• 제목/요약/키워드: Thermal Spectrum

검색결과 400건 처리시간 0.035초

PET 말단에 대한 인계난연제의 라디칼계 부가반응 (2) - 리소시놀비스다이페닐포스페이트의 반응 - (Radical Addition Reaction of Phosphorous based Flame Retardant with End Groups of PET (2) - Reaction of Resorcinol bis(diphenyl phosphate) -)

  • 김민관;손광호;김한도
    • 한국염색가공학회지
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    • 제24권1호
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    • pp.39-44
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    • 2012
  • To improve flame retardation of poly(ethylene terephthalate) (PET) against burning, resorcinol bis(diphenyl phosphate) (RDP), phosphorous containing flame retardant, was incorporated into PET backbone by radical reaction pathway. Radical endcapping of PET with RDP was confirmed by spectroscopic and thermal analysis. From 400 MHz $^{31}P$ solid state FT-NMR spectrum of PET with RDP (PET-RDP), phosphorus spectra peak in RDP was found at ca. -10 ppm. Furthermore, P-C bond stretching vibration peaks were found ca. $530cm^{-1}$ in FT-IR spectrums of PET-RDP. These results indicated that RDP can be chemically bound at the ends of PET by radical addition method. Thermal characteristics of pure PET (pPET) and PET-RDP were measured and evaluated by TGA thermal analysis. There was not significant changes in thermal characteristics of PET-RDP compared to that of pPET.

Loss of Coolant Accident Analysis During Shutdown Operation of YGN Units 3/4

  • Bang, Young-Seok;Kim, Kap;Seul, Kwang-Won;Kim, Hho-Jung
    • Nuclear Engineering and Technology
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    • 제31권1호
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    • pp.17-28
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    • 1999
  • A thermal-hydraulic analysis is conducted on the loss-of-coolant-accident (LOCA) during shutdown operation of YGN Units 3/4. Based on the review of plant-specific characteristics of YGN Units 3/4 in design and operation, a set of analysis cases is determined, and predicted by the RELAP5/MOD3.2 code during LOCA in the hot-standby mode. The evaluated thermal-hydraulic phenomena are blowdown, break flow, inventory distribution, natural circulation, and core thermal response. The difference in thermal-hydraulic behavior of LOCA at shutolown condition from that of LOCA at full power is identified as depressurization rate, the delay in peak natural circulation timing and the loop seal clearing (LSC) timing. In addition, the effect of high pressure safety injection (HPSI) on plant response is also evaluated. The break spectrum analysis shows that the critical break size can be between 1% to 2% of cold leg area, and that the available operator action time for the Sl actuation and the margin in the peak clad temperature (PCT) could be reduced when considering uncertainties of the present RELAP5 calculation.

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얼굴영상과 예측한 열 적외선 텍스처의 융합에 의한 얼굴 인식 (Design of an observer-based decentralized fuzzy controller for discrete-time interconnected fuzzy systems)

  • 공성곤
    • 한국지능시스템학회논문지
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    • 제25권5호
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    • pp.437-443
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    • 2015
  • 이 논문에서는 가시광선 얼굴영상과 그로부터 예측한 열 적외선 텍스처의 데이터 융합에 의한 얼굴인식 방법에 관하여 연구하였다. 제안하는 얼굴인식 기법은 가시광선 얼굴영상과 열 적외선 텍스처를 PCA에 의하여 낮은 차원의 특징공간에서 특징벡터로 변환한 다음, 다층 신경회로망을 사용하여 가시광선 영상 특징으로부터 얼굴의 열적외선 특징을 예측하여 열 적외선 텍스처를 생성하였다. 학습과정에서는 주어진 개체로부터 획득한 한 쌍의 가시광선 및 열 적외선 영상에 대해서 PCA를 이용하여 낮은 차원의 특징공간으로 변환한 다음, 가시광선 영상특징으로부터 열 분포 특징으로 매핑시키는 비선형 함수에 해당하는 신경회로망의 내부 파라미터를 결정한다. 학습된 신경회로망은 입력 가시광선 얼굴 특징으로부터 열 에너지 분포 특성의 PCA계수를 예측하고, 이로부터 열 적외선 텍스처를 생성한다. 대표적인 두 가지 얼굴인식 알고리즘 Eigenfaces와 Fisherfaces을 사용하여 NIST/Equinox 데이터베이스에 대하여 얼굴인식에 관한 실험을 수행하였다. 예측한 열 적외선 텍스처와 가시광선 얼굴영상의 데이터 융합결과는 가시광선 얼굴영상만을 사용한 경우에 비해서 얼굴인식의 성능이 개선되었음을 수신자 조작특성 (ROC) 및 첫 번째 매칭성능에 의하여 검증하였다.

