• Title/Summary/Keyword: Thermal NO$_{}$ x/

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The Study on The Magnetic Properties of Amorphous Fe-B-Si-Ge Ribbons (Fe-B-Si-Ge 비정질 리본의 자기적 특성 연구)

  • 민복기
    • Electrical & Electronic Materials
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    • v.10 no.2
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    • pp.113-118
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    • 1997
  • For the amorphous F $e_{78}$ $B_{13}$S $i_{9-x}$G $e_{x}$ alloy, thermal analysis and measurements of the magnetic properties were carried out. As the content of Ge increased, the crystallization temperature was decreased and the Curie temperature was increased, and the tendencies were almost linear. The core loss of the amorphous alloy for x=1.7, field annealed at optimized condition, was 0.057 W/kg(l.0T, 60Hz), which was about 30% lower than that of no Ge added amorphous alloy (basic composition). Such a low core loss characteristics was thought to be caused by the lower coercive force and good squareness of B-H loop of the alloy.y.y.

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Characterization of NOx Reduction on Filter Bag Support System at Low Temperature using Powder Type MnOx and V2O2/TiO2 Catalysts (분말형 MnOx와 V2O2/TiO2 촉매를 이용한 저온영역의 백필터 공정에서 질소산화물 제거 특성)

  • Kim, Byung-Hwan;Kim, Jeong-Heon;Kang, Pil-Sun;Yoo, Seung-Kwan
    • Journal of Korean Society for Atmospheric Environment
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    • v.26 no.1
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    • pp.1-9
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    • 2010
  • In this study, the selective catalytic reduction of $NO_x$ with ammonia was carried out in a filter bag support reactor. The experiments were performed by powder type $MnO_x$ and $V_2O_5$/$TiO_2$ catalyst at low temperature between 130 and $250^{\circ}C$. Also, the effect of $SO_2$ and $H_2O$ on the NO conversion was investigated under our test conditions. The powder type catalysts were analyzed by X-ray photoelectron spectrum (XPS), X-ray diffraction(XRD), scanning electron microscopy (SEM) and thermal gravimetric analysis (TGA). It was observed that NO removal efficiency of the powder type $V_2O_5$/$TiO_2$ catalyst was 85% at low temperature($200^{\circ}C$) under presence of oxygen and that of $MnO_x$ was 50% at the same condition. The powder type $V_2O_5$/$TiO_2$ catalyst, in conclusion, was found to be available for SCR reaction in a filter bag support system.

Synthesis and Characterization of Te-rich $Sb_xTe_{1-x}$ Nanowires and Nanotubes (Te이 과량 포함된 $Sb_xTe_{1-x}$ 나노와이어 및 나노튜브의 합성 및 분석)

  • Lee, Joon-Suk;No, Kwang-Soo;Jung, Soon-Won;Yoon, Sung-Min;Yu, Byoung-Gon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.423-423
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    • 2008
  • One dimensional (1D) nanostructures, including nanowires, nanorods, nanobelts, and nanotubes, have been the focus of current research on nanotechnology because of their fundamental significance in chemistry, physics, materials science and engineering, and potential applications in nanoelectronics. We have synthesized Te-rich $Sb_xTe_{1-x}$ nanowires and nanotubes via thermal evaporation method under vapor-solid mechanism. The physical morphology and chemical composition of the fabricated nanowires and nanotubes were investigated by scanning electron microscopy (SEM), transmission electron microscopy (TEM), and energy dispersive X-ray spectroscopy (EDX).

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A Study on Heat Exchange Efficiency of EGR Cooler for Diesel Engine to Meet Euro-5 Emission Regulation (Euro-5 대응 디젤엔진용 EGR 쿨러의 열교환 효율 연구)

  • Lee, Joon;Han, Chang-Suk
    • Transactions of the Korean Society of Automotive Engineers
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    • v.15 no.3
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    • pp.183-188
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    • 2007
  • Recently, diesel engine has been frequently applied to RV, SUV and light duty truck due to the good fuel economy and high thermal efficiency. $NO_x$ and PM, environmental pollution materials are basically produced in diesel combustion process. The most important target in diesel engine research is the development of system to reduce the emissions of $NO_x$ and PM. Cooled EGR system is an effective method for the reduction of $NO_x$ emission and PM emission from a diesel engine and EGR cooler is the key component of the system. This study investigates the EGR cooler of oval gas tubes compared with the EGR cooler of shell & tubes to verify the heat exchange efficiency of cooler by means of engine dynamometer tests, rig performance tests and numerical analyses.

