[KSCI] Korea Science Citation Index Service

http://dx.doi.org/10.5012/bkcs.2013.34.8.2375

Synthesis, Structures and Properties of Two Metal-organic Frameworks Derived from 3-Nitro-1,2-benzenedicarboxylic Acid

Xu, Wen-Jia (College of Chemistry and Chemical Engineering, Guangxi University for Nationalities)
Zhang, Ling-Yu (College of Chemistry and Chemical Engineering, Guangxi University for Nationalities)
Tang, Jin-Niu (College of Chemistry and Chemical Engineering, Guangxi University for Nationalities)
Wang, Dai-Yin (College of Chemistry and Chemical Engineering, Guangxi University for Nationalities)
Pan, Gang-Hong (College of Chemistry and Chemical Engineering, Guangxi University for Nationalities)
Feng, Yu (College of Chemistry and Chemical Engineering, Guangxi University for Nationalities)

Publication Information

Bulletin of the Korean Chemical Society / v.34, no.8, 2013 , pp. 2375-2380 More about this Journal

Abstract

Two metal-organic frameworks based on the connectivity co-effect between rigid benzenedicarboxylic acid and bridging ligand have been synthesized $$[Zn_2(3-NO_2-bdc)_2(4,4$ $]$ $_n$$ (1), $$[Co(3-NO_2-bdc)(4,4$ $]$ $_n$$ (2) (where $3-NO_2-bdcH_2$ = 3-nitro-1,2-benzenedicarboxylic acid, 4,4'-bpy = 4,4'-bipyridine). The two novel complexes were characterized by IR spectrum, elemental analysis, fluorescent properties, thermogravimetric analysis, single-crystal X-ray diffraction and powder X-ray diffraction (PXRD). X-ray structure analysis reveals that 1 and 2 are two-dimensional (2D) network structures. Complex 1 and complex 2 belong to triclinic crystal with P-1 space group. The luminescence measurements reveal that two complexes exhibit good fluorescent emissions in the solid state at room temperature. Also, thermal decomposition process and powder X-ray diffraction of complexes were investigated.

Keywords

X-ray crystal diffraction; 3-Nitro-1,2-benzenedicarboxylic acid; Two-dimensional network polymer;

Citations & Related Records

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