) and less than 3 atm suction pressure (low pressure) were the design conditions. The inlet temperature of a counterflow heat exchanger in the high Pressure side was about 300 K. The proper composition of the mixed refrigerant for the designed J-T cryocooler is 15% mol of$ N_2, 30% mol of $CH_4,\; 30% mol\; of C^2H^ 6,\; 10%\; mol\; of\; C_3H_8\; and \;15%\; mol\; of\; i-C_4H_10$.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.11 no.3
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• pp.349-358
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• 1999

Thermodynamic cycle analysis has been performed to maximize the liquid amount for various hydrogen liquefaction systems using GM(Gifford-McMahon) refrigerator. Since the present authors' previous experiments showed that the liquefaction rate was approximately 5.1mg/s in a direct contact with a commercial GM refrigerator, the purpose of this study is to predict how much the liquefaction rate can be increased in different configurations and with improved heat exchanger performance. The optimal operating conditions have been analytically sought with real properties of normal hydrogen for the single-stage GM precooled L-H(Linde-Hampson) system, the two-stage GM direct contact system, the two-stage GM precooled L-H system and the two-stage helium GM-JT (Joule-Thomson) system. The maximum liquefaction rate has been predicted to be only about 7 times greater than the previous experiment, when the two-stage precooling is employed and the effectiveness of heat exchangers approaches to 99.0%. It is concluded that the liquefaction rate is limited mainly by the cooling capacity of the current GM refrigerators and a larger scale of hydrogen liquefaction is possible with a greater capacity of cryocooler at 60-70 K range.

• Transactions of the Korean hydrogen and new energy society
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• v.23 no.3
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• pp.264-273
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• 2012

In this paper, two types of integrated gasification combined cycle (IGCC) plants using either an air separation unit (ASU) or an ion transport membrane (ITM), which provide the oxygen required in the gasification process, were simulated and their thermodynamic performance was compared. Also, the influence of adopting a pre-combustion $CO_2$ capture in the downstream of the gasification process on the performance of the two systems was examined. The system using the ITM exhibits greater net power output than the system using the ASU. However, its net plant efficiency is slightly lower because of the additional fuel consumption required to operate the ITM at an appropriate operating temperature. This efficiency comparison is based on the assumption of a moderately high purity (95%) of the oxygen generated from the ASU. However, if the oxygen purity of the ASU is to be comparable to that of the ITM, which is over 99%, the ASU based IGCC system would exhibit a lower net efficiency than the ITM based system.

• Nuclear Engineering and Technology
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• v.40 no.2
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• pp.133-138
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• 2008

The use of Supercritical Fluids(SCF) has been proposed for numerous power cycle designs as part of the Generation IV advanced reactor designs, and can provide for higher thermal efficiency. One particular area of interest involves the behavior of SCF during a blowdown or depressurization process. Currently, no data are available in the open literature at supercritical conditions to characterize this phenomenon. A preliminary computational analysis, using a homogeneous equilibrium model when a second phase appears in the process, has shown the complexity of behavior that can occur. Depending on the initial thermodynamic state of the SCF, critical flow phenomena can be characterized in three different ways; the flow can remain in single phase(high temperature), a second phase can appear through vaporization(high pressure low temperature) or condensation(high pressure, intermediate temperature). An experimental facility has been built at the University of Wisconsin to study SCF depressurization through several diameter breaks. The preliminary results obtained show that the experimental data can be predicted with good agreement by the model for all the different initial conditions.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.20 no.11
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• pp.733-738
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• 2008

Due to environmental concerns $CO_2$ has been reintroduced as a potential candidate to replace HFCs in refrigeration systems. Oils are always required in a vapor-compression cycle, and thus it is necessary to precisely estimate the thermodynamic mixture properties of $CO_2$-lubricant oil. In the present study, the density and the viscosity of the mixture was calculated by the Redlich and Kwong type EoS and the modified Peng and Robinson type viscosity EoS, respectively. The viscosity model was based on the similarity between P-v-T and T-$\mu$-P relationships. The predicted results were compared with the experimental data of Pens ado et al. whose test conditions were 100$\sim$650 bar of pressure and 303 K$\sim$353 K of temperature with the $CO_2$-POEs mixtures under 92.2 wt.% and 83.3 wt.% of $CO_2$ concentration. The mean deviations of the mixture density were 7.93% and 8.32% for 92.2 wt.% and 83.3 wt.% of $CO_2$ concentration, respectively. Concerning the viscosity, the mean deviations were 4% and 10% for 92.2 wt.% and 83.3 wt.% of $CO_2$ concentration under the Pensado et al.'s test conditions.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.21 no.10
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• pp.1254-1261
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• 1997