Synthesis, Structures and Properties of Two Metal-organic Frameworks Derived from 3-Nitro-1,2-benzenedicarboxylic Acid

  • Xu, Wen-Jia;Zhang, Ling-Yu;Tang, Jin-Niu;Wang, Dai-Yin;Pan, Gang-Hong;Feng, Yu
    • Bulletin of the Korean Chemical Society
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    • v.34 no.8
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    • pp.2375-2380
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    • 2013
  • Two metal-organic frameworks based on the connectivity co-effect between rigid benzenedicarboxylic acid and bridging ligand have been synthesized $[Zn_2(3-NO_2-bdc)_2(4,4'-bpy)_2H_2O]_n$ (1), $[Co(3-NO_2-bdc)(4,4'-bpy)H_2O]_n$ (2) (where $3-NO_2-bdcH_2$ = 3-nitro-1,2-benzenedicarboxylic acid, 4,4'-bpy = 4,4'-bipyridine). The two novel complexes were characterized by IR spectrum, elemental analysis, fluorescent properties, thermogravimetric analysis, single-crystal X-ray diffraction and powder X-ray diffraction (PXRD). X-ray structure analysis reveals that 1 and 2 are two-dimensional (2D) network structures. Complex 1 and complex 2 belong to triclinic crystal with P-1 space group. The luminescence measurements reveal that two complexes exhibit good fluorescent emissions in the solid state at room temperature. Also, thermal decomposition process and powder X-ray diffraction of complexes were investigated.

Control of pretilt angles on $SiO_x$ Thin Film by Electron Beam Evaporation Method (전자빔 경사증착을 이용한 $SiO_x$ 박막의 프리틸트각 제어)

  • Kang, Hyung-Ku;Kim, Young-Hwan;Kim, Jong-Hwan;Han, Jin-Woo;Kang, Soo-Hee;Hwang, Jeoung-Yeon;Seo, Dae-Shik
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.11a
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    • pp.311-312
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    • 2005
  • By using 45$^{\circ}$ obliqued evaporation method with electron beam system, uniformly vertical liquid crystal (LC) alignment was achieved. And a high pretilt angles of about 2.5$^{\circ}$ were measured. Also, it was verified that there are no variations of pretilt angle as a function of $SiO_x$ thin film thickness 20nm and 50nm. A good LC alignment states were observed at annealing temperature of 250$^{\circ}C$. The high pretilt angle and the good thermal stability of LC alignment by 45$^{\circ}$ obliqued electron beam evaporation method on the $SiO_x$ thin film can be achieved.

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A Study of Nitrous Oxide Thermal Decomposition and Reaction Rate in High Temperature Inert Gas (고온 불활성 기체 분위기에서 아산화질소 열분해 및 반응속도에 관한 연구)

  • Lee, Han Min;Yun, Jae Geun;Hong, Jung Goo
    • Journal of ILASS-Korea
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    • v.25 no.3
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    • pp.132-138
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    • 2020
  • N2O is hazardous atmosphere pollution matter which can damage the ozone layer and cause green house effect. There are many other nitrogen oxide emission control but N2O has no its particular method. Preventing further environmental pollution and global warming, it is essential to control N2O emission from industrial machines. In this study, the thermal decomposition experiment of N2O gas mixture is conducted by using cylindrical reactor to figure out N2O reduction and NO formation. And CHEMKIN calculation is conducted to figure out reaction rate and mechanism. Residence time of the N2O gas in the reactor is set as experimental variable to imitate real SNCR system. As a result, most of the nitrogen components are converted into N2. Reaction rate of the N2O gas decreases with N2O emitted concentration. At 800℃ and 900℃, N2O reduction variance and NO concentration are increased with residence time and temperature. However, at 1000℃, N2O reduction variance and NO concentration are deceased in 40s due to forward reaction rate diminished and reverse reaction rate appeared.