원전 설비 열차폐를 위한 반사형 금속단열재의 내진 해석 (Seismic Analysis of the Reflective Metal Insulation for Thermal Shielding of Main Equipments of Nuclear Power Plants)

  • 김승현;이희남
    • 한국산학기술학회논문지
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    • 제17권6호
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    • pp.166-172
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    • 2016
  • 원자력발전소 일차 냉각계통 주요 설비의 외부면에 열차폐를 위해 설치되는 반사형 금속단열재의 내진 성능을 확인하기 위한 연구가 수행되었다. 추후 실제 내진 시험 수행을 대비하기 위해서 국내 내진시험 시설에서 시험이 가능한 시편의 크기와 무게의 한도를 고려하여 원전 원자로압력용기의 실제 동특성과 근접한 진동 특성을 가지는 축소모델을 설계하였다. 또한 축소모델의 외곽에 금속단열재를 설치한 유한요소해석 모델을 작성하였으며, 등가정적해석법 및 응답스펙트럼해석법을 통해서 국내 원전의 안전정지지진 층 응답스펙트럼을 적용하여 내진해석을 수행하였다. 보수성을 확보하기 위하여 일차 냉각계통 주요 기기들의 층 응답스펙트럼들을 포괄하는 포괄 응답스펙트럼을 작성하여 가진 데이터로서 사용하였다. 해석 결과 최대응력이 금속단열재 재질의 항복응력보다 충분히 작게 나오는 것을 확인하였고, 따라서 국산화 개발 중인 반사형 금속단열재가 안전정지지진이 발생할 경우에도 구조적 건전성을 유지할 수 있음을 해석을 통해 확인하였다. 본 연구 결과는 추후 수행할 예정으로 있는 내진시험 결과와 비교할 예정이며 이를 통하여 국산화된 금속단열재의 내진 성능을 확보할 수 있고 내진해석과 내진시험을 비교 분석하여 내진검증방법을 체계적으로 구축할 수 있을 것이다.

가시광 스펙트럼 영역에서 선택적인 투과와 내열충격성을 갖는 LAS계 글라스세라믹의 특성 (Characteristics of glass-ceramics of LAS system having high thermal shock resistance and selective transparency in visible region of spectrum)

  • 변우봉
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2003년도 하계학술대회 논문집 C
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    • pp.1565-1567
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    • 2003
  • LAS($Li_2O-Al_2O_3-SiO_2$)계에 전이금속과 희토류 이온을 첨가한 글라스세라믹의 colouring에 대한 특성 분석이 이루어졌다. 투과성이 높고, 내열 충격성이 우수한 글라스세라믹을 제조한 수 있었으며, 주 결정상은 ${\beta}$-eucryptite(SS)이었다. 또한 colouring에 의한 빛의 흡수 특성과 이러한 글라스세라믹에서의 colouring 이온의 구조적 상태가 조사되었다.

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Effect of Niobium on the Electronic Properties of Passive Films on Zirconium Alloys

  • Kim, Bo Young;Kwon, Hyuk Sang
    • Corrosion Science and Technology
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    • 제2권2호
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    • pp.68-74
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    • 2003
  • The effects of Niobium on the structure and properties(especially electric properties) of passive film of Zirconium alloys in pH 8.5 buffer solution are examined by the photo-electrochemical analysis. For Zr-xNb alloys (x = 0, 0.45, 1.5, 2.5 wt%), photocurrent began to increase at the incident energy of 3.5 ~ 3.7 eV and exhibited the $1^{st}$ peak at 4.3 eV and the $2^{nd}$ peak at 5.7 eV. From $(i_{ph}hv)^{1/2}$ vs. hv plot, indirect band gap energies $E_g{^1}$= 3.01~3.47 eV, $E_g{^2}$= 4.44~4.91 eV were obtained. With increasing Nb content, the relative photocurrent intensity of $1^{st}$ peak significantly increased. Compared with photocurrent spectrum of thermal oxide of Zr-2.5Nb, It was revealed that $1^{st}$ peak in photocurrent spectrum for the passive film formed on Zr-Nb alloy was generated by two types of electron transitions; the one caused by hydrous $ZrO_2$ and the other created by Nb. Two electron transition sources were overlapped over the same range of incident photon energy. In the photocurrent spectrum for passive film formed on Zr-2.5Nb alloy in which Nb is dissolved into matrix by quenching, the relative photocurrent intensity of $1^{st}$ peak increased, which implies that dissolved Nb act as another electron transition source.

