• Proceedings of the Korean Institute of Building Construction Conference
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• 2002.05a
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• pp.91-96
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• 2002

This study is to investigate the insulation performance of lightweight concrete using recycled lightweight aggregate, to develop lightweight concrete products which have an excellence on the insulation performance are satisfied with properties of building materials. As a result of this study, recycled EPS aggregate is considered to have an independent pores which is closed by dense partitions. So, it is showed that the insulation performance of lightweight concrete using recycled EPS aggregate are excellent. Especially, in the case of lightweight concrete under conditions of replacement ratio over 100%, it is considered that insulation performance is very excellent as thermal conductivity is showed about 0.2kcal/mh$^{\circ}C$. According to considering the relation between ultrasonic pulse velocity, unit weight and thermal conductivity through the graph, the result of relation between ultrasonic pulse velocity, unit weight and thermal conductivity on the graph expressed their high interaction shown as direct proportion on the graph. So that it is possible to extract the insulation performance of lightweight concrete using recycled EPS aggregate by ultrasonic pulse velocity and unit weight.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2003.05a
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• pp.31-34
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• 2003

Sandwich panel is composed of the facing sheets which support the external load, the cellular core with the low thermal conductivity and the adhesive agent to bond them. The cellular core was produced by binding lightweight cellular aggregates with cement and two types of acrylic base St/BA emulsion were added with a view to improving the workability ion due to high absorption of light weight aggregate and to develope more strength, respectively. This investigation is to comprehend the effect of the addition of two types of St/BA on thermal conductivity, calorific value and exhaustion content of noxious gas in addition re compressive and flexural strength. Flexural strength of the specimen made with St/BA-2 ranged 20kgf/cm2 to 25kgf/cm2 and was about 50% to 100% as high as that of the non-fiber specimen. Thermal conductivity was recorded from 2.0 to 3.0 kcal/mh$^{\circ}C$ and calorific value of St/BA modified specimen was much lower than that of commercial sandwich panel core of EPS and urethane. Careful caution has to be taken because generation of noxious gas such as CO, NO and SO2 tend to increase with addition of polymer cement ratio.

• Transactions of the Korean hydrogen and new energy society
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• v.29 no.5
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• pp.458-465
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• 2018

This study reports the fabrication of anion exchange membranes (AEMs) containing two kinds of functional groups: i) trimethylphosphite (TMP) and ii) trimethylamine (TMA). We carried out the synthesis of polymers to enhance thermal stability and ion conductivity. The alternative polymer was prepared using 2,2-bis(4-hydroxy-3-methylphenyl)propane and decafluorobiphenyl. The membrane was fabricated by solution casting method. The thermal stability of membranes was examined by TGA. The physiochemical properties of membranes were also investigated in terms of water uptake, swelling ratio, ion exchange capacity, and ion conductivity. The hydroxide ion conductivity of the membranes reached about 20.2 mS/cm for quaternary ammonium poly(arylene ether) (QA-PAE) containing TMA moiety and 5.1 mS/cm for quaternary phosphonium PAE (QP-PAE) containing TMP moiety at $90^{\circ}C$.

• Journal of the Korean Geotechnical Society
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• v.27 no.11
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• pp.39-45
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• 2011

This study presents the thermal behaviors of glass beads-rubber mixtures depending on the volumetric fraction of each constituent and relative size between them. The transient plane source method is used to measure the effective thermal conductivity of mixtures. The discrete element method (DEM) and the thermal network model are integrated to investigate the particle-scale mechanism of heat transfer in granular packings. Results show that 1) the effective thermal conductivity decreases as the rubber fraction increases, and 2) the relative size between two solid particles dominates the spatial configuration of inter-particle contact condition that in tum determines the majority of heat propagation path through particle contacts. For the mixtures whose volumetric fraction of rubber is identical, the less conductive materials (e.g., rubber particles) with a large size facilitate heat transfer in granular materials. The experimental results and particle-scale observation highlight that the thermal conduction behavior is dominated not only by the volumetric fraction but also the spatial configuration of each constituent.

• Journal of Electrochemical Science and Technology
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• v.1 no.1
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• pp.57-62
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• 2010

The lithium ion concentration dependant ionic conductivity and thermal properties of poly(ethylene glycol) methyl ether methacrylate (PEGMA)/acrylonitrile-based copolymer electrolytes with $LiClO_4$ have been studied by differential scanning calorimetry (DSC), linear sweep voltammetry (LSV) and AC complex impedance measurements. In systems with 11 wt% of acrylonitrile all liquid electrolytes were obtained regardless of lithium ion concentration. Complex impedance measurements with stainless steel electrodes give ambient ionic conductivities $8.1\times10^{-6}\sim1.4\times10^{-4}S cm^{-1}$. On the other hand, a hard and soft films at ambient temperature were obtained in copolymer electrolyte system consists of 15 wt% acrylonitrile with 6 : 1 and 3 : 1 of [EO] : [Li] ratio, respectively. DSC measurements indicate the crystalline melting temperature of poly(PEGMA) disappeared completely after addition of $LiClO_4$ in this system due to the complex formation between ethylene oxide (EO) unit and lithium salt. As a result, free standing film with room temperature ionic conductivity of $1.7\times10^{-4}S cm^{-1}$ and high electrochemical stability up to 5.5V was obtained by controlling of acrylonitrile and lithium salt concentration.

