• Proceedings of the KSME Conference
• /
• 2000.04b
• /
• pp.949-955
• /
• 2000

Numerical study with detailed chemistry has been conducted to investigate the NOx formation and structure in $CH_4/Air-CO_2$ counterflow diffusion flames. The importance of radiation effect is identified and the role of $CO_2$ addition is addressed to thermal and chemical reaction effects, which can be precisely specified through the introduction of an imaginary species. Also NO separation technique is utilized to distinguish the contribution of thermal and prompt NO formation mechanisms. The results are as follows : The radiation effect is dominant at low strain rates and it is intensified by $CO_2$ addition. Thermal effect mainly contributes to the changes in flame structure and the amount of NO formation but the chemical reaction effect also cannot be neglected. It is noted that flame structure is changed considerably due to the addition of $CO_2$ in such a manner that the path of methane oxidation prefers to take $CH_4 {\rightarrow}CH_3{\rightarrow}C_2H_6{\rightarrow}C_2H_5$ instead of $CH_4 {\rightarrow}CH_3{\rightarrow}CH_2{\rightarrow}CH$. At low strain rate(a=10) the reduction of thermal NO is dominant with respect to reduction rate, but that of prompt NO is dominant with respect to total amount.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 2002.07b
• /
• pp.917-921
• /
• 2002

In this paper, we made different types of non-thermal plasma reactors such as Metal-particle reactor with $Al_2O_3$ to measure NOx removal characteristic and the dielectric effect for NOx removal. NOx removal rate is not so good when we use just dielectric of $Al_2O_3$ at the Metal-particle reactor, also we just put sludge pellets(100%) without Metal-particle reactor with $Al_2O_3$ and dielectric such as $TiO_2$, $BaTiO_3$ to measure the effect of sludge for NOx removal so that NOx removal rate is almost the same. However NOx removal rate is more than 90% in case of the reactor of composition shape used both dielectric of $Al_2O_3$ and sludge pellets at the same time. In case of the shape of plasma reactor with dielectric, the Metal-particle reactor with $Al_2O_3$, and the metal-particle reactor with both $Al_2O_3$ and dielectric such as $TiO_2$, $BaTiO_3$ at the same time, they are almost the same effect for NOx removal, so we made MNPR(Metal-particle Non-thermal Plasma Reactor with $Al_2O_3$) to reduce these kinds of demerits. Finally, we think MNPR should be much better than other reactors for NOx removal.

• 한국연소학회:학술대회논문집
• /
• 2006.10a
• /
• pp.122-127
• /
• 2006

The objective of this research is to determine generally applicable design principles for the development of Rapid mix burner. Details operating RMB(Rapid mix burner) is designed that thermal NOx and prompt NOx formation be reduced through control of low peak flame temperature, and nearly uniform flame temperature by rapid mixing at the ignition point. Results from RMB(Rapid mix burner) achieving lower than 43 ppm NOx emissions and nearly flame temperature uniform

• 한국연소학회:학술대회논문집
• /
• 2003.12a
• /
• pp.299-308
• /
• 2003

This paper provides a review of the status and of the perspectives of advanced catalytic combustion for ultra clean combustion of gas turbines and for industrial combustors. The development of catalytic materials and their combustion techniques for gas turbines are briefly reported. The fuel-rich approaches to catalytic combustion are mentioned for a new technology of thermal- and fuel-NOx control. The fuel-rich catalytic combustion are also applicable to the combustor of ceramic gas turbine, and to the combustion of biomess and municipal waste sludge. Some extended technologies of combustion synthesis are introduced for the synthesis of carbon nanotube and of Perovskite combustion catalysts