초고온 태양열을 이용한 태양연료 생산기술 연구동향 (Review on the Solar Fuel Production Technology Using High-Temperature Solar Furnace)

  • 강용혁;김진수;이상남;윤환기;유창균
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2005년도 춘계학술대회
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    • pp.408-411
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    • 2005
  • Solar fuel production technology using high-temperature solar furnace was briefly reviewed in this paper. 'Hydrogen' which is known to be the most promising energy carrier in the near future is to be generated environment-friendly from non-carbon resources. Combination of solar furnace operated by concentrated solar energy and high-temperature thermal reactions could be one of the most efficient ways to fulfill this need eventually. Various reaction mechanisms are feasible within a wide spectrum of solar fuel production technology, but intensive research efforts in related key areas need to be taken for successful development and commercialization of the technology.

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근 적외선 건조기의 건조특성에 대한 연구 (A study on the Drying Characteristics of NIR Dryer)

  • 장영석
    • 한국태양에너지학회 논문집
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    • 제24권1호
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    • pp.21-27
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    • 2004
  • Near Infrared Ray (NIR) are primarily of interest to the high energy physicist. It is the intermediate portion of the spectrum, which extends from approximately 0.8 to 1.5 ${\mu}m$ and include a portion of the all of infrared, that is thermal radiation and is pertinent to heat transfer. It is important to study that temperature distribution of the drying materials by surface encompasses a range of NIR wave lengths. This study is to investigate the characteristics of NIR dryer by experimental results. it was made a comparison with various textiles, velocity ratio and distance of lamp and textiles. In case of spongy type textile the drying performance is the superior of all. The 0.15m distance drying effect of improvement 30% more than 0.26m distance between lamp and textiles. As the contained water increases, the drying speed for textile can be increased.

Sn-complexes를 이용한 OLED의 발광 특성 향상에 관한 연구 (Improvement of Luminance Properties of Blue OLEO using $SnDP(HPB)_2$)

  • 김동은;최규채;권영수
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2008년도 춘계학술대회 논문집 센서 박막재료연구회 및 광주 전남지부
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    • pp.121-122
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    • 2008
  • Blue emitting materials have been explored by various researchers. However, blue-emitting materials with high luminous efficiency, good color purity, and thermal stability are still much desired. In this study, we synthesized a new blue luminescent material, $SnDP(HPB)_2$ which is low molecular compound and thermal stability. The PL spectrum of $SnDP(HPB)_2$ was observed blue at the wavelength of 447nm. The ionization potential(IP) and the electron affinity(EA) of $SnDP(HPB)_2$ was measured to be 6.7 eV and 3.0 eV, respectively. The fundamental structure of the OLED was ITO/NPB/$SnDP(HPB)_2/Alq_3$/LiF/Al. As a Result, we obtained to enhance the performance of blue OLED.

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바크하우젠 노이즈 해석에 의한 재료의 열화도 평가 (Degradation Estimation Of Material by Barkhausen Noise Analysis)

  • 이명호
    • 한국공작기계학회논문집
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    • 제14권3호
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    • pp.38-46
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    • 2005
  • The destructive method is reliable and widely used for the estimation of material degradation but it have time-consuming and a great difficulty in preparing specimens from in-service industrial facilities. Therefore, the estimation of degraded structural materials used at high temperature by nondestructive evaluation such as electric resistance method, replica method, Barkhausen noise method, electro-chemical method and ultrasonic method are strongly desired. In this study, various nondestructive evaluation(NDE) parameters of the Barkhausen noise method, such as MPA(Maximum Peak Amplitude), RMS, IABNS(Internal Area of Barkhausen Noise on Signal) and average amplitude of frequency spectrum are investigated and correlated with thermal damage level of 2.25cr-1.0Mo steel using wavelet analysis. Those parameters tend to increase while thermal degradation proceeds. It also turns out that the wavelet technique can help to reduce experimental false call in data analysis.