• Proceedings of the KSME Conference
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• 2007.05b
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• pp.2297-2302
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• 2007

Numerical simulations are conducted to analyze conjugate heat transfer characteristics in a ribbed channel. In this simulation, the effects of Reynolds number and heat capacity of the solid channel wall on convective heat transfer are observed in the turbulent flow regime. In the case of the conducting wall against isothermal wall, the relative ratio of the thermal resistance between the solid wall and the flow field varies with Reynolds number. Thus the characteristics of the conjugate heat transfer are changed with the Reynolds number. Heat capacity ratio affects the temperature fluctuation inside solid wall. The temperature fluctuation inside the solid wall decreases with increasing the heat capacity of the solid wall so that the convective heat transfer increases. When the thermal conductivity ratio is smaller than 10, the effects of flow characteristics on heat transfer are changed.

• Journal of Energy Engineering
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• v.20 no.3
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• pp.209-215
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• 2011

In this study, for efficiency enhancement of low temperature heat exchanger, the thermal conductivity and the viscosity of carbon nanofluids and oxidized carbon nanofluids were measured at $10^{\circ}C$ and $25^{\circ}C$, respectively. Carbon nanofluids were made by ultrasonic-dispersing ones in distilled water after Multi-Walled Carbon Nanotubes (MWCNTs) mixed Sodium Dodecyl Sulfate (SDS, 100 wt%), Polyvinyl pyrrolidone (PVP, 300 wt%) each. Oxidized carbon nanofluids were made by ultrasonic-dispersing Oxidized Carbon Nanotubes (OMWCNTs) in distilled water. The thermal conductivity of carbon nanofluids was measured by using a transient hot-wire method. The viscosity was measured by using a digital viscometer. As a result, the thermal conductivity of oxidized carbon nanofluids was the highest of those compared and the other carbon nanofluids at the same mixture ratio and temperature, and the viscosity was measured the lowest of those compared and the other carbon nanofluids.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.12 no.7
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• pp.2931-2938
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• 2011

Effective thermal conductivity of three-phase composites, consisting of matrix and two kinds of spherical inclusions, has been derived as an explicit form by extending modified Eshelby model (MEM) for two-phase composites. The present results are compared with those by differential effective medium model (DEMM), which are also compared with the experimental results of two- and three-phase composites in the literatures to be validated. For two-phase composites, the results by MEM are better than those by DEMM for the inclusion volume fraction smaller than 0.5. Comparisons between the results by two models and experimental results have been made for three-phase composite, resulting in that MEM predicts better than DEMM for smaller volume fraction of the inclusion having larger inclusion-to-matrix thermal conductivity ratio, but DEMM predicts better as its volume fraction increases. It has been observed through parametric study that its volume fraction is the critical factor affecting the deviation of predictions by the two models. The results by them show a good agreement with the three-phase composite proposed by Molina et al..

• Korean Chemical Engineering Research
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• v.49 no.1
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• pp.120-127
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• 2011

For the development of the environment-friendly insulating composite materials, natural cellulose (wood chip and sawdust) was used as a core material and activated Hwangtoh was used as a binder. Various specimens were prepared with the water/binder ratio and natural cellulose/binder ratio. The physical properties of these specimens were then investigated through compressive and flexural strength test, absorption test, hot water resistance test, thermal conductivity, measurement of pore distribution and observation of micro-structures using scanning electron microscope (SEM). Results showed that the absorption ratio increased with the increase of natural cellulose/binder ratio but decreased remarkably with the increase of polymer/binder ratio. The compressive and flexural strength development varied appreciably with the increase of water/binder ratio and natural cellulose/binder ratio. On the other hand, thermal conductivity decreased with the increase of natural cellulose/binder ratio and polymer/binder ratio. Through SEM, it was found that activated Hwangtoh that reacted with water formed a hydrate crystal leading to the compact structure and the total pore volume of the specimen using activated Hwangtoh was smaller than that of the non-activated Hwangtoh.

• Journal of the Microelectronics and Packaging Society
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• v.6 no.4
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• pp.41-48
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• 1999

Silica is the most popular materials as a filler of EMC for microelectronic packaging. However, because of its low thermal conductivity, the use of silica is restricted to parts requiring high thermal dissipation. The superior fluidity of EMC can be achieved with a combination of filler size distribution. In this study, physical properties of EMC filled with the crystalline silica(13$\mu\textrm{m}$) which have high fluidity and low cost and the AlN(2 $\mu\textrm{m}$) which have high thermal conductivity and low coefficient of thermal expansion were evaluated by changing the AlN/silica ratios. As a result of the evaluation of physical properties of EMC, the optimum mixing ratio of AlN/crystalline silica was 0.3/0.7. In this condition, binary mixture(AlN/crystalline silica) filled EMC showed superior properties, i.e., in the thermal conductivity, CTE, dielectric constant, flexural strength, and thermal shock resistance without reduction of fluidity.