• Title/Summary/Keyword: Thermal mechanism

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Experimental Study on the Stimulating Effect of Commercial Moxa Combustion through the Measurement of Temperature -Focused on Combustion time and temperature- (온도 측정을 통한 상용 쑥뜸의 자극효과에 대한 실험적 연구 -연소시간 및 연소온도를 중심으로-)

  • Lee, Geon-Mok;Yang, Yoo-Sun;Lee, Gun-Hyee
    • Journal of Acupuncture Research
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    • v.19 no.2
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    • pp.114-127
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    • 2002
  • Objective : The purpose of this study is to investigate the mechanism and effect of moxibustion objectively and to be used as the quantitative data for developing the new thermal stimulating treatment by observing the combustion time and temperature of commercial moxaes. Methods : We have selected two types(large-size moxa A(LMA), large-size moxa B (LMB)) among large moxaes used widely in the clinic. We examined combustion times, temperatures in each period during a combustion of moxa. Results : 1. The combustion time in the preheating period was about 30sec in both moxaes on the non-contact heated surface. 2. The combustion time in the heating period was about 345sec in LMA and about 1391 sec in LMB, about 4 times longer in LMB on the non-contact surface. 3. The maximum temperature in the heating period was $44.5^{\circ}C$ in LMA and $45.4^{\circ}C$ in LMB respectively, higher by $0.9^{\circ}C$ in LMB. The average temperature in the heating period was $35.5{\sim}37.6^{\circ}C$ in LMA and $36.0{\sim}39.8^{\circ}C$ in LMB, a little higher in LMB. 4. The combustion time in the retaining period in LMA was 45.4sec and 13% of that in the heating period, and in LMB 594.7sec and 43% of that in the heating period on the non-contact surface. 5. On the point(PH) measured maximum temperature, the average temperature during the retaining period was $44.0^{\circ}C$, $42.9^{\circ}C$ respectively and the temperature at an end of the retaining period was $43.0^{\circ}C$, $40.2^{\circ}C$ respectively. 6. The time at a beginning of the cooling period was about 418 sec from ignition in LMA and 2021sec in LMB, and the temperature at that time was $36.9{\sim}39.1^{\circ}C$ on the non-contact surface. Conclusion : It was thought that not only the figure of moxicombustion device, but also the form and size of moxa had influence on the combustion characteristics deciding the performance of stimulus seriously.

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The Study on Phase Separation Development by Curing Reaction Rate for Unsaturated Polyester/Polyvinylacetate Semi-IPN (Unsaturated Polyester/Polyvinylacetate Semi-IPN의 경화반응속도에 따른 상분리현상 연구)

  • Chang, Won-Young;Kim, Moo-Sool;Kim, Jin-Hwan;Nam, Jae-Do
    • Polymer(Korea)
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    • v.25 no.1
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    • pp.78-89
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    • 2001
  • Morphological changes of unsaturated polyester/polyvinylacetate semi-IPN were studied while the phase separation and the cure reaction occurred in a competing fashion. The light scattering and thermal analysis techniques were used to investigate the phase separation rates and mechanical properties resultantly induced by molecular diffusion of thermoplastic polymer during the curing process of thermosetting polymer. The reaction activation energy was calculated by using Flynn-Wall method and the semi-IPN structure exhibited various phase-separation morphological characteristics. When PVAc composition was 10 wt%, the phase separation was not observed during the curing reaction, but the phase separation occurred in a similar fashion to nucleation and growth(NG) mechanism at room temperature. On the other hand, when PVAc composition was over 11.65 wt%, the phase separation was generated in the middle of the curing process. Consequently, the phase separation seemed to influence the curing reaction rate, which was also supported by the changing activation energy with conversion and PVAc composition. Finally, the total scattered intensity was measured at various temperature, and subsequently the diffusion rates of phase separation R(${\beta}m$) were evaluated.

