• Applied Chemistry for Engineering
• /
• 제18권1호
• /
• pp.94-97
• /
• 2007

Carbon nanotubes and nanowires were prepared by methane pyrolysis over Pd(5)/SPK catalyst by changing oxygen molar ratio in a fixed bed flow reactor under atmospheric condition and also analyzed by SEM and TEM. When the $CH_4/O_2$ molar ratio was 1, carbons were not almost deposited on the catalyst bed support, but when it was 2, carbons were deposited as much as plugging reactor. TEM and SEM images for the deposited carbons showed a number of single-walled carbon nanotubes and carbon nanowires. The growth mechanism of carbon nanotubes produced on the catalyst surface was the tip growth mode. It should be played an important role in carbon nanotubes and nanowires produced on the catalyst bed support to formate the carbon growth velocity vectors and nuclei of ring structure of carbon nanowires. SPK carrier was $N_2$ isotherm of IV type with mesopores, and excellent in the thermal stability.

• Applied Chemistry for Engineering
• /
• 제23권3호
• /
• pp.253-258
• /
• 2012

The effects of active sites and valence states were investigated over $Pd/TiO_2$ catalyst on simultaneous oxidation of $CH_4$ and CO. The Pd species (PdO) crystallite size increased with increasing Pd loadings, which results in enhancement of the activity of $CH_4$ oxidation. Different results from the activity of $CH_4$ and CO oxidation were shown to be dependent on the Pd valence state on the surface of the catalyst prepared through a thermal treatment. XRD and $H_2-TPR$ analysis confirmed that $Pd^{2+}$species was predominated in the calcination catalyst, while $Pd^0$species was predominated in the reduction catalyst. Additionally, it could be found that the valence state of Pd was a more important factor on the catalytic activity than that of factors as the surface area and pore volume. The reaction mechanism of $CH_4$ and CO followed by the valence state of Pd could be identified using FT-IR analysis.

• Laser Solutions
• /
• 제11권4호
• /
• pp.29-34
• /
• 2008

Ultraviolet laser micromachining has increasingly been applied to the electronics industry where precision machining of high-density, multi-layer, and multi material components is in a strong demand. Due to the ever-decreasing size of electronic products such as cellular phones, MP3 players, digital cameras, etc., flexible printed circuit board (FPCB), multi-layered with polymers and metals, tends to be thicker. In present, multi-layered FPCBs are being mechanically cut with a punching die. The mechanical cutting of FPCBs causes such defects as burr on layer edges, cracks in terminals, delamination and chipping of layers. In this study, the laser cutting mechanism of FPCB was examined to solve problems related to surface debris and short-circuiting that can be caused by the photo-thermal effect. The laser cutting of PI and FCCL, which are base materials of FPCB, was carried out using a pico-second laser(355nm, 532nm) and nano-second UV laser with adjusting variables such as the average/peak power, scanning speed, cycles, gas and materials. Points which special attention should be paid are that a fast scanning speed, low repetition rate and high peak power are required for precision machining.

• Journal of the Korean Society of Clothing and Textiles
• /
• 제14권1호
• /
• pp.20-30
• /
• 1990

In order to investigate the mechanism of the formation of clothing microclimate with different blouse designs and materials, physiological and subjective sensational changes were measured. Experimental clothing were four types of blouse made of $100\%$ cotton, $100\%$ regular polyes­ter, and $100\%$ hygroscopic polyester. Four types of box style blouse were with stand collar and long sleeve, with stand collar and sleeveless, with long sleeve and collarless, and sleeveless and collarless. Five healthy female were chosen as subjects. Experiments were carried out in the environ­mental chamber controlled at $28{\pm}1^{\circ}C$ , $70{\pm}5\%$ RH. and still-air condition for SO min. The skin temperature (9 spots), oral temperature, humidity inside chest, and subjective sensations were measured. Obtained results are: I) Material which is capable of absorbing sweat effectively and transfering moisture rapidly made a comfortable feeling, because cloth­ing humidity is increasing slowly at this material. 2) During exercise period, covered arms have more influenced on thermal comfort than a covered neck.

