• 제목/요약/키워드: Thermodynamic Characteristics

검색결과 355건 처리시간 0.029초

열기계적 분석법으로 측정된 레진 포뮬레이션의 경화 수축 특성 (Cure Shrinkage Characteristics of Resin Formulations by Thermomechanical Analysis)

  • 서안나;이종현
    • 대한금속재료학회지
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    • 제50권9호
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    • pp.629-636
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    • 2012
  • Volume shrinkage behavior accompanying the cure of resin formulations might be a critical factor when assembly processes using polymer materials are considered. In this study, cure shrinkage behavior with respect to resin formulation type and heating method was measured on sandwich structure samples by a thermomechanical analyzer (TMA). Quartz, used as a cover material for the sandwich structure, indicated the coefficient of thermal expansion close to $0ppm/^{\circ}C$. When a dynamic heating mode was conducted, a squeeze-out region and a cross-linking region for each resin formulation could be separated clearly with overlapping differential scanning calorimeter results on the TMA results. In addition, a cure shrinkage dominant region and a thermal expansion dominant region in the cross-linking region were distinguished. Consequently, the degree of cure at the initiation of the thermal expansion dominant region was successfully measured. Measurement of all resin formulations indicated the thermal expansion behavior exceeded cure shrinkage before full cure.

Hydrogenation Properties of MgH2-CaO Composites Synthesized by Hydrogen-Induced Mechanical Alloying

  • Kim, Min Gyeom;Han, Jeong-Heum;Lee, Young-Hwan;Son, Jong-Tae;Hong, Tae Whan
    • 대한금속재료학회지
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    • 제56권11호
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    • pp.829-834
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    • 2018
  • Although magnesium-based alloys are attractive materials for hydrogen storage applications, their activation properties, hydrogenation/dehydrogenation kinetics, thermodynamic equilibrium parameters, and degradation characteristics must be improved for practical applications. Further, magnesium poses several risks, including explosion hazard, environmental pollution, insufficient formability, and industrial damage. To overcome these problems, CaO-added Mg alloys, also called Eco-Mg (environment-conscious Mg) alloys, have been developed. In this study, $Eco-MgH_x$ composites were fabricated from Mg-CaO chips by hydrogen-induced mechanical alloying in a high-pressure atmosphere. The balls-to-chips mass ratio (BCR) was varied between a low and high value. The particles obtained were characterized by X-ray diffraction (XRD), and the absorbed hydrogen was quantified by thermogravimetric analysis. The XRD results revealed that the $MgH_2$ peaks broadened for the high BCR. Further, PSA results revealed particles size were decreased from $52{\mu}m$ to $15{\mu}m$.

이중연소 램제트 엔진의 예비 성능해석 (Preliminary Performance Analysis of a Dual Combustion Ramjet Engine)

  • 변종렬;안중기;윤현걸;임진식
    • 한국추진공학회:학술대회논문집
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    • 한국추진공학회 2011년도 제36회 춘계학술대회논문집
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    • pp.318-325
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    • 2011
  • 이중연소 램제트 엔진의 작동특성 및 주요 설계인자를 파악하기 위하여 공기역학 및 열역학적 이론을 기반으로 한 기본적인 성능해석 모델을 수립하였다. 이중연소 램제트 엔진의 예비 성능해석을 수행하였고, 그 결과는 흡입구, 가스발생기, 초음속 연소기 사이의 상세한 관계를 설명하고 있다. 본 연구에서 제시된 방법은 가스발생기와 초음속 연소기의 기하학적 형상을 정량적으로 결정하고, 엔진 각 구성품의 성능에 대한 영향을 평가하기 위한 도구를 제공한다. 또한 예비 성능해석을 통해 이중 연소 램제트 엔진의 기본 형상 설계 결과를 도출하였다.

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무향칼만필터와 연속확률비 평가를 이용한 무인기용 소형제트엔진의 결함탐지 (Fault Detection of Small Turbojet Engine for UAV Using Unscented Kalman Filter and Sequential Probability Ratio Test)

  • 한동주
    • 항공우주시스템공학회지
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    • 제11권4호
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    • pp.22-29
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    • 2017
  • 비선형특성을 갖고 있는 실제 무인기용 소형터보제트엔진의 운전 중 발생하는 결함을 효과적으로 탐지하기 위한 방안에 대해 연구하였다. 이를 위해서 동적 열역학 사이클해석을 통한 비선형 동특성 모델을 도출하였다. 실제적인 운전상황의 연출을 위해 잡음특성의 평가에 부합하는 무향칼만필터를 적용하였고 필터성능이 가미된 제어기를 설계하였다. 엔진회전수 센서의 결함을 통한 엔진 결함발생을 모사하였고, 발생된 결함의 실시간적인 탐지 방안으로 연속확률비 평가기법을 도입하였다. 이를 운전 중 엔진결함탐지에 적용한 결과 분명한 결정양상을 보임으로써 매우 효과적이고 유용함을 확인하였다.