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SnO2 Nanowire Networks on a Spherical Sn Surface: Synthesis and NO2 sensing properties (구형 Sn 표면의 SnO2 나노와이어 네트워크: 합성과 NO2 감지 특성)

  • Pham, Tien Hung;Jo, Hyunil;Vu, Xuan Hien;Lee, Sang-Wook;Lee, Joon-Hyung;Kim, Jeong-Joo;Heo, Young-Woo
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2018.06a
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    • pp.142.2-142.2
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    • 2018
  • One-dimensional metal oxide nanostructures have attracted considerable research activities owing to their strong application potential as components for nanosize electronic or optoelectronic devices utilizing superior optical and electrical properties. In which, semiconducting $SnO_2$ material with wide-bandgap Eg = 3.6 eV at room temperature, is one of the attractive candidates for optoelectronic devices operating at room temperature [1, 2], gas sensor [3, 4], and transparent conducting electrodes [5]. The synthesis and gas sensing properties of semiconducting $SnO_2$ nanomaterials have become one of important research issues since the first synthesis of SnO2 nanowires. In this study, $SnO_2$ nanowire networks were synthesized on a basis of a two-step process. In step 1, Sn spheres (30-800 nm in diameter) embedded in $SiO_2$ on a Si substrate was synthesized by a chemical vapor deposition method at $700^{\circ}C$. In step 2, using the source of these Sn spheres, $SnO_2$ nanowire (20-40 nm in diameter; $1-10{\mu}m$ in length) networks on a spherical Sn surface were synthesized by a thermal oxidation method at $800^{\circ}C$. The Au layers were pre-deposited on the surface of Sn spherical and subsequently oxidized Sn surface of Sn spherical formed SnO2 nanowires networks. Field emission scanning electron microscopy and high-resolution transmission electron microscopy images indicated that $SnO_2$ nanowires are single crystalline. In addition, the $SnO_2$ nanowire is also a tetragonal rutile, with the preferred growth directions along [100] and a lattice spacing of 0.237 nm. Subsequently, the $NO_2$ sensing properties of the $SnO_2$ network nanowires sensor at an operating temperature of $50-250^{\circ}C$ were examined, and showed a reversible response to $NO_2$ at various $NO_2$ concentrations. Finally, details of the growth mechanism and formation of Sn spheres and $SnO_2$ nanowire networks are also discussed.

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Electrochemical Characterization of Cobalt Oxide Xerogel Electrode for Supercapacitor (수퍼커패시터용 산화코발트 건조겔전극의 전기화학적 특성)

  • Kim Han-Joo;Shin Dal-Woo;Kim Yong-Chul;Kim Seong-Ho;Park Soo-Gil
    • Journal of the Korean Electrochemical Society
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    • v.3 no.3
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    • pp.146-151
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    • 2000
  • So fine cobalt oxide xerogel powders were prepared by using a unique solution chemistry associated with the sol-gel process. The effect of thermal treatment on the crystalinity, particle structure, and corresponding electrochemical properties of the resulting xerogel remained amorphous as $Co(OH)_2$ up to $160^{\circ}C$ With an increase in the temperature above $200^{\circ}C$, both the surface area and pore volume decreased sharply, because the amorphous $Co(OH)_2$ decomposed to form CoO that was subsequently oxidized to form crystalline Co304. In addition, the changes in the crystallinity, and particle structure all had significant but coupled effects on the electrochemical properties of the xerogels. A maximum capacitance of 192F1g was obtained for an electrode prepared with the $CoO_x$ Xerogel calcined at$150^{\circ}C$, which was consistent with the maxima exhibited in both the surface area and pore volume. This capacitance was attributed solely to a surface redox mechanism.

A Study on Electrical Properties of $Ta_2O_{5-x}$ Thin-films Obtained by $O_2$ RTA ($O_2$RTA 방법으로 제조된 $Ta_2O_{5-x}$ 박막의 전기적 특성)

