• 한국기계가공학회지
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• 제19권5호
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• pp.105-110
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• 2020

The global battery market is rapidly growing due to the development of vehicles(EV) and wireless electronic products. In particular logistics robots, which hielp to produce EVs, have attracted much interest in research in Korea Because logistics sites and factories operate continuously for 24 hours, the technology that can dramatically increase the operation time of the logistics equipment is rapidly developing, and various high-level technologies are required for the batteries used in. for example, logistics robots. These required technologies include those that enable rapid battery charging as well wireless charging to charge batteries while moving. The development of these technologies, however, result in increasing explosions and topical accidents involving rapid charging batteries These accidents due to the thermal shock caused by the heat generated during the charging of the battery cell. In this study, a performance evaluation of a heat dissipation design using infrared thermal imaging was performed on an energy storage systrm(Ess) applied with an internal heat conduction cooling method using a heating plate.

• 한국재료학회지
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• 제32권10호
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• pp.429-434
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• 2022

There is ongoing research to develop lithium ion batteries as sustainable energy sources. Because of safety problems, solid state batteries, where electrolytes are replaced with solids, are attracting attention. Sulfide electrolytes, with a high ion conductivity of 10^-3 S/cm or more, have the highest potential performance, but the price of the main materials is high. This study investigated lithium hydride materials, which offer economic advantages and low density. To analyze the change in ion conductivity in polymer electrolyte composites, PVDF, a representative polymer substance was used at a certain mass ratio. XRD, SEM, and BET were performed for metallurgical analyses of the materials, and ion conductivity was calculated through the EIS method. In addition, thermal conductivity was measured to analyze thermal stability, which is a major parameter of lithium ion batteries. As a result, the ion conductivity of LiH was found to be 10^-6 S/cm, and the ion conductivity further decreased as the PVDF ratio increased when the composite was formed.

• 한국전기전자재료학회논문지
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• 제29권10호
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• pp.652-658
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• 2016

Thermal batteries use inorganic salt as electrolyte, which is inactive at room temperature. As soon as heat pellets are fired by an igniter, all the solid electrolytes are instantly melted into excellent ionic conductors. However, the abnormal heat generation by the igniter flame or heat pellets causes the thermal decomposition of the electrode and the melting of the anode, eventually leading to a thermal runaway, which results in overheating or explosion. The thermal runaway can be significantly reduced by the adoption of $Zr/BaCrO_4$ heat papers. In this study, the heat papers with various ratios of fuel (Zr) and oxidizer ($BaCrO_4$) were prepared by the paper-making process. We have investigated the calorimetric value, burning rate, and ignition sensitivity. The ignition test of heat pellets and the discharge test of thermal batteries were also carried out. At the composition of 40 wt.% of Zr, the heat papers showed the highest specific calorimetric value and burning rate. As a result, $Zr/BaCrO_4$ heat paper made by the paper-making process has shown the applicability for thermal batteries.

• 한국군사과학기술학회지
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• 제15권6호
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• pp.820-826
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• 2012

For the development of reliable thermal batteries, electrolyte is quite important because it is closely related to the performance and stability of thermal batteries. This paper describes general image processing method used for the inspection of molten-salt based electrolyte disk and also describes how we can apply this image processing method to the inspection of thermal battery electrolyte. Moreover we have found optimized image processing conditions to improve the discriminating ability of compaction defects such as non-uniform parts in an electrolyte.

• Corrosion Science and Technology
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• 제22권1호
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• pp.36-43
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• 2023

Single-crystal Ni-rich NCM is a material that has drawn attention in the field of lithium-ion batteries due to its high energy density and long cycle life. In this study, we investigated the properties of single-crystal NCM 811 and its potential for use in lithium-ion batteries. High-quality single crystals of NCM 811 were successfully synthesized by crystal growth via a flux method. The single-crystal nature of the samples was confirmed through detailed characterization techniques, such as scanning electron microscopy and x-ray diffraction with Rietveld refinement. The crystal structure and electrochemical performances of the single-crystal NCM 811 were analyzed and compared to its poly-crystal counterpart. The results indicated that single-crystal NCM 811 had electrochemical performance and thermal stability superior to poly-crystalline NCM 811, making it a suitable candidate for high-performance batteries. The findings of this study contribute to a better understanding of the characteristics and potential of single-crystal NCM 811 for lithium-ion batteries.