• Journal of The Korean Astronomical Society
• /
• 제34권4호
• /
• pp.309-311
• /
• 2001

Strong thermal X-ray emission, called Galactic Ridge X-ray Emission, is observed along the Galactic plane (Koyama et al. 1986). The origin of hot ($\~$7 keV) component of GRXE is not known, while cool ($\~$0.8 keV) one is associated with supernovae (Kaneda et al. 1997, Sugizaki et al. 2001). We propose a possible mechanism to explain the origin; locally strong magnetic fields of $B_{local}\;\~30{\mu}G$ heat interstellar gas to $\~$7 keV via magnetic reconnection (Tanuma et al. 1999). There will be the small-scale (< 10 pc) strong magnetic fields, which can be observed as $(B)_{obs} \;\~3{\mu}G$ by integration of Faraday Rotation Measure, if it is localized by a volume filling factor of f $\~$ 0.1. In order to examine this model, we solved three-dimensional (3D) resistive magnetohydrodynamic (MHD) equations numerically to examine the magnetic reconnect ion triggered by a supernova shock (fig.l). We assume that the magnetic field is Bx = 30tanh(y/20pc) $\mu$G, By = Bz = 0, and the temperature is uniform, at the initial condition. We put a supernova explosion outside the current sheet. The supernova-shock, as a result, triggers the magnetic reconnect ion, and the gas is heatd to > 7 keV. The magnetic reconnect ion heats the interstellar gas to $\~$7 keV in the Galactic plane, if it occurs in the locally strong magnetic fields of $B_{local}\;\~30{\mu}G$. The heated plasma is confined by the magnetic field for $\~10^{5.5} yr$. The required interval of the magnetic reconnect ions (triggered by anything) is $\~$1 - 10 yr. The magnetic reconnect ion will explain the origin of X-rays from the Galactic ridge, furthermore the Galactic halo, and clusters of galaxies.

• The Bulletin of The Korean Astronomical Society
• /
• 제36권2호
• /
• pp.155.1-155.1
• /
• 2011

The Korea Astronomy and Space Science Institute (KASI) and the Department of Astronomy at the University of Texas at Austin (UT) are developing a near infrared wide-band high resolution spectrograph, IGRINS (Immersion Grating Infrared Spectrograph). The white-pupil design of the instrument optics uses 7 cryogenic mirrors including 3 aspherical off-axis collimators and 4 flat fold mirrors. Two of the 3 collimators are H- and K-band pupil transfer mirrors and they are designed as compensators for the system alignment in each channel. Therefore, their mount design will be one of the most sensitive parts in the IGRINS optomechanical system. The other flat fold mirrors are designed within the limited area. Each of those includes the features of 3 axial hard points and 2 radial hard points with one spring plunger in order for the proper deflection of the mirror. The design work will include the computer-aided 3D modeling and finite element analysis (FEA) to optimize the structural stability and the thermal behavior of the mount models. The mount body will also include a tip-tilt and translation adjustment mechanism to be used as the alignment compensators.

• Transactions on Electrical and Electronic Materials
• /
• 제8권2호
• /
• pp.53-57
• /
• 2007

In this study, a novel slurry containing ceria as the abrasive particles was analyzed in terms of its frictional, thermal and kinetic attributes for interlayer dielectric (ILD) CMP application. The novel slurry was used to polish 200-mm blanket ILD wafers on an $IC1000_{TM}$ K-groove pad with in-situ conditioning. Polishing pressures ranged from 1 to 5 PSI and the sliding velocity ranged from 0.5 to 1.5 m/s. Shear force and pad temperature were measured in real time during the polishing process. The frictional analysis indicated that boundary lubrication was the dominant tribological mechanism. The measured average pad leading edge temperature increased from 26.4 to $38.4\;^{\circ}C$ with the increase in polishing power. The ILD removal rate also increased with the polishing power, ranging from 400 to 4000 A/min. The ILD removal rate deviated from Prestonian behavior at the highest $p{\times}V$ polishing condition and exhibited a strong correlation with the measured average pad leading edge temperature. A modified two-step Langmuir-Hinshelwood kinetic model was used to simulate the ILD removal rate. In this model, transient flash heating temperature is assumed to dominate the chemical reaction temperature. The model successfully captured the variable removal rate behavior at the highest $p{\times}V$ polishing condition and indicates that the polishing process was mechanical limited in the low $p{\times}V$ polishing region and became chemically and mechanically balanced with increasing polishing power.