  • Kim, In-Seong;Song, Jae-Seong;Yun, Mun-Su;Park, Jeong-Hu
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.51 no.8
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    • pp.340-346
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    • 2002
  • Capacitor material utilized in the downsizing passive devices and integration of passive devices requires the physical and electrical properties at given area such as capacitor thickness reduction, relative dielectric constant increase, low leakage current and thermal stability. common capacitor materials, $Al_2O_3$, $SiO_2$, $Si_3N_4$, $SiO_2$/$Si_3N_4$, TaN and et al., used until recently have reached their physical limits in their application to integration of passive devices. $Ta_2O_{5}$ is known to be a good alternative to the existing materials for the capacitor application because of its high dielectric constant (25~35), low leakage current and high breakdown strength. Despite the numerous investigations of $Ta_2O_{5}$ material, there have little been established the clear understanding of the annealing effect on capacitance characteristic and conduction mechanism. This study presents the dielectric properties $Ta_2O_{5}$ MIM capacitor structure Processed by $O_2$ RTA oxidation. X-ray diffraction patterns showed the existence of amorphous phase in $600^{\circ}C$ annealing under the $O_2$ RTA and the formation of preferentially oriented-$Ta_2O_{5}$ in 650, $700^{\circ}C$ annealing and the AES depth profile showed $O_2$ RTA oxidation effect gives rise to the $O_2$ deficientd into the new layer. The leakage current density respectively, at 3~1l$\times$$10_{-2}$(kV/cm) were $10_{-3}$~$10_{-6}$(A/$\textrm{cm}^2$). In addition, behavior is stable irrespective of applied electric field. the frequency vs capacitance characteristic enhanced stability more then $Ta_2O_{5}$ thin films obtained by $O_2$ reactive sputtering. The capacitance vs voltage measurement that, Vfb(flat-band voltage) was increase dependance on the $O_2$ RTA oxidation temperature.

Comparative Experiments to Assess the Effects of Accumulator Nitrogen Injection on Passive Core Cooling During Small Break LOCA

  • Li, Yuquan;Hao, Botao;Zhong, Jia;Wang, Nan
    • Nuclear Engineering and Technology
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    • v.49 no.1
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    • pp.54-70
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    • 2017
  • The accumulator is a passive safety injection device for emergency core cooling systems. As an important safety feature for providing a high-speed injection flow to the core by compressed nitrogen gas pressure during a loss-of-coolant accident (LOCA), the accumulator injects its precharged nitrogen into the system after its coolant has been emptied. Attention has been drawn to the possible negative effects caused by such a nitrogen injection in passive safety nuclear power plants. Although some experimental work on the nitrogen injection has been done, there have been no comparative tests in which the effects on the system responses and the core safety have been clearly assessed. In this study, a new thermal hydraulic integral test facility-the advanced core-cooling mechanism experiment (ACME)-was designed and constructed to support the CAP1400 safety review. The ACME test facility was used to study the nitrogen injection effects on the system responses to the small break loss-of-coolant accident LOCA (SBLOCA) transient. Two comparison test groups-a 2-inch cold leg break and a double-ended direct-vessel-injection (DEDVI) line break-were conducted. Each group consists of a nitrogen injection test and a nitrogen isolation comparison test with the same break conditions. To assess the nitrogen injection effects, the experimental data that are representative of the system responses and the core safety were compared and analyzed. The results of the comparison show that the effects of nitrogen injection on system responses and core safety are significantly different between the 2-inch and DEDVI breaks. The mechanisms of the different effects on the transient were also investigated. The amount of nitrogen injected, along with its heat absorption, was likewise evaluated in order to assess its effect on the system depressurization process. The results of the comparison and analyses in this study are important for recognizing and understanding the potential negative effects on the passive core cooling performance caused by nitrogen injection during the SBLOCA transient.

Preparation and Stability of Silyl Adlayers on 2×1-Reconstructed and Modified Si(100) Surfaces (Si(100)-2×1 표면과 개질된 Si(100) 표면 상에서 실릴 (Silyl) 흡착충의 형성과 안정성)