The impact of corrosion on marine vapour recovery systems by VOC generated from ships

  • Choi, Yoo Youl;Lee, Seok Hee;Park, Jae-Cheul;Choi, Doo Jin;Yoon, Young Soo
    • International Journal of Naval Architecture and Ocean Engineering
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    • 제11권1호
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    • pp.52-58
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    • 2019
  • Marine emissions of Volatile Organic Compounds (VOCs) have received much attention because the International Maritime Organization (IMO) requires the installation of vapour emission control systems for the loading of crude oils or petroleum products onto ships. It was recently recognised that significant corrosion occurs inside these vapour emission control systems, which can cause severe clogging issues. In this study, we analysed the chemical composition of drain water sampled from currently operating systems to investigate the primary causes of corrosion in vapour recovery systems. Immersion and electrochemical tests were conducted under simulated conditions with various real drain water samples, and the impact of corrosion on the marine vapour recovery system was carefully investigated. Moreover, corrosion tests on alternative materials were conducted to begin identifying appropriate substitutes. Thermodynamic calculations showed the effects of environmental factors on the production of condensed sulphuric acid from VOC gas. A model of sulphuric acid formation and accumulation by the characteristics of VOC from crude oil and flue gas is suggested.

저등급 열원으로 구동되는 직렬 열병합 발전시스템의 엑서지와 엔트랜시 성능 특성 (Exergy and Entransy Performance Characteristics of Cogeneration System in Series Circuit Using Low-Grade Heat Source)

  • 김경훈;정영관
    • 한국수소및신에너지학회논문집
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    • 제31권6호
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    • pp.637-645
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    • 2020
  • In this paper, entransy analysis is carried out for combined heat and power (CHP) generation system driven by low-grade heat source compared with energy and exergy analyses. The system consists of a regenerative organic rankine cycle (ORC) and an additional process heater in a series circuit. Special attention is paid to the effects of the turbine inlet pressure, source temperature, and the working fluid on the thermodynamic performance of the system. Results showed that the work efficiency of entransy is higher than that of energy but lower than that of exergy, wheress the process heat efficiency of entransy is lower than that of energy but higher than that of exergy. Entrance analysis showed the potential to complement the exergy analysis in the optimal design of the energy system.

저등급 열원으로 구동되는 병렬 열병합 발전시스템의 엑서지와 엔트랜시 성능 특성 (Exergy and Entransy Performance Characteristics of Cogeneration System in Parallel Circuit Using Low-Grade Heat Source)

  • 김경훈;김경진;정영관
    • 한국수소및신에너지학회논문집
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    • 제32권1호
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    • pp.77-85
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    • 2021
  • In this paper, entransy analysis is carried out for combined heat and power (CHP) generation system driven by low-grade heat source compared with energy and exergy analyses. The system consists of an organic Rankine cycle (ORC) and an additional process heater in a parallel circuit. Special attention is paid to the effects of the source temperature, turbine inlet pressure, and the working fluid on the thermodynamic performance of the system. Results showed that the work efficiency of entransy is higher than that of energy but lower than that of exergy, wheress the process heat efficiency of entransy is lower than that of energy but higher than that of exergy. Entrancy analysis showed the potential to complement the exergy analysis in the optimal design of the energy system.

Experimental Investigation on Critical Heat Flux in Bilaterally Heated Annulus with equal heat flux on both sides

  • Miao Gui;Junliang Guo;Huanjun Kong;Pan Wu;Jianqiang Shan;Yujiao Peng
    • Nuclear Engineering and Technology
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    • 제55권9호
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    • pp.3313-3319
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    • 2023
  • A phenomenological study on CHF in a bilaterally heated annulus with equal heat flux on both sides was experimentally performed. The working fluid of the present test was R-134a. Variation characteristics of CHF and transition of CHF occurrence location were investigated under different pressure, mass flux and quality conditions. With the increase of critical thermodynamic quality, it was found that CHF first occurred on the outer surface of the annulus, then simultaneously occurred on both sides, and finally occurred on the inner surface at relatively high critical quality. After the CHF location transitioned to the inner rod, the sharp fall of CHF in the limiting critical quality region was observed. The critical quality corresponding to the CHF location transition decreased with the increase of mass flux and pressure. Besides, CHF in tube, internally heated, externally heated and bilaterally heated annuli were compared under the same hydraulic diameter conditions. The present study is conducive to improving the understanding of complicated CHF mechanism in bilaterally heated annulus, enriching the experimental database, and providing evidence for developing accurate CHF mechanism model for annuli.