• Journal of Power System Engineering
• /
• v.18 no.3
• /
• pp.14-19
• /
• 2014

The purpose of the study is to investigate the effect of additive catalyst according to the thermal aging of vanadia SCR catalysts. At a fresh condition, the $3V_2O_5-5WO_5-92TiO_2$ SCR showed the highest NOx conversion rate of about 30%, the performance of 5 kinds of SCR to which additive catalysts were added was not improved due to the insignificant effect of acid site control. For catalysts aged for 12h at $700^{\circ}C$, the SCR to which 3wt% Zeolite was added decreased in NOx conversion rate by 2.5% on average compared to the fresh SCR, it showed higher thermal durability than other additive catalyst. For 3Zeolite with high performance of NOx conversion rate during thermal aging, the Zeolite with stronger durability at a high temperature than other 5 kinds of SCR catalysts decreased the sintering of catalysts.

• Journal of the Korean Applied Science and Technology
• /
• v.30 no.3
• /
• pp.451-460
• /
• 2013

NOx from the thermal power plants are NO and $NO_2$. This work investigated the chemical/physical characteristics and SCR efficiency of newly prepared catalysts including tungsten ($WO_3$), molybdenum ($MoO_3$) and antimony ($SbO_3$) based on vanadia($V_2O_5$) over titania($TiO_2$). As a result of the examination, the surface area of the catalysts promoted with additional metals was larger and the de-NOx efficiency also was enhanced with temperature. The most efficient catalytst was $V_2O_5/TiO_2-WO_3$(10%) at $200^{\circ}C$. Such a high efficiency could contribute to reduce the ammonia slip.

• Journal of Sensor Science and Technology
• /
• v.5 no.6
• /
• pp.43-50
• /
• 1996

It is very important to improve the combustion efficiency and reduce pollutant emission in order to save energy and environment. Especially, thermal NOx has been reduced through monitoring burner flame, because the thermal NOx is strongly related to flame characteristics. In this work, a flame-monitoring system was fabricated with photodiode, optical fiber, interference filter and data acquisition system, and it was applied to a lab-scale methane combustion system and a testing facility. Flame intensity and mean frequency increased with increasing turbulent intensity and fuel loading. The sensor signal from flame fluctuations differed from that without flame, which showed the availability af the flame scanner to find the presence of flame. NOx emissions increased with flame intensity.

• Proceedings of the Korea Air Pollution Research Association Conference
• /
• 1996.04a
• /
• pp.161-162
• /
• 1996

• Journal of the Korean Society of Propulsion Engineers
• /
• v.11 no.4
• /
• pp.1-9
• /
• 2007

Many processing companies are facing environmental regulations such as decreasing NOx emissions when they by to increase thermal efficiencies of combustor. We study a potential new method that may achieve both increase of thermal efficiency and decrease of NOx emissions. This new concept of burner, the precessing jet burner, is known to significantly reduce pollutants such as NOx emissions and simultaneously increase radial heat transfer. This precessing jet nozzle may increase the combustion efficiency of gas turbine engine. A basic research on characteristics of precessing jet nozzle has been conducted using FLUENT and laser visualization technique. Velocities at He nozzle cross-section are compared with the published experimental results. Precessing jet nozzle with centerbody results in better precessing phenomena.

• Transactions of the Korean Society of Automotive Engineers
• /
• v.15 no.3
• /
• pp.147-152
• /
• 2007

This study investigates the aging characteristics of NOx storage and reduction(NSR) catalyst on the emission conditions of lean burn natural gas vehicles. We designed various NSR catalysts using by the double-layer washcoat technology to increase of a surface area and a thermal durability performance of the catalysts. The experiments were conducted with 3 kinds of the NSR catalysts, which were manufactured using by a honeycomb cordierite substrate. It was found that Ba is weak in the thermal aging because it has lower melting temperature than that of precious metals (PMs). The suitable loading amount of Ba in this study should be about 42 g/L from the results of the NOx adsorption and the NOx reduction efficiency. The major reason in deactivation of the NSR catalyst is the decrease of the adsorption site owing to the agglomeration and sintering of Ba rather than PM aging by hydrothermal aging. It was confirmed by results of BET, SEM and TEM.