• Title/Summary/Keyword: Thermal Cracking

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Analysis of Catalytic Cracking and Steam Reforming Technologies for Improving Endothermic Reaction Performance of Hydrocarbon Aviation Fuels (탄화수소 항공유의 흡열반응 성능향상을 위한 촉매 분해 및 수증기 개질 기술분석)

  • Lee, Hyung Ju
    • Journal of the Korean Society of Propulsion Engineers
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    • v.25 no.2
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    • pp.98-109
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    • 2021
  • Fundamental parameters describing overall operational characteristics of active cooling systems of a hypersonic flight vehicle are mainly classified into endothermic hydrocarbon fuels, regenerative cooling channels, and materials and system structures. Of primary importance is the improvement of endothermic performance of hydrocarbon aviation fuels in a series of studies developing efficient regenerative cooling systems. In a previous study, therefore, an extensive technical analysis has been carried out on thermal decomposition characteristics of liquid hydrocarbon fuels. As a subsequent study, catalytic cracking and steam reforming technologies have been reviewed to find a way for the improvement of endothermic reaction performance of hydrocarbon aviation fuels.

Corrosion characteristics in stress and various environments with Sn addition to Cu pipe (구리 배관의 Sn 첨가에 따른 응력 및 다양한 환경에서의 부식 특성)

  • Serim Kim;Uijun Kim;Myeonghoon Lee;Seunghyo Lee
    • Journal of the Korean institute of surface engineering
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    • v.57 no.3
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    • pp.192-200
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    • 2024
  • Cu as a heat exchanger tube is an important component in thermal fluid transfer. However, Cu tubes are exposed to stress in certain environments, leading to stress corrosion cracking (SCC). In this study, the effect of Sn addition on microstructure and corrosion characteristics was examined. The microstructural examination revealed the presence of columnar crystal and a grain refinement due to the addition of Sn. Electrochemical measurements showed that the 5 wt.% NH3 environment was the most vulnerable environment to Cu corrosion, and the corrosion current density increased as stress increased. The immersion test exhibited the formation of Cu2O and Cu(OH)2 corrosion product in 3.5 wt.% NaCl and 5 wt.% NH3 environments, respectively. Results indicated that Sn addition to Cu was an important factor in improving the mechanical strength.

Estimation of Critical Degree of Hydration and Thermal Expansion Coefficient of Early-Age Concrete from Measured Temperature, Strain and Stress (온도, 변형 및 응력 계측을 통한 초기재령 콘크리트의 임계수화도 및 열팽창계수 추정)

  • 오병환;최성철;신준호
    • Proceedings of the Korea Concrete Institute Conference
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    • 2002.10a
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    • pp.809-814
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    • 2002
  • Recently, the properties of early-age concrete are increasingly important because these properties directly influence the behavior of early-age concrete structures including stress and cracking behavior. Nevertheless, the studies on early-age concrete are limited to strength and temperature development. The purpose of present study is to propose a simple and rational method which can predict the stress and strain behavior of young age concrete. A series of test have been done to measure the temperature development, strains and stresses in concrete members. The concept of equivalent age was used to define the degree of hydration and this degree of hydration was used to calculate the strength and elastic modulus. The critical degree of hydration and thermal expansion coefficient were calculated using experimental data. It is seen that the critical degree of hydration range from 0.05 to 0.11 based on the measuring method. The thermal expansion coefficient was calculated based on the measured non-mechanical strain and it is found that the coefficient decreases slightly with the increase of age. The consideration of critical degree of hydration in calculating stresses gives more accurate results. The present study provides useful method and data in evaluating early-age behavior of concrete structure.

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Small Punch Test for the Evaluation of Thermal Aging Embrittlement of CF8 Duplex Stainless Steel

  • Cheon, Jin-Sik;Kim, In-Sup;Jang, Jae-Gyoo;Kim, Joon-Gu
    • Proceedings of the Korean Nuclear Society Conference
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    • 1996.05c
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    • pp.79-84
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    • 1996
  • Small punch test was performed on CF8 duplex stainless steel aged at 370 and 400$^{\circ}C$ up to 5,000 h to evaluate the degree of the thermal aging embrittlement. At room temperature, the SP load-displacement curve was in a similar shape to those of ferritic steels and had a good reproducibility in spite of two-phase structure. The aging heat treatment resulted in a slight increase of the yield strength. As test temperature was lowered, the SP load showed a sudden drop followed by serrations before the SP specimen was fractured, resulting from the cracking of ferrite phase. The extent of thermal embrittlement was assessed in terms of the SP energy. Aging treatment at higher temperature led to a larger shift in the transition temperature and the corresponding change in the fracture mode. The main cause of the degradation was the embrittlement of ferrite phase. Additionally the phase boundary separation profoundly contributed to the degradation of the specimen aged at 400$^{\circ}C$.