  • Jo, Sam-K.
    • Journal of the Korean Vacuum Society
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    • v.18 no.1
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    • pp.15-23
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    • 2009
  • Saturation-coverage silyl, $-SiH_3(a)$, overlayers were prepared from $Si_2H_6$ adsorption on three comparative surfaces: clean unmodified; D-precovered; and atomically roughened Si(100). Together with its precursor-mediated adsorption behavior, the surface reactivity of $Si_2H_6$ was found to be the highest on the unmodified Si(100)-$2{\times}1$ surface. This was correlated with its dissociative adsorption mechanism, in which both the $H_3Si-SiH_3$ bond scission and the dual surface $Si-SiH_3(a)$ bond formation require a surface dangling bond 'pair'. The unusually high thermal stability of $-SiH_3(a)$ on the unmodified surface was ascribed to a nearly close-packed $-SiH_3(a)$ coverage of ${\sim}0.9$ monolayer and the consequent lack of dangling bonds on the silyl-packed surface.

Carbonization Patten and Operation Characteristics of a 1Φ 2 W MCCB Damaged by PCITS (PCITS에 의해 소손된 1Φ 2 W MCCB의 탄화 패턴 및 작동 특성)

  • Lee, Jae-Hyuk;Choi, Chung-Seog
    • Fire Science and Engineering
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    • v.28 no.5
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    • pp.8-13
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    • 2014
  • The purpose of this study is to analyze the damage pattern when overcurrent is applied to a thermal magnetic type molded case circuit breaker (MCCB) using a Primary Current Injection Test System (PCITS). When an overcurrent of 150 A was applied to the PCITS for 5 seconds with the trip bar of an MCCB being damaged, it was found that the surface of the temperature control device (bimetallic strip) positioned at the right was significantly carbonized. When an overcurrent of 300 A was applied to the PCITS for 5 s under the same conditions, the entire temperature control device was deteriorated, becoming flattened and in close contact with the MCCB. When an overcurrent of 450 A was applied to the PCITS for 5 s, the coil of the temperature control device was melted and disconnected. In addition, it was observed that the contacts, the enclosure and upper cover were deformed and there was a trace of carbonization on them. When approximately 3 s had elapsed after an overcurrent of 600 A was applied, white smoke occurred inside the MCCB and a flame was radiated out, after which the overcurrent supply stopped with "phutt" (whomp) sound. It was observed that when the same type of MCCB is damaged by a general flame, the surfaces of its handle, terminal, arc divider (extinguisher) and temperature control device were carbonized uniformly. In addition, it was found that the trip bar of the operating mechanism was melted down and the metal operation pin was moved while being tripped.

Chromophore formation and phosphorylation analysis of constitutively active rhodopsin mutants (Chromophore 형성과 rhodopsin kinase 활성을 이용한 항활성 로돕신 mutant의 분석)

  • Kim, Jong-Myoung
    • Journal of Life Science
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    • v.17 no.6 s.86
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    • pp.783-790
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    • 2007
  • G protein coupled receptors (GPCRs) transmit various extracellular signals into the cells. Upon binding of the ligands, conformational changes in the extracellular and/or transmembrane (TM) domains of CPCRs were propagated into the cytoplasmic (CP) domain of the molecule leading to the activation of their cognate heterotrimeric C proteins and kinases. Constitutively active GPCR mutants causing the activation of C Protein signaling even in the absence of ligand binding are of interest for the study of activation mechanism of GPCRs. Two classes of constitutively active mutations, categorized by their effects on the salt bridge between Ell3 and K296, were found in the TM domain of rhodopsin. Opsin mutants containing combinations of the mutations were constructed to study the conformational changes required for the activation of rhodopsin. Rhodopsin chromophore regenerated with 11-cis-retinal showed a thermal stability inversely correlated with its constitutive activity. In contrast, rhodopsin mutants exhibited a binding affinity to an agonist, all-trans-retinal, in a constitutive activity-dependent manner. In order to test whether the conformational changes responsible for the activation of trans-ducin (Gt) are the same as the conformation required for the recognition of rhodopsin kinase, analysis of the mutants were carried out with phosphorylation by rhodopsin kinase. Rhodopsin mutants containing combinations of different classes of the mutations showed a strong synergistic effect on the phosphorylation of the mutants in the dark as similar to that of Gt activation. The results suggest that at least two or three kinds of segmental and independent conformational changes are required for the activation of rhodopsin and the conformational changes responsible for activating rhodopsin kinase and Gt are similar to each other.