격강구(隔薑灸)의 연소(燃燒) 특성(特性)에 관한 실험적(實驗的) 연구(硏究) (Experimental Study on the Characteristics of Combustion in the Indirect Moxibustion with Ginger)

  • 이건목;이건휘;문성재;황병천;국우석;장지연;김양중;장재호;윤주영
    • Journal of Acupuncture Research
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    • 제21권3호
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    • pp.193-214
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    • 2004
  • Objective : The purpose of this study is to investigate the mechanism and effect of moxibustion with ginger objectively, to be used as the quantitative data through the measurement of temperature, and to grasp the thermodynamic characteristics of moxibustion with ginger. Methods : We have selected the indirect moxibustion with ginger among many indirect moxibustions. We produced a slice of ginger to a thickness of 3, 4, 5mm and the moxa cone having a diameter of 8mm, a height of 10mm for making a comparative study of characteristics of moxa cone according to change the density. We have made a comparative study of the thermodynamic characteristics of moxibustion with ginger with or without holes. We measured combustion times and calculated temperatures, temperature gradients in each period during a combustion of moxa. Results : 1. We found out it was not significantly influenced by the existence of the punched holes in a slice of ginger because the punched holes grow smaller immediately. 2. The duration of the preheating period became longer according to thickness of a slice of ginger and was not directly proportional to the density of moxa cone. The duration of the preheating period was extremely short when it burned a 100mg moxa cone. That was influenced by the density of moxa cone. 3. The duration of the heating period became longer according to thickness of a slice of ginger likewise the preheating period bacause the density of moxa cone had effected on the combustion characteristics. The duration of the heating period was extremely long when it burned a 100mg moxa cone. On the other hand the maximum temperature in the heating period was appeared that the combustion with a thin slice of ginger was highest and measured that the large density of moxa cone was higher. But the maximum temperature in the heating period was about $37.8^{\circ}C{\sim}44.2^{\circ}C$respectively lower in others. 4. The duration of the retaining period was some doubling shorter than that of the heating period that is concerned the shape of moxa cone. The temperature measured the close of a retaining period was $36.6^{\circ}C{\sim}41.8^{\circ}C$, that was considerably lower temperature. 5. The mean ascending temperature velocity and the mean descending temperature velocity were $0.042{\sim}0.073^{\circ}C/sec$, $-0.027{\sim}-0.064^{\circ}C/sec$ respectively. Then, the ascending temperature velocity was some faster than the ascending temperature velocity. Conclusions : The quantitative standard for obtaining the effective heating stimulation is that if the slice of ginger made a hole in it, we had to use the needle above 1.5mm diameter. The recommended size of a slice ginger is the 14mm diameter and the 2~3mm thickness. The moxa cone is formed the conical shape that the base diameter was 8mm, the height was 10mm, the density was $600mg/cm^2$.

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Inverse Gas Chromatography를 이용한 Poly(dimethylsiloxane)-Solvent계의 열역학적 연구 (Thermodynamic Study of Poly(dimethylsiloxane)-Solvents Systems Using Inverse Gas Chromatography)

  • 조정모;강춘형
    • 공업화학
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    • 제10권5호
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    • pp.718-725
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    • 1999
  • Inverse gas chromatography(IGC) 방법은 고분자-용매 계의 열역학적 특성을 신속하고 정확하게 결정할 수 있는 신뢰할 만한 방법 중 하나이다. 본 연구에서는 유한 농도에서의 IGC 방법을 사용하여 poly(dimethylsiloxane)(PDMS)과 물, 에탄올, 그리고 이소프로판올과의 상호작용을 정량적으로 결정하였다. 이를 위하여 고정상 내 용매의 체류시간으로부터 Flory-Huggins의 상호작용 계수를 산출하여 PDMS와 용매간의 소수성 상호작용을 의미하는 큰 양의 값(2$2.0{\times}10^{-3}mol/g$이었다. 또한 선형고분자에 대한 Kirkwood-Buff-Zimm(KBZ) 적분을 행하여 고분자와 용매의 분자분포 구조를 추정하였다. 이로부터 물분자는 PDMS에 대하여 용매화되지 않고 자체 분자끼리 부분적인 클러스트를 형성하며, 에탄올과 이소프로판올에서는 탄소수가 증가함에 따라 균일한 혼합에 가까운 분자분포의 구조적 성질을 추정할 수 있었다.

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