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An Experimental Study on Hydration Heat Control in The Mass Concrete Using Oscillating Capillary Tube Heat Pipe (진동세관형 히트파이프(OCHP)를 이용한 매스콘크리트의 수화열 제어에 관한 실험적 연구)

  • Beak, Dong-Il;Kim, Myung-Sik;Lee, Moon-Sik;Kim, Kang-Min;Yum, Chi-Sun
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.05b
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    • pp.409-412
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    • 2006
  • In process of reinforced concrete(RC) box structure, the heat of hydration may cause serious thermal cracking problems. In order to eliminate hydration heat of mass concrete, this paper reports results of hydration heat control in mass concrete using the OCHP(Oscillating Capillary tube Heat Pipe). Recently OCHP is drawn special attention from these points of low cost as well as short construction schedule for the manufacturing of heat exchanger, flexibility, simplification and high performance. There were three RC box molds$(1.2{\times}1.2{\times}1.2m)$ which shows a difference as compared with each other. One was not equipped with OCHP. While others were equipped with OCHP and these were cooled with air natural convection and spraying water respectively. The OCHP was composed of copper pipe with 12 turns(O.D : 4mm, I.D : 2.8mm). The working fluid was R-22 and its charging ratio was 30(Vol. %). In order to analyze the distribution of temperature and index figure of thermal crack in sequential placement of mass concrete, we used HYCON of computer program. As a result of the experiment, the peak temperature decreased about $15.6\sim23.4^{\circ}C$ than the general specimen and the probability of thermal crack generated in mass concrete decreased up to 0%.

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An Experimental Study on Cooling of Hydration Heat of Mass Concrete Structure using Pulsating Heat Pipe in Summer Season (진동형 히트 파이프를 이용한 하계 매스 콘크리트의 수화열 냉각에 관한 실험적 고찰)

  • Yang, Tae-Jin;Kim, Jeong-Hoon;Kim, Jong-Soo
    • Journal of Advanced Marine Engineering and Technology
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    • v.31 no.1
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    • pp.51-57
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    • 2007
  • In process of reinforced concrete (RC) box structure. the heat of hydration may cause serious thermal cracking. In order to eliminate hydration heat of mass concrete. this paper reports results of hydration heat control in mass concrete structure using the pulsating heat pipe. There were three RC box molds($1.2{\times}l.8{\times}2.4m^3$) which shows a difference as compared with each other. One was not equipped with pulsating heat pipe. The others were equipped with pulsating heat pipe. All of them were cooled with natural air convection. The pulsating heat pipe was composed of serpentine type copper pipe with 10 turns (outer diameter: 4mm. inner diameter: 2.8mm). The working fluid was R-22 and its charging ratio was 40% by volume. The conditions such as the number of turns. the length and the pitch of the pulsating heat pipe and the size of concrete structure were changed. Based on these experiments, it was confirmed that this construction method using pulsating heat pipe was effective to remove hydration heat of mass concrete structure and thus it was possible to prevent harmful thermal crack and construction Period and costs of concrete structure would be cut down.

Catalysis of carbon black for hydrogen production by butane decomposition reaction (부탄의 직접분해로부터 수소 생산을 위한 카본블랙의 촉매적 작용)