Mechanism improvement of the heat exchanger and the ventilator for the thermal efficiency increment of hot-air heater (온풍난방기의 열이용효율 증대를 위한 열교환부 및 송풍기 구조개선)

  • 이기명;박규식;최성우
    • Proceedings of the Korean Society for Agricultural Machinery Conference
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    • 2002.02a
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    • pp.558-563
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    • 2002
  • 시설원예에서 난방장치를 사용하는 겨울철 재배 농산물의 생산비 중 난방 연료비가 30%~37% 정도를 차지하여 비중이 가장 높다. 따라서 시설원예 농가에서는 난방비를 절감하는 것이 농가소득과 직결되므로, 난방장치의 선정이 대단히 중요하다. 본 연구에서는 겨울철 재배 농산물의 생산비 중 30%-37% 정도를 차지하는 연료비를 절감하기 위해 기존의 온풍난방기와 다른 새로운 방식의 열교환기와 원심식 송풍블로워를 사용하는 블로워 송풍방식의 온풍난방기를 개발하고 개발된 온풍난방기의 가동으로 인한 난방 연료비 절감효과와 온실내의 균일한 온도분포를 획득하기 위해 8연동 비닐온실에서의 시험을 실시하였으며 얻어진 결과를 요약하면 다음과 같다. 가. 저 정압용의 전동기 축직결식 송풍팬을 대신하여 고 정압용의 블로워 송풍팬을 장착하고 열교환 면적을 크게 한 지그재그식 환류의 열교환실을 채용한 온풍난방기를 개발하였다. 나. 공시한 온실에서 기존 온풍난방기의 2일 가동시 DH당 연료 사용량이 평균 1.082$\ell$/$^{\circ}C$.hr 이며, 블로워 송풍방식 온풍난방기의 3일 가동시 DH당 연료 사용량은 평균 0.854$\ell$/$^{\circ}C$.hr로써 21%의 난방 연료비 절감효과가 나타났다. 다. 블로워 송풍방식 온풍난방기는 동일시간대 3$^{\circ}C$의 경시적 온도변화가 발생하였고, 기존의 은풍난방기의 동일시간대 온도변화는 최대 6.1$^{\circ}C$로 나타나 개발된 블로워 송풍방식 온풍난방기가 동일시간대 온실내의 온도변화를 크게 줄일 수 있었고 온도분포를 비교적 균일하게 하는 효과가 있음을 확인하였다.도 33$^{\circ}C$를 기준으로 한 열 회수 시간은 유입공기 온도가 52$^{\circ}C$ 및 64$^{\circ}C$ 일 각각 120분 및 140분으로 나타났다. (3) 제 3종 자갈: 축열조로 공급되는 공기의 온도가 52$^{\circ}C$와 64$^{\circ}C$ 일 때, 축열조 출구의 공기온도가 33$^{\circ}C$에 도달될 때까지 가열되는데 소요된 시간은 가열공기의 온도가 52$^{\circ}C$와 64$^{\circ}C$ 일 때 각각 180분과 150분이었고, 방열에 소요된 시간은 각각 240분 및 270분으로 나타났다. 방열과정 동안 축열조 출구의 최고 공기온도는 가열 공급공기의 온도가 52$^{\circ}C$$65^{\circ}C$일 때 각각 35.5$^{\circ}C$ 및 39.5$^{\circ}C$였다. 출구 공기온도 33$^{\circ}C$이상을 기준으로 한 에너지 회수시간은 유입공기 온도가 52$^{\circ}C$ 및 64$^{\circ}C$일 때 각각 140분 및 160분으로 나타났다. 이와 같이 자갈이 작을수록 축열조 출구의 공기온도가 기준온도 33$^{\circ}C$에 도달되는 시간이 길었으며, 이것은 축열조내의 공극이 작고 비중량이 커 자갈층을 가열시키는 축열시간이 길어지기 때문인 것으로 사료된다. 또한 작은 자갈일수록 방열시간도 다소 길어져 회수 가능 열에너지가 큰 것으로 나타났다

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