Browse > Article

A Study on Electrical Properties of $Ta_2O_{5-x}$ Thin-films Obtained by $O_2$ RTA  

Kim, In-Seong (한국전기연구원 전자기소재그룹)
Song, Jae-Seong (한국전기연구원 전자기소재그룹)
Yun, Mun-Su (한국전기연구원 전자기소재그룹)
Park, Jeong-Hu (부산대 공대 전자전기통신공학부)
Publication Information
The Transactions of the Korean Institute of Electrical Engineers C / v.51, no.8, 2002 , pp. 340-346 More about this Journal
Abstract
Capacitor material utilized in the downsizing passive devices and integration of passive devices requires the physical and electrical properties at given area such as capacitor thickness reduction, relative dielectric constant increase, low leakage current and thermal stability. common capacitor materials, $Al_2O_3$, $SiO_2$, $Si_3N_4$, $SiO_2$/$Si_3N_4$, TaN and et al., used until recently have reached their physical limits in their application to integration of passive devices. $Ta_2O_{5}$ is known to be a good alternative to the existing materials for the capacitor application because of its high dielectric constant (25~35), low leakage current and high breakdown strength. Despite the numerous investigations of $Ta_2O_{5}$ material, there have little been established the clear understanding of the annealing effect on capacitance characteristic and conduction mechanism. This study presents the dielectric properties $Ta_2O_{5}$ MIM capacitor structure Processed by $O_2$ RTA oxidation. X-ray diffraction patterns showed the existence of amorphous phase in $600^{\circ}C$ annealing under the $O_2$ RTA and the formation of preferentially oriented-$Ta_2O_{5}$ in 650, $700^{\circ}C$ annealing and the AES depth profile showed $O_2$ RTA oxidation effect gives rise to the $O_2$ deficientd into the new layer. The leakage current density respectively, at 3~1l$\times$$10_{-2}$(kV/cm) were $10_{-3}$~$10_{-6}$(A/$\textrm{cm}^2$). In addition, behavior is stable irrespective of applied electric field. the frequency vs capacitance characteristic enhanced stability more then $Ta_2O_{5}$ thin films obtained by $O_2$ reactive sputtering. The capacitance vs voltage measurement that, Vfb(flat-band voltage) was increase dependance on the $O_2$ RTA oxidation temperature.
Keywords
RTA oxidation; $Ta_2O_{5-x}$; MIM Capacitor; thin films; Electrical properties;
Citations & Related Records
Times Cited By KSCI : 1  (Citation Analysis)
연도 인용수 순위
1 M. Kee, U. Mackens, R. Kiewitt, G. Greuel and C. Metzmacher, 'Ferroelectrical Thin Films for Integrated Passive Component', Phillps Journal of Research Vol. 51 no. 3, 1998
2 V. Mikhelashvili, G. Eisenstein, 'Charactrisistics of MIS Capacitors based on ultilayer $TiO_2/Ta_2O_5$ structures', Microelectronics Reliability Vol. 40, pp. 657, 2000   DOI   ScienceOn
3 S. Zaima, T. Furuka, Y. Yasuda and M. Iida, 'Preparation and Properties of Ta2O5 films by LPCVD for ULSI Application', J. Electrochem. Soc. Vol. 137, pp.1297, 1990   DOI
4 Susumu Shibata, 'Dielectric constant of $Ta_2O_5$ thin film deposited by RF sputtering', Elsevier Thin Solid Films, Vol. 277, pp. 1, 1996   DOI   ScienceOn
5 S. Ezhilvalavan, Ming Shiahn Tsaia and Tseung Yuen Tseng 'Dielectric Relaxation and Analysis of $Ta_2O_5$ Thin films', J. Phys. D: Appl. Phys., Vol. 33 (200) pp. 1137, 2000   DOI   ScienceOn
6 S. Zaima, T. Furuta, Y. Yasuda and M. Iidda, 'Conduction Mechanism of Leakage Current in $Ta_2O_5$ films on Si Prepared by LPCVD', J. Electrochem. Soc., Vol. 137, no. 9, pp. 2876, 1990   DOI
7 R. M. Fleming, D. V. Lang C.D. W. Jones, 'Defect dominate charge transport in amorphous $Ta_2O_5$ thin films', J. of Appl. Phys., Vol. 88, no. 2, pp. 850-862, 2000   DOI   ScienceOn
8 김인성, 이동윤, 송재성, 윤문수, 박정후, '$Ta_2O_5$ 커패시터 박막의 유전 특성과 열 안정성에 관한 연구', 대한전기학회논문지, 제 51C권, 5호, pp. 185, 2002. 5   과학기술학회마을
9 Shin-Ichiro Kimura, Yasushiro Nishioka, Akira Shintani and Kiichiro Mukai, 'Leakage-current in-crease in amorphous $Ta_2O_3$films due to pin-hole growth during annealing below $600^{\circ}C$', J. Electrochem. Soc. Vol. 130,, No. 129, pp. 2414, 1983   DOI
10 Nishioka Y., Kimura, S. Shinnriki, 'Dielectric Characteristics of Double layer Structure of Extremely Thin $Ta_2O_5/SiO_2$ Films on Si', J. of Electrochem. Soc., Vol. 34, pp. 410-422, 1987   DOI
11 A. G. revesz, J. H. Reynolds, and J. F. Allison, 'Optical Properties of Tantalum Oxide Films on Silicon', J. Electrochem. Soc., Vol. 123, no. 6, pp. 889, 1976   DOI
12 P. C. Joshi and M. W. Cole, 'Influence of postdeposition annealing on the enhanced structural and electrical properties of amorphous and crystalliane $Ta_2O_5$ thin films for dynamic random access memory application', J. Appl. Phy., Vol. 86, no. 2, pp. 871, 1999   DOI
13 H. S. Yang, Y. S. Choi and S. M. Cho, 'Preparation and Properties of $Ta_2O_5$ Film Capacitors Using $TiSi_2$ Bottom Electrode,'Journal of Electronic Materials, Vol. 28, no. 12, 1999   DOI
14 Lewis E. Hollander, and Patricia L. Castro, 'Dielectric Properties of Single-Crystal Nonstoichipmetric Rutile $(TiO_2)$', J. Appl. Phy., Vol. 33, no. 12, pp. 3421, 1962   DOI
15 Gottlieb S. Oehrlein, Thin Solid Films, Vol. 156, pp. 207, 1988   DOI   ScienceOn
16 H. Shinriki, M. Nakata, A. Nakao and S. Tachi, Extended Abstract of the 1991 International Conf. on Solid State Devices and Materials, pp. 198, 1991
17 J. A. Nielsen, C. P. Chien, F. Shi, 'Embedded Tantalum Pentoxide Thin Film Capacitor for Use in Power Electronic Application' 2000 International Conference on High-Density Interconnect and System Packing, Proceeding pp. 346, 2000