Textile Coloration and Finishing (한국염색가공학회지)

The Korean Society of Dyers and Finishers (한국염색가공학회)
권호 표지
DOI QR코드

DOI QR Code

Radical Addition Reaction of Phosphorous based Flame Retardant with End Groups of PET (2) - Reaction of Resorcinol bis(diphenyl phosphate) -

PET 말단에 대한 인계난연제의 라디칼계 부가반응 (2) - 리소시놀비스다이페닐포스페이트의 반응 -

  • Kim, Min-Kwan (Department of Advanced Organic Materials Science and Engineering, Kyungpook National University) ;
  • Sohn, Kwang-Ho (Department of Fire Protection Engineering, Gymcheon University) ;
  • Ghim, Han-Do (Department of Advanced Organic Materials Science and Engineering, Kyungpook National University)
  • 김민관 (경북대학교 기능물질공학과) ;
  • 손광호 (김천대학교 소방학과) ;
  • 김한도 (경북대학교 기능물질공학과)
  • Received : 2012.01.12
  • Accepted : 2012.03.12
  • Published : 2012.03.27
Download PDF
⟨ Previous Next ⟩

Abstract

To improve flame retardation of poly(ethylene terephthalate) (PET) against burning, resorcinol bis(diphenyl phosphate) (RDP), phosphorous containing flame retardant, was incorporated into PET backbone by radical reaction pathway. Radical endcapping of PET with RDP was confirmed by spectroscopic and thermal analysis. From 400 MHz $^{31}P$ solid state FT-NMR spectrum of PET with RDP (PET-RDP), phosphorus spectra peak in RDP was found at ca. -10 ppm. Furthermore, P-C bond stretching vibration peaks were found ca. $530cm^{-1}$ in FT-IR spectrums of PET-RDP. These results indicated that RDP can be chemically bound at the ends of PET by radical addition method. Thermal characteristics of pure PET (pPET) and PET-RDP were measured and evaluated by TGA thermal analysis. There was not significant changes in thermal characteristics of PET-RDP compared to that of pPET.

