• Journal of the Korean Crystal Growth and Crystal Technology
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• v.4 no.2
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• pp.178-189
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• 1994

Fine $BaTiO_3$ powder was synthesized from the various starting solution with 0.05 M by ultrasonic spray pyrolysis method. The conditions of synthesis were fixed on flow rate was 0.5 cm/sec, low temperature furnace was $300^{\circ}C$, and high temperatures furnace was $700^{\circ}C$. The formation procedure was investigated directly by SEM with the collected particle from the each reaction step. Also, the trace of particle in reaction tube was researched theoretically. Fine $BaTiO_3$ was synthesized only in the case of nitrate aqueous solution. The synthesized $BaTiO_3$ powder was porous and spherical which was consist of primary particle at the size of 19.1 nm. The formation procedure was as follows : the particle size decreased in drying step and then increased in initial thermal decomposition step. Finally, particle size was decreased to $0.42 {mu}m$. The trace of particle in reaction tube was also theoretically simulated and discussed.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2011.11a
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• pp.694-696
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• 2011

The high enthalpy plasma research center in Chonbuk national university is under construction for four types of plasma equipments. The equipments are 1set of 0.4 MW class enhanced Huels type plasma equipment, 1 set of 2.4 MW class enhanced Huels type plasma quipment, 1 set of 60 kW RF plasma equipment and 1 set of 200 kW RF plasma equipment. 60kW RF plasma system is R&D and pilot scale production equipment of nano powder synthesis and plasma spray coating. 200kW RF plasma system is mass production equipment with high power capacity of nano powder synthesis. 0.4MW plasma system can be applied to the ground test facility for material testing under re-entry conditions for space vehicles.

• Journal of Powder Materials
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• v.12 no.2 s.49
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• pp.106-111
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• 2005

The effect of post-heat treatment on the coating characteristics and the fatigue strength of the gas flame thermally sprayed Stellite alloy coatings on $0.35\%$ carbon steel were investigated. The fatigue fracture surfaces of the heat treated samples were observed using SEM (Scanning Electron Microscopy). For as-sprayed samples, there was considerable scattering in the fatigue life due to the presence of the pores in the coating. After the post-heat treatment to improve the microstructural characteristics of the coating layer, the fatigue strength of the specimens was greatly improved, increasing with increasing the coating thickness. For the specimens with the 0.3mm and 0.5mm thick coating, the fatigue cracks originated in the substrate region just below the interface. On the contrary, for the specimens with the 1.0mm thick coating, they nucleated at the pore within the coating, and the fatigue strength was 2.6 times higher than that of the substrate due to the high fatigue resistance of the coating.

• Korean Journal of Materials Research
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• v.31 no.11
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• pp.601-607
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• 2021

Laser cladding a surface treatment process that grants superior characteristics such as toughness, hardness, and corrosion resistance to the surface, and rebuilds cracked molds; as such, it can be a strong tool to prolong service life of mold steel. Furthermore, compared with the other similar coating processes - thermal spray, etc., laser cladding provides superior bonding strength and precision coating on a local area. In this study, surface characteristics are studied after laser cladding of low carbon steel using 18%Cr-2.5%Ni-Fe powder (Rockit404), known for its high hardness and excellent corrosion resistance. A diode laser with wavelength of 900-1070 nm is adopted as laser source under argon atmosphere; electrical power for the laser cladding process is 5, 6, and 10 kW. Fundamental surface characteristics such as crossectional microstructure and hardness profile are observed and measured, and special evaluation, such as a soldering test with molten ALDC12 alloy, is conducted to investigate the corrosion resistance characteristics. As a result of the die-soldering test by immersion of low carbon alloy steel in ALDC12 molten metal, the clad layer's soldering thickness decreases.

• Proceedings of the Materials Research Society of Korea Conference
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• 2003.11a
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• pp.50-50
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• 2003

용사 공정은 소재의 표면 특성을 개질하기 위한 가장 효과적인 공정의 하나로서, 최근 항공기용 엔진 부품을 포함하여 자동차, 및 각종 산업 분야에 폭 넓게 사용되고 있으나, 산업 환경의 고도화로 용사 코팅층의 다양한 분야에서의 고특성화가 요구되고 있다. 소재의 나노화는 이러 한 소재의 고 특성화 요구에 부응할 수 있는 새로운 기술로서, 현재 많은 분야에서 응용이 진행되고 있다. 특히 최근에는 나노기술을 용사 공정에 응용하기 위한 시도가 진행되고 있으나, 나노 분말 제조 기술이 아직 확립되어 있지 않고, 또한 나노 분말을 용사 공정에 응용하기 위한 기술의 부족으로 나노 용사공정에의 적용은 제한을 받고 있다. 이를 위해서는 나노분말 제조 기술의 개발이 이루어져야하고, 나노 분말 제조 기술과 용사 분말 제조 기술 그리고 용사 기술의 접목이 이루어 져야하는 어려움이 있다. 본 연구에서는 나노 용사용 분말을 제조하기 위 한 원료용 나노 분말을 화학적 공정에 의하여 제조 한 후, 이 분말의 유동도 및 밀도 제어를 위한 후 처리 공정을 개발하였다. 제조된 분말의 입자 크기는 약 150nm였으며, 용사 분말 제조후 분말의 겉보기 겉보기 밀도가 3.8g/cc로서 일반 용사용 분말에 비하여 우수하였다.