Pulse boiling, the unsteady periodic boiling phenomenon appearing in the evaporator of thermosyphons was investigated by many researchers. In the present study investigations were conducted to examine the evolution of flow patterns at the evaporator, and changes in thermodynamic state that each of liquid pool and vapor experiences through 1 cycle of pulse boiling process. For wall and liquid pool the degree of superheat for the onset of nucleation was examined. It revealed that the degree of superheat increased with the increase of pulse period, reaching to 16.5 deg.C and 23 deg.C for liquid pool and evaporator wall respectively at .tau.=80 sec. The data on flow patterns obtained through series of operation tests were plotted in the coordinates of heat flux and vapor pressure to get a regime map. Further this map could be used to figure out the conditions of pulse boiling for a thermosyphon.

• Journal of Aerospace System Engineering
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• v.11 no.4
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• pp.22-29
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• 2017

A study is performed for the effective detection method of a fault which is occurred during operation in a small turbojet engine with non-linear characteristics used by unmanned air vehicle. For this study the non-linear dynamic model of the engine is derived from transient thermodynamic cycle analysis. Also for inducing real operation conditions the controller is developed associated with unscented Kalman filter to estimate noises. Sequential probability ratio test is introduced as a real time method to detect a fault which is manipulated for simulation as a malfunction of rotational speed sensor contaminated by large amount of noise. The method applied to the fault detection during operation verifies its effectiveness and high feasibility by showing good and definite decision performances of the fault.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.19 no.3
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• pp.353-366
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• 2021

The solubilities of different multicomponent lanthanide oxide (Ln₂O₃) solid solutions including binary (Ln₁ and Ln₂ = La, Nd, Eu, or Tm), ternary (Ln₁, Ln₂, and Ln₃ = La, Nd, Eu, or Tm), and higher systems (Ln = La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu) were studied after aging for four weeks at 60℃. Our recent study revealed that the phase transformations in binary ((La, Nd) and (La, Eu)) and ternary (La, Nd, Eu) systems are responsible for the formation of (La, Nd)(OH)₃, (La, Eu)(OH)₃, and (La, Nd, Eu)(OH)₃ solid solutions, respectively. The variations in the mole fractions of La³⁺, Nd³⁺, and Eu³⁺ in the sample solutions of these hydroxide solid solutions indicated that a thermodynamic equilibrium might account for the apparent La, Nd, and Eu solubilities. Conversely, the binary and ternary systems containing Tm₂O₃ as the heavy lanthanide oxide retained the oxide-based solid solutions, and their solubility behaviors were dominated by their congruent dissolutions. In the higher multicomponent system, the X-ray diffraction patterns of the solid phases, before and after contact with the aqueous phase indicated the formation of a stable oxide solid solution and their solubility behavior was explained by its congruent dissolution.

• Membrane and Water Treatment
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• v.13 no.6
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• pp.321-335
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• 2022

Copper-based Metal-organic framework (MOF) namely ([Cu (INA)₂]-MOF) is synthesized by ball milling and characterized using scanning electron microscopy (SEM) for the topography, microstructure, and elemental evidence determination, powdered X-ray diffraction (XRD) for the crystallinity measurement, thermogravimetric (TG) analysis was performed to determine the thermal stability of the material, and Fourier transformed infrared (FTIR) spectroscopy for functional groups identification. The use of [Cu (INA)₂]-MOF as hazardous removal material of β-agonists as persistent hazardous micro-pollutants in our environmental water is first reported in this study. The removal efficiency of the Cu-MOF is successfully determined to be 97.7% within 40 minutes, and the MOF has established an exceptional removal capacity of 835 mg L^-1 with 95 % percent removal on Clenbuterol (CLB) even after the 5th consecutive cycle. The Langmuir model of the adsorption isotherms was shown to be more favourable, while the pseudo-second-order model was found to be favoured in the kinetics. The reaction was exothermic and spontaneous from a thermodynamic standpoint, and the higher temperatures were unfavourable for the adsorption study of the CLB. As a result, the studied MOF have shown promising properties as possible adsorbents for the removal of CLB in wastewater.