Keywords

References

  1. R. W. Stackman, Phosphorus Based Additives for Flame Retardant Polyester. 1. Low Molecular Weight Additives, Ind. Eng. Chem. Prod. Res. Dev., 21, 328-331(1982). https://doi.org/10.1021/i300006a027
  2. G. Koo and J. Jang, Breathable Water Proof Finish of PET Fabrics via Microporous UV Coating of Polyurethane Diacrylate, Textile Coloration and Finishing(J. of Korean Soc. Dyers & Finishers), 22, 239-245(2010). https://doi.org/10.5764/TCF.2010.22.3.239
  3. Y. S. Kim, S. J. Lee and Y. A. Son, Dyeing Properties of Acid and Reactive Dye for Super Soft Angora/PET, Nylon Blended Fabric, Textile Coloration and Finishing(J. of Korean Soc. Dyers & Finishers), 22, 332-340(2010). https://doi.org/10.5764/TCF.2010.22.4.332
  4. L. Yu, S. Zhang, W. Liu, X. Zhu, X. Chen and X. Chen, Improving the Flame Retardancy of PET Fabric by Photo-induced Grafting, Polym. Deg. Stab., 95, 1934-1942(2010). https://doi.org/10.1016/j.polymdegradstab.2010.04.005
  5. H. A. Lecomte and J. J. Liggat, Commercial Fireretarded PET Formulations-Relationship between Thermal Degradation Behaviour and Fire-retardant Action, Polym. Deg. Stab., 93, 498-506(2008). https://doi.org/10.1016/j.polymdegradstab.2007.11.005
  6. S. Liu and G. Sun, Functional Modification of Poly (ethylene terephthalate) with an Allyl Monomer: Chemistry and Structure Characterization, Polymer, 49, 5225-5232(2008). https://doi.org/10.1016/j.polymer.2008.09.054
  7. C. Nguyen and J. Kim, Thermal Stabilities and Flame Retardancies of Nitrogen-Phosphorus Flame Retardants Based on Bisphosphoramidates, Polym. Deg. Stab., 93, 1037-1043(2008). https://doi.org/10.1016/j.polymdegradstab.2008.03.024
  8. H. Vothi, C. Nguyen, K. Lee and J. Kim, Thermal Stability and Flame Retardancy of Novel Phloroglucinol Based Organo Phosphorus Compound, Polym. Deg. Stab., 95, 1092-1098(2010). https://doi.org/10.1016/j.polymdegradstab.2010.02.024
  9. G. Xue, Orientation Studies of Poly(ethylene terephthalate) Film and Fiber Surfaces Using FT-IR Diffuse Reflectance Optics, Makromol. Chem. Rapid. Commun., 6, 811-814(1985). https://doi.org/10.1002/marc.1985.030061204
  10. G. Socrates, "Infrared and Raman Characteristic Group Frequencie, 3rd ed.", John Wiley & Sons, NY, pp.229-240, 2001.
  11. S. Liu, L. Jiang, Z. Jiang, J. Zhao, and Y. Fu, The Impact of Resorcinol bis(diphenyl phosphate) and Poly(phenylene ether) on Flame Retardancy of PC/PBT Blends, Polym. Adv. Technol., 22, 2392-2402(2011). https://doi.org/10.1002/pat.1775
  12. B. N. Jang and C. A. Wilkie, The Effects of Triphenylphosphate and Resorcinol bis(diphenylphosphate) on The Thermal Degradation of Polycarbonate in Air, Thermochimica Acta, 433, 1-12 (2005). https://doi.org/10.1016/j.tca.2005.01.071
  13. E. A. Murashko, G. F. Levchik, S. V. Levchik, D. A. Bright, and S. Dashevsky, Fire-Retardant Action of Resorcinol Bis(diphenyl Phosphate) in PC-ABS Blend. II. Reactions in the Condensed Phase, J. App. Polym. Sci., 71, 1863-1872(1999). https://doi.org/10.1002/(SICI)1097-4628(19990314)71:11<1863::AID-APP17>3.0.CO;2-O
  14. Q. He, L. Song, Y. Hu and S. Zhou, Synergistic Effects of Polyhedral Oligomeric Silsesquioxane (POSS) and Oligomeric Bisphenyl A bis(diphenyl phosphate) (BDP) on Thermal and Flame Retardant Properties of Polycarbonate, J. Mater. Sci., 44, 1308-1316(2009). https://doi.org/10.1007/s10853-009-3266-5
  15. B. J. Holland and J. N. Hay, The Thermal Degradation of PET and Analogous Polyesters Measured by Thermal Analysis-Fourier Transform Infrared Spectroscopy, Polymer, 43, 1835-1847(2001). https://doi.org/10.1016/S0032-3861(01)00775-3
  16. B. Perret, K. H. Pawlowski and B. Schartel, Fire Retardancy Mechanisms of Arylphosphates in Polycarbonate(PC) and PC/Acrylonitrile-Butadiene-Styrene, J. Therm. Anal. Calorim., 97, 949-958(2009). https://doi.org/10.1007/s10973-009-0379-7
  17. K. H. Pawlowski and B. Schartel, Flame Retardancy Mechanisms of Triphenyl Phosphate, Resorcinol bis(diphenyl phosphate) and Bisphenol A bis(diphenyl phosphate) in Polycarbonate/Acrylonitrile-Butadiene -Styrene Blends, Polym. Int., 56, 1404-1414(2007). https://doi.org/10.1002/pi.2290
  18. S. Y. Lu and I. Hamerton, Recent Developments in The Chemistry of Halogen-Free Flame Retardant Polymers, Prog. Polym. Sci., 27, 1661-1712(2002). https://doi.org/10.1016/S0079-6700(02)00018-7

Cited by

  1. Fabrication and Characteristics of Flame Retardant Fabric Developed by using Bicomponent Filament vol.25, pp.2, 2013, https://doi.org/10.5764/TCF.2013.25.2.110