An Experimental Study on the Effect of Combined X-ray and Microwave Hyperthermia on the Rectum and Urinary Bladder of Rats (흰쥐의 직장과 방광에 X-선 조사와 마이크로파 온열요법의 효과에 관한 실험적 연구)

  • Lee, Kyung-Ja;Rhee, Chung-Sik
    • Radiation Oncology Journal
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    • v.4 no.2
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    • pp.115-128
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    • 1986
  • Hyperthermia can enhance the radiation effect as a synergistic reaction in combined X-ray irradiation and hyperthermia; hyperthermia sensitize radioresistant S-phase cells and inhibit cellular recovery from sublethal damage. We fabricated 100 watts, 2450 MHz microwave applicator for hyperthermia and planned the method and condition of heating and measured the temperature by using Agar phantom as a preliminary test. For biological examination, 102 rats were divided into 4 groups as hyperthermia, X-ray irradiation (6Gy-15Gy), combined X-ray and hyperthermia, and normal control groups. Microscopic examination of the rectum and bladder was done and the results were as followings: 1. The microwave generator with 100 watts, 2450MHz magnetron could be heating up to $40^{\circ}{\sim}50^{\circ}C$ for one hour in living tissue. 2. The thermal distribution in tissue equivalent phantom with microwave can be maintained at $40^{\circ}{\sim}44^{\circ}C$ in area of 3cm in depth and 2-10cm in diameter. 3. In Hyperthermia alone group, there was submucosal edema of the rectum but no histologic change in the urinary bladder was seen. 4. The minimal necrosis of the mucosa was appeared in the rectum and bladder after 15 days of 6 Gy and 8 Gy irradiation respectively. The minimal necrosis of the muscle layer of rectum and bladder was appeared after 15 days of 8Gy and 60days of 10Gy irradiation respectively. 5. In combined group of radiation and hyperthermia, thermal enhancement ratio (calculated at necrosis of mucosa and muscle layer) of rectum and bladder was 1.0, and it suggest that there is no change of tolerance dose of normal rectum and bladder.

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Drying Characteristics of a Radiative Industrial Dryer Adopting a Mat-Type Premixed Catalytic Burner (매트 형태의 예혼합 촉매 버너에 의한 복사 건조 특성)

  • Kim, Hyouck-Ju;Ahn, Joon;Song, Kwang-Sup
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.35 no.7
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    • pp.735-742
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    • 2011
  • A catalytic burner that utilizes the thermal energy from fossil fuels without the emission of nitrogen oxides ($NO_x$) has been developed. For this purpose, the newly developed burner has two features: firstly, it is in the shape of a flat mat so as to maximize its heating surface, and secondly, it adopts premixed combustion so that it can be used in a closed space. In the present study, the burner was used in a radiation-type industrial dryer. This dryer yields thermal energy in the form of thermal radiation in the infrared regime, which has been proved to be effective for drying organic substances under low-moisture conditions. Analysis of the experimental data has proved that the thermal efficiency of the dryer is better correlated to the moisture than to the dry rate

Synthesis of $La_{1-x}Sr_xCoO_3$ (x≤0.2) at Low Temperature from PVA-polymeric Gel Precursors

  • 권호진;박동곤;국승태;박휴범;김건
    • Bulletin of the Korean Chemical Society
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    • v.18 no.12
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    • pp.1249-1256
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    • 1997
  • Single phase La1-xSrxCoO3 (x≤0.2) was synthesized as a uniform sized 100 nm particulates with relatively high surface area of 20-30 m2/g, at low temperature (≥600 ℃), from a polymeric gel precursors prepared by using poly(vinyl alcohol) as homogenizer. No minor phase developed during the crystallization when polymer/metal mole ratio was higher than 3. As the polymer/metal mole ratio was raised in the gel, the amount of carbonaceous residues in the amorphous solid precursor prepared by heating the gel at 300 ℃ increased. Most of the residues were eliminated by exothermic thermal decomposition around 400 ℃. The amount of residual carbon (less than 1%) left in the crystalline La1-xSrxCoO3 decreased as more polymer was used, eliminating detrimental effect which might be posed by using large amount of organic homogenizer. The crystal structure of La1-xSrxCoO3 synthesized at temperature lower than 800 ℃ was observed to be shifted from rhombohedral to more symmetric cubic. The structure shifted back to rhombohedral as the cubic sample was annealed at 1000 ℃.