• 한국환경과학회지
• /
• 제20권12호
• /
• pp.1607-1615
• /
• 2011

The adsorption performance of cupper and zinc ions($Cu^{2+}$ and $Zn^{2+}$) in aqueous solution was investigated by an adsorption process on reagent grade Na-A zeolite(Z-WK) and Na-A zeolite (Z-C1) prepared from coal fly ash. Z-C1 was synthesized by a fusion method with coal fly ash from a thermal power plant. Batch adsorption experiment with Z-C1 was employed to study the kinetics and equilibrium parameters such as initial metal ions concentration and adsorption time of the solution on the adsorption process. Adsorption rate of metal ions occurred rapidly and adsorption equilibrium reached at less than 120 minutes. The kinetics data of $Cu^{2+}$ and $Zn^{2+}$ ions were well fitted by a pseudo-second-order kinetics model more than a pseudo-first-order kinetics model. The equilibrium data were well fitted by a Langmuir model and this result showed $Cu^{2+}$ and $Zn^{2+}$ adsorption on Z-C1 would be occupied by a monolayer adsorption. The maximum adsorption capacity($q_{max}$) by the Langmuir model was determined as $Cu^{2+}$ 99.8 mg/g and $Zn^{2+}$ 108.3 mg/g, respectively. It appeared that the synthetic zeolite, Z-C1, has potential application as absorbents in metal ion recovery and mining wastewater.

• 한국신재생에너지학회:학술대회논문집
• /
• 한국신재생에너지학회 2008년도 추계학술대회 논문집
• /
• pp.254-257
• /
• 2008

For crystalline slags, of which the viscosity rapidly increases at $T_{cv}$ due to the formation of crystalline phases, the Tcv is affected by measurement conditions. In this study, we investigated the effect of cooling rate, and alumina dissolution on the determination of $T_{cv}$. Using synthetic slag samples based on the composition of Alaska Usibelli slag, $T_{cv}$ were determined under a constant cooling rate of $2^{\circ}C$/min, and under rapid cooling with holding time to allow the slag to reach thermal and rheological equilibrium. The effect of alumina dissolution was investigated using platinum lined crucibles. The constant cooling resulted in lower $T_{cv}$ by $33^{\circ}C$ as compared to the equilibrium measurements. Under $2^{\circ}C$/min cooling, the blocking alumina dissolution resulted in lower $T_{cv}$ by $23^{\circ}C$. When the $T_{cv}$ was measured under $2^{\circ}C$/min cooling using an alumina crucible, therefore, the effects of a constant cooling is somewhat offset by the alumina dissolution effect, and bring the measured value closer to the true value.

• 한국지반공학회논문집
• /
• 제38권9호
• /
• pp.45-52
• /
• 2022

암반내 불연속면이나 지반-구조물의 접촉면은 열-수리-역학적으로 연계된 거동 특성을 보이므로, 온전한 지배방정식에 근거한 경계면 요소의 개발이 필요하다. 본 논문은 경계면 요소에 대한 힘평형 방정식, 유체의 연속방정식 그리고 에너지 평형 방정식을 유도하였다. 그리고 경계면 요소에 대한 탄소성 역학 모델의 강성행렬을 제시하였다. 개발된 유한요소는 2차원 조건에서 변위는 6절점, 수압과 온도는 4절점을 사용한다. 단층내 유체 주입에 대한 완전연계된 THM 해석은 단층내의 유효응력 감소와 주위 암반의 온도 수축에 의한 주입압의 복합적인 변화을 모델링 할수 있었다. 하지만, 열적 현상을 무시한 HM해석은 수리-역학적 변수를 과다하게 산정하였다.

• 한국복합재료학회:학술대회논문집
• /
• 한국복합재료학회 2005년도 춘계학술발표대회 논문집
• /
• pp.1-4
• /
• 2005

A higher order zig-zag shell theory is developed to refine accurately predict deformation and stress of smart shell structures under the mechanical, thermal, and electric loading. The displacement fields through the thickness are constructed by superimposing linear zig-zag field to the smooth globally cubic varying field. Smooth parabolic distribution through the thickness is assumed in the transverse deflection in order to consider transverse normal deformation. The mechanical, thermal, and electric loading is applied in the sinusoidal distribution function in the in-surface direction. Thermal and electric loading is given in the linear variation through the thickness. Especially, in electric loading case, voltage is only applied in piezo-layer. The layer-dependent degrees of freedom of displacement fields are expressed in terms of reference primary degrees of freedom by applying interface continuity conditions as well as bounding surface conditions of transverse shear stresses. In order to obtain accurate transverse shear and normal stresses, integration of equilibrium equation approach is used. The numerical examples of present theory demonstrate the accuracy and efficiency of the proposed theory. The present theory is suitable for the predictions of behaviors of thick smart composite shell under mechanical, thermal, and electric loadings combined.