• Journal of the Korean Society of Propulsion Engineers
• /
• 제18권4호
• /
• pp.9-17
• /
• 2014

In this study, in order to improve the ignitability of high energy aluminum powder, natural oxide films (alumina) were chemically removed, and instead nickel coat was applied. We used an electroless plating for nickel coating and confirmed quantitatively and qualitatively a time-dependent degree of nickel coating through analysis of surface by SEM/EDS. We also conducted element analysis by XRD and thermal properties by TGA/DSC in air oxidizer environment. There results explained the ignition enhancement mechanism of the nickel-coated aluminum powder in air. The difference between coated and un-coated aluminum powder, the effectiveness of coated powder has better ignitability.

• Archives of Pharmacal Research
• /
• 제3권1호
• /
• pp.7-12
• /
• 1980

Ampliciline was synthesized from 6-amino-pencillanic acid (6-APA) and D-.alpha. phenylglycine methyl ester by using amplicilin synthesizing enzyme from Peudomonas melanogenum (IAM 1655). The whole cell enzyme was immobilized by entrapping it in the polyacrylamide gel lattices. The polymer used in the enzyme entrapment was made from 150 mg per ml of acrylamide monomer and 8 mg per ml of N, N'-methylenebisacrylamide. About 200 mg/whole cell enzyme was mixed in the polymer for entrapment. The maximal activity retention after immobilization was 56%. The optimal pH values for the whole cell enzyme and the immobilized whole cell enzyme were 6.0 and 5.9, respectively. The optimal temperature for the enzyme activity were the same for both type of preparations. The enzyme stabilities against pH and heat increased for immobilized whole cell enzyme. Immobilized cell was more stable especially in the acidic condition while both type were found to be very suceptible to thermal inactivation at a temperature above 4.deg.C. The kinetic constants obtained from Lineweaver-Burk plot based on two substate reaction mechanism showed somewhat higher value for immobilized whole cell enzyme as compared to the whole cell enzyme : the Km value for 6-APA were 7.0 mM and 12.5 mM while Km values for phenylglycine methyl ester were 4.5 mM and 8.2 mM, respectively. Using the immobilized whole cell enzyme packed in a column reactor, the productivity of ampiciline was studied by varying the flow rate of substrate solution. At the space velocity, SV, 0.14 hr$^{-1}$ the conversion was 45%. Operational stability found in terms of half life was 30 hr at SV = 0.2 hr.

• Plant Journal
• /
• 제11권1호
• /
• pp.50-57
• /
• 2015

This study presents prediction of maximum fly ash conveying capacity of fly ash system in a power plant. The mixture ratio and pressure drop characteristics of air-fly ash flow in piping system are not well understood due to the complexity of particle motion mechanism. In this paper, the researcher investigated the optimum mixture ratio when the pressure drop of fly ash conveying system is equal to maximum static pressure of displacement fly ash transport blower and the capacity of fly ash transport according to the optimum mixture ratio by experimenting the fly ash conveying system of domestic D coal thermal power plants, which is currently in operation. The experiment results showed that the maximum fly ash conveying capacity of fly ash system were founded under the condition of maximum air volume 5,040 m3/h, static pressure of trip condition 1,163 mmH2O. In addition, it was predicted maximum mixture ratio of the air-fly ash was 8.66 and maximum capacity of fly ash conveying was 52,600 kg/h under these conditions.