• Journal of Power System Engineering
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• v.15 no.1
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• pp.51-56
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• 2011

The various process parameters of thermal spray process affects on quality of Ni-based coatings. Thus, there is need to analyze the effect of process parameters on quality of Ni-based coatings. In this paper, the effects of process parameters on hardness and wear rate of Ni-based coatings were investigated using 4 design of experiments. First, the Ni-based coatings were fabricated according to $L_9(3^4)$ orthogonal array. The hardness tests and the wear tests were performed on the Ni-based coatings. The analysis of variance for the hardness and wear rate were carried out. As a results, the acetylene gas flow and the powder feed rate were identified as main factors effected on the hardness and the oxygen gas flow and the acetylene gas flow were identified as main factors effected on the wear rate. The full factorial experiments design with different levels was applied for investigation of effect of these main factors.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.21 no.8
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• pp.248-255
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• 2020

The effects of the coating thickness on the thermal durability and thermal stability of thermal barrier coatings (TBCs) with a gradient coating thickness were investigated using a flame thermal fatigue (FTF) test and thermal shock (TS) test. The bond and topcoats were deposited on the Ni-based super-alloy (GTD-111) using an air plasma spray (APS) method with Ni-Cr based MCrAlY feedstock powder and yttria-stabilized zirconia (YSZ), respectively. After the FTF test at 1100 ℃ for 1429 cycles, the bond coat was oxidized partially and the thermally grown oxide (TGO) layer was observed at the interface between the topcoat and bond coat. On the other hand, the interface microstructure of each part in the TBC specimen showed a good condition without cracking or delamination. As a result of the TS test at 1100 ℃, the TBC with gradient coating thickness was initially delaminated at a thin part of the coating layer after 37 cycles, and the TBC was delaminated by more than 50% after 98 cycles. The TBCs of the thin part showed more oxidation of the bond coat with the delamination of topcoat than the thick part. The thick part of the TBC thickness showed good thermal stability and oxidation resistance of the bond coat due to the increased thermal barrier effect.

• The Korean Journal of Food And Nutrition
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• v.10 no.2
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• pp.234-240
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• 1997

Agar has widely been used as medical aids and food ingredients due to its pecular physicochemical and rheological properties. In this paper, the effects of spray drying and extrusion drying on functional properties of agar were investigated to clarify the sol-gel transition mechanism at low temperature and microstructure of agar gel by measuring phase transition by differential scanning calorimetery, structural differences by light microscope and scanning electron microscope observation. The lowest endothermic onset(To), peak(Tp), conclusion(Tc) temperature and enthalpy($\Delta$H) using differential scanning calorimetery were showed in extrusion-dried agar wic were checked in 41.30, 61.72, 80.50 and 0.73cal/g. In cases of unmodified and spray-dried, the values were 81.20, 95.51, 112.14 and 3.22cal/g, and 60.11, 76.45, 89.54 and 1.53cal/g, respectively. When all samples were reheated using differential scanning calorimetery after gelling fully, no significant differences of endothermic To, Tp, Tc and $\Delta$H appeared. The surface structure of unmodified agar powder observed by light microscope and scanning electron microscope appeared a continuous surface without any indication of small pores, gaps or point of discontinuity. In cases of spray-dried agar, the unstable structures with pores was resulted. The microstructures of extrusion-dried agar, however, was solid with large gaps and areas of discontinuity in the surface. From the results above, it was suggested that significant differences in phase transition and surface microstructures were clearly related to the physicochemical changes and rheological properties, solubility and gelling ability of the types of agar gel.

• Corrosion Science and Technology
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• v.6 no.4
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• pp.159-163
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• 2007

Micron size Co-alloy 800 (T800) powder is coated on the high temperature, oxidation and corrosion resistant super alloy Inconel 718 substrate by the optimal high velocity oxy-fuel (HVOF) thermal spray coating process developed by this laboratory. For the study of durability improvement of high speed spindle operating without lubricants, friction and sliding wear behaviors of the coatings are investigated both at room and at an elevated temperature of $1000^{\circ}F(538^{\circ}C)$. Friction coefficients, wear traces and wear debris of coatings are drastically reduced compared to those of non-coated surface of Inconel 718 substrate both at room temperature and at $538^{\circ}C$. Friction coefficients and wear traces of both coated and non-coated surfaces are drastically reduced at higher temperature of $538^{\circ}C$ compared with those at room temperature. At high temperature, the brittle oxides such as CoO, $Co_{3}O_{4}$, $MoO_2$ and $MoO_3$ are formed rapidly on the sliding surfaces, and the brittle oxide phases are easily attrited by reciprocating slides at high temperature through oxidation and abrasive wear mechanisms. The brittle solid oxide particles, softens, melts and partial-melts play roles as solid and liquid lubricants reducing friction coefficient and wear. These show that the coating is highly recommendable for the durability improvement coating on the machine component surfaces vulnerable to frictional heat and wear.

• Journal of the Korean institute of surface engineering
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• v.42 no.1
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• pp.1-7
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• 2009

Resistive heating sources are widely used to prepare thin films by vapor deposition because they are cheap, and easy to install and handle in vacuum system. Graphite is one of materials used to make the resistive heating source, but until now only limited applications have been possible as it reacts easily with evaporating materials at high temperature. In this study, evaporation characteristics of aluminum have been investigated by using graphite boat thermally treated with BN powder. The employed graphite boat has been prepared by spray-coating BN power onto the cavity surface of the boat and thermal treatment with aluminum in vacuum at the temperature of more than $1400^{\circ}C$. The voltage-current characteristics as well as resistivity changes of the graphite boat have been investigated during aluminum evaporation according to the applied voltage and time. The evaporation aspect has been picturized during flash evaporation for 40 seconds based on the characterization results. The evaporation rate of the graphite boat has been compared with that of BN boat. The graphite boat showed some different characteristics compared with BN boat, in that the evaporation occurred at the last stage of flash evaporation. The film appearance according to the applied voltage has been compared, and also the reflectance of the resulting film has been investigated according to the film thickness. It has been found that the graphite boat thermally treated with BN powder can be used for aluminum evaporation without problem.