• 한국환경과학회지
• /
• 제9권3호
• /
• pp.229-239
• /
• 2000

Spring, ground and thermal waters in the vicinity of Mt. Geumjeong and Mt. Baekyang area have been sampled and analyzed for major and minor elements. According to the Piper diagram, spring water belongs to $Ca-HCO_3$ and $Na-HCO_3$ types, groundwater to $Ca-HCO_3$ type, and thermal water to Na-Cl type. Based on the phase stability diagrams of $[Ca^{2+}]/{[H^+]}^2, [Mg^{2+}]/{[H^+]}^2, [K^+]/[H^+]$, and $[Na^+]/[H^+] vs. [H_4SiO_4]$, spring water, groundwater and thermal water are mostly in equilibrium with kaolinite. The result of factor analysis shows three factors (factor 1, 2 and factor 3) for the spring water, the groundwater and the thermal water which are represented by the influence of the dissolution of feldspar, calcite, anthropogenic sources (domestic and industrial wastes) and salt water.

• 항공우주기술
• /
• 제8권2호
• /
• pp.113-121
• /
• 2009

발사환경 시 작용하는 진동 환경을 지상에서 구현하기 위해 가진 시스템을 이용하고 있다. 진동시험은 수직, 수평 방향에 대해 수행되며, 수평방향 시험의 경우 슬립테이블 시스템과 연계하여 시험을 수행하게 된다. 최근 개발 중인 대형 위성의 경우, 위성과 진동 시험기 사이의 연결 구조물의 하중 및 동적 설계 요구 조건을 만족하기 위하여 수평가진 시스템과 열 특성이 매우 다른 스틸 소재를 이용하여 제작하였다. 본 연구에서는 수평가진 시스템과 열팽창 계수가 다른 소재를 이용하는 대형 구조물의 열 특성 및 모멘트 검증 과정과 발생한 문제점을 개선하고자 적용한 안을 제시하고자 한다.

• 한국연소학회:학술대회논문집
• /
• 한국연소학회 2014년도 제49회 KOSCO SYMPOSIUM 초록집
• /
• pp.135-137
• /
• 2014

Excess enthalpy flame propagating an porous inert medium, which recirculate exhaust heat to the upstream cold mixture, is theoretically analyzed. Using the activation-energy asymptotics, the flame structure is divided into the thin reaction and the gas-phase preheat zone, as is traditionally done. Ahead and behind of the two, there exist an outer preheat zone, where heat is convectively transferred from solid to gas, and a downstream re-equilibrium zone, where thermal equilibrium between phases is established. Asymptotic solutions of species and energy equations in each zone are obtained and then matched to each other, and finally the mass burning rate is obtained as a function of the flame propagation velocity with respect to the solid phase and physical properties of gas and solid.

• Structural Engineering and Mechanics
• /
• 제56권1호
• /
• pp.85-106
• /
• 2015

Postbuckling of thick plates made of functionally graded material (FGM) subjected to in-plane compressive, thermal and thermomechanical loads is investigated in this work. It is assumed that the plate is in contact with a Pasternak-type elastic foundation during deformation. Thermomechanical non-homogeneous properties are considered to be temperature independent, and graded smoothly by the distribution of power law across the thickness in the thickness in terms of the volume fractions of constituents. By employing the higher order shear deformation plate theory together the non-linear von-Karman strain-displacement relations, the equilibrium and compatibility equations of imperfect FGM plates are derived. The Galerkin technique is used to determine the buckling loads and postbuckling equilibrium paths for simply supported plates. Numerical examples are presented to show the influences of power law index, foundation stiffness and imperfection on the buckling and postbuckling loading capacity of the plates.

• 한국전산유체공학회:학술대회논문집
• /
• 한국전산유체공학회 2006년도 추계 학술대회논문집
• /
• pp.13-17
• /
• 2006

RoeM and AUSMPW+ schemes are two of the most accurate and efficient schemes which are recently developed for the analysis of single phase gas dynamics. In this paper, we developed two-phase versions of these schemes for the analysis of gas-liquid large density ratio two-phase flow. We adopt homogeneous equilibrium model (HEM) using mass fraction to describe different two phases. In the Eulerian-Eulerian framework, HEM assumes dynamic and thermal equilibrium of the two phases in the same computational mesh. From the mixture equation of state (EOS), we derived new shock-discontinuity sensing term (SDST), which is commonly used in RoeM and AUSMPW+ for the stable numerical flux calculation. The proposed two-phase versions of RoeM and AUSMPW+ schemes are applied on several air-water two-phase test problems. In spite of the large discrepancy of material properties such as density, enthalpy, and speed of sound, the numerical results show that both schemes provide very satisfactory solutions.

• 한국전산유체공학회지
• /
• 제18권3호
• /
• pp.87-93
• /
• 2013

A computational study has been performed to examine the effects of catalytic walls on the stagnation region heat transfer. The boundary conditions for none, finite, and fully catalytic walls have been incorporated into a multi-block compressible Navier-Stokes solver. In the present study, both chemical and thermal non-equilibrium effects were included. The flows over a blunt body model were simulated by varying surface catalytic recombination rates. A full range of catalycities was explored in the context of a constant wall temperature assumption. Detailed information on species concentrations, temperature, and surface heat flux are presented. Comparison with available flight data of surface heat flux is also made.