  • Yoon, Suk-Hoon;Han, Gi-Bo;Park, No-Kuk;Ryu, Si-Ok;Yoon, Ki-June;Han, Gui-Young;Lee, Tae-Jin
    • New & Renewable Energy
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    • v.2 no.4 s.8
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    • pp.70-77
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    • 2006
  • The butane decomposition over the catalyst is an attractive method for the hydrogen production. The objective of the work was investigated the catalysis of carbon black in butane decomposition reaction. The Butane decomposition was performed over carbon black catalyst in a range of $500-1100^{\circ}C$. The butane conversion of thermal decomposition and catalytic decomposition were increased with increasing the reaction temperature The butane conversion of the thermal decomposition was higher than the butane conversion of the catalytic decomposition. Hydrogen and methane were mostly observed in the butane decomposition over $1000^{\circ}C$. Especially, the hydrogen yield was steadily increased with raising the reaction temperature, It could be known that the hydrogen yield of the catalytic decomposition was higher than one of the thermal cracking because the hydrogen productivity was improved by the catalyst. The deactivation of the catalyst was not observed in the reactivity test. The surface and crystalline of the fresh and used catalysts were characterized by TEM, BET surface area and XRD analysis, respectively. The fresh carbon black particles had mostly smoothly round-shaped surfaces. In the surface of the carbon black after the reaction, the deposited carbon was formed as the protrusion-shaped carbon and the cone-shaped. The proper peaks of carbon black appeared in XRD analysis.

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Comparison of Degradation Behaviors for Titanium-based Hard Coatings by Pulsed Laser Thermal Shock

  • Jeon, Seol;Lee, Heesoo
    • Journal of the Korean Ceramic Society
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    • v.50 no.6
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    • pp.523-527
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    • 2013
  • Ti-based coatings following laser ablation were studied to compare degradation behaviors by thermomechanical stress. TiN, TiCN, and TiAlN coatings were degraded by a Nd:YAG pulsed laser with an increase in the laser pulses. A decrease in the hardness was identified as the pulses increased, and the hardness levels were in the order of TiAlN > TiCN > TiN. The TiN showed cracks on the surface, and cracks with pores formed along the cracks were observed in the TiCN. The dominant degradation behavior of the TiAlN was surface pore formation. EDS results revealed that diffusion of substrate atoms to the coating surface occurred in the TiN. Delamination occurred in the TiN and TiCN, while the TiAlN which has higher thermal stability than the TiN and TiCN maintained adhesion to the substrate. It was considered that the decrease in the hardness of the Ti-based hard coatings is attributed to surface cracking and the diffusion of substrate atoms.

Fabrication and Thermal Properties of Fumed Silica/Ceramic Wool Inorganic Composites (Fumed Silica/Ceramic Wool 무기복합재의 제조 및 열적 성질)

  • Ahn, WonSool
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.15 no.6
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    • pp.4007-4012
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    • 2014
  • This study examined the fabrication and thermal properties of fumed silica/ceramic wool inorganic composites. A predetermined quantity of fumed silica and ceramic wool was mixed uniformly into a slurry state and stabilized in the mold at room temperature, and converted to a massive foamed body through a complete drying process at $150^{\circ}C$. Although the samples without polyvinyl alcohol (PVA) as an interfacial adhesive showed a bulk density of 0.6-0.8 $g/cm^3$ in the range, 10-70wt% fumed silica, those samples with 3wt% PVA exhibited remarkably lower bulk densities with enhanced mechanical and thermal insulation properties, without thermal cracking even above $800^{\circ}C$. The K-factor of the samples was lower in proportion to the fumed silica contents, showing good thermal insulation properties of ca. 0.08 $W/m^{\circ}K$ at $500^{\circ}C$ for the sample with 30wt% fumed silica.

Thermal Durability of 4YSZ Thermal Barrier Coating Deposited by Electron Beam PVD (전자빔을 이용한 물리기상증착법으로 제조된 열차폐용 4 mol% YSZ 코팅의 내열특성)

  • Park, Chanyoung;Yang, Younghwan;Kim, Seongwon;Lee, Sungmin;Kim, Hyungtae;Lim, Daesoon;Jang, Byungkoog;Oh, Yoonsuk
    • Journal of Powder Materials
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    • v.20 no.6
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    • pp.460-466
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    • 2013
  • 4 mol% Yttria-stabilized zirconia (4YSZ) coatings with $200{\mu}m$ thick are fabricated by Electron Beam Physical Vapor Deposition (EB-PVD) for thermal barrier coating (TBC). $150{\mu}m$ of NiCrAlY based bond coat is prepared by conventional APS (Air Plasma Spray) method on the NiCrCoAl alloy substrate before deposition of top coating. 4 mol% YSZ top coating shows typical tetragonal phase and columnar structure due to vapor phase deposition process. The adhesion strength of coating is measured about 40 MPa. There is no delamination or cracking of coatings after thermal cyclic fatigue and shock test at $850^{\circ}C$.