• 산업기술연구
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• 제43권1호
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• pp.15-23
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• 2023

Lithium-ion batteries are predominantly employed in electric vehicles and energy storage devices, offering the advantage of high energy density. However, they are susceptible to efficiency degradation when operated at high temperatures due to their sensitivity to the external environment. In this study, we conducted experiments using an indirect cooling method to prevent thermal runaway and explosions in lithium-ion batteries. The results were validated by comparing them with heat transfer simulations conducted through a commercial finite element analysis program. The experiments included single-cell exothermic tests and cooling experiments on a battery pack with 10 cells connected in series, utilizing 21700 lithium-ion batteries. To block external temperature influences, the experimental environment featured an extrusion method insulation in the environmental chamber. The cooling system, suitable for indirect cooling, was constructed with copper tubes and pins. The heat transfer analysis began by presenting a single-cell heating model using commercial software, which was then employed to analyze the heating and cooling of the battery pack.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2015년도 제49회 하계 정기학술대회 초록집
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• pp.84.2-84.2
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• 2015

Growing market of electric vehicles such as hybrid, plug-in hybrid, and bare electric vehicles in the world is accelerating the significance of Li-ion batteries as a renewable green energy. According to such market flow, the developing components such as cathode, anode, electrolyte, and separator, composing the Li-ion batteries, is significantly important tasks for the commercialization. In particular, development of the cathode material having high capacity and stable thermal stability is essential for long-distance electric vehicle in the near future. Herein we introduce various applications of Li-ion batteries such as portable electronics, electric vehicles, and energy storage system, and also its research trend, in particular on the cathode materials.

• 한국수소및신에너지학회논문집
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• 제33권1호
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• pp.85-94
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• 2022

To detect anomaly signs of thermal runaway in advance, this study analyzed the signals from various sensors installed in lithium-ion batteries. The thermal runaway mechanism was analyzed, and measurement variables for anomalies of a battery cell were surface temperature, strain, and gas concentration. The changes and characteristics of three variables during the thermal runaway process were analyzed under the abuse environment: the overheat and the overcharge. In experiment, the thermal runaway of the battery proceeded in the initial developing stage, the outgassing stage, and the ignition stage. Analysis from the measured data indicated that the suitable variable to detect all stages of thermal runaway is the surface temperature of the battery, and surface strain is alternative.

• 한국전기전자재료학회논문지
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• 제35권4호
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• pp.398-406
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• 2022

In order to increase the electrochemical performance of thermal battery anode, LIFT anode having the same weight but a larger lithium content in electrodes was fabricated by mixing lithium, iron and titanium. By applying these electrodes, a single cell and a thermal battery were prepared, and the effect of LIFT anode on electrochemical performance was evaluated. The LIFT-applied single cell presented a better cell performance than LIFe-applied single cell at 500℃ and 550℃. The discharge performance of LIFT-applied single cell, which included the operating time (787s), specific capacity (1,683 Asg^-1), and electrode utilization (80.7%), was improved collectively compared to the LIFe applied single cell (736s, 1,245 As g^-1, and 74.6%) at 500℃. As the discharge progressed, the internal resistance of LIFT anode decreased, because the lithium migration path was formed due to the presence of large titanium particles among iron particles. These results were analyzed in terms of the microstructure of electrode using SEM. Energy density of LIFT-applied single cell also increased by 10% to 142.1 Wh kg^-1 compared to that of LIFe-applied single cell (127.4 Wh kg^-1). In addition, the LIFT-applied single cell presented a stable discharge performance for 6,500s without a short circuit which could occur by molten lithium under an open circuit voltage condition with a high pressure (4 kgf cm^-2). As observed in the high temperature thermal battery performance tests, the voltage and specific capacity of LIFT-applied thermal battery are superior to those of LIFe-applied thermal batteries, indicating that the energy density of LIFT-applied thermal batteries should remarkably increase.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2008년도 추계학술대회A
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• pp.538-543
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• 2008

A roller with a shaft and hot oil paths for pressing electrodes of polymer batteries were modeled and analyzed by FEM. There are many hot oil tubes in the roller and shaft, through which $72^{\circ}C$ hot oil flows for heating the surface of a roller and shaft. Thermal deformations and temperatures distributions of the roller and shaft were calculated and a convection boundary condition on surfaces was used. The influence of existence of a groove in the shaft on the flatness of a roller surface caused by thermal deformation was investigated. In addition, the amount of spring-back of electrodes under vacuum pressure and heating was calculated after the hot rolling process. It was shown from this study that the groove in one shaft had a favorable effect on the surface flatness.