• Title/Summary/Keyword: Thermal Block

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Sequence Structure and Thermal Property of Poly(butylene terephthalate) (PBT)/p-Acetoxybenzoic Acid (ABA) Copolymers Obtained Through Melt Trans-esterification Reaction (용융 에스테르 교환반응에 의해 제조된 폴리부틸렌테레프탈레이트/파라아세톡시벤조산 공중합체의 서열구조와 열적 성질)

  • 김도경;박수영;박종래
    • Polymer(Korea)
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    • v.24 no.1
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    • pp.58-64
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    • 2000
  • Poly(butylene terephthalate-co-oxybenzoate) (PBOT ) was synthesized by melt trans-esterification of poly(butylene terephthalate)(PBT) and p-acetoxybensoic acid (ABA) at 250, 260, and 27$0^{\circ}C$ with the compositions of PBT/ABA of 4/6, 5/5, 6/4. The sequence analysis of PBOT with a $^1$H FT-NMR indicated that the number of consecutive oxybenzoate units ranges from 1.2 to 1.5, which is larger than that of the corresponding poly(ethylene terephthalate)(PET)/ABA (PEOT) obtained at the same reaction conditions as the PBOT. The difference in the block length influenced the thermal degradation behavior: Polyoxybezoate (POB), PBT and PEOT showed one-step degradation whereas PBOT exhibited two-step degradation. The results suggested that PBOT consisted of three phases of PBT-rich phase, random phase of PBT and ABA, and ABA-rich phase.

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An Evaluation of Indoor Thermal Environment for Zero-Carbon Green Home according to the Operation Conditions in Summer (제로카본 그린홈의 여름철 운영조건에 따른 실내 열환경 평가)

  • Yu, Jung yeon;Cho, Dong woo;Kim, Kee Han
    • Journal of the Korean Solar Energy Society
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    • v.40 no.2
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    • pp.25-36
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    • 2020
  • The Korean government has a plan to mandate zero-energy buildings in 2020 for public and 2025 for private buildings. In order to design a zero-energy building, insulation and airtightness, which are the most basic elements of passive house technology, are required, and the government has been accomplished this through step-by-step strengthening of related standards. In passive house with high thermal insulation and airtightness performance, the heat introduced into the building through solar radiation can be stored for a long time to keep the inside warm during winter. On the other hand, during summer, heat introduced into the building cannot be easily released to outside, so it is necessary to actively block solar radiation and high temperature outdoor air to prevent an increase of indoor temperature. Therefore, this study aims to derive an appropriate operation condition of passive house to maintain the indoor temperature at an suitable level according to the ventilation methods and solar shading conditions. As a result, under the conditions that the outdoor temperature was 28℃ or less, the ventilation using a heat recovery ventilation system at daytime and natural ventilation at nighttime were selected for the most appropriate operation method. In addition, in the case of solar shading, it was found that blocking solar radiation at daytime using the blind and open the blind at nighttime to ensure natural ventilation were selected for the most appropriate solar shading condition.

Synthesis and characterization of polymer electrolyte membrane for fuel cell including sulfonated bis (4-fluorophenyl) phenylphosphine oxide (술폰화된 비스(4-플루오로페닐) 페닐포스핀옥사이드를 포함한 연료전지용 고분자 전해질막의 합성과 특성분석)

  • Yoo, Eun Sil;Nahm, Kee Suk;Yoo, Dong Jin
    • Journal of Energy Engineering
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    • v.25 no.4
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    • pp.176-183
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    • 2016
  • This study relates to a polymer electrolyte membrane for improved performance fuel cell, were researched with respect to properties required for driving a fuel cell. The bis(4-fluorophenyl)phenyl phosphine oxide was sulfonated using fuming sulfuric acid. Synthetic hydrophilic oligomer and the hydrophobic oligomer and the block copolymers were prepared via aromatic nucleophilic substitution polycondensation. A block copolymer structure and degree of sulfonation was analyzed by $^1H$-NMR and gel permeation chromatography(GPC) analysis. Thermal stability was confirmed by thermogravimetric analysis(TGA), block copolymer was stable at high temperature(>$200^{\circ}C$), The ion conductivity was measured in order to demonstrate the performance of fuel cell. Synthesis membrane was the increase of temperature was improved conductivity up to 58 mS/cm due to the influence of the developed ion clusters. The phase separation of the polymer was observed to make AFM analysis.

Anhydrous Polymer Electrolyte Membranes Prepared From Polystyrene-b-Poly (hydroxyl ethyl methacrylate) Block Copolymer (Polystyrene-b-Poly(hydroxyl ethyl methacrylate) 블록 공중합체를 이용한 무가습 고분자 전해질막)

  • Kim, Jong-Hak;Seo, Jin-Ah;Lee, Do-Kyung;Roh, Dong-Kyu;Shul, Yong-Gun
    • Membrane Journal
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    • v.19 no.4
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    • pp.302-309
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    • 2009
  • A block copolymer of polystyrene-b-poly (hydroxyl ethyl methacrylate), PS-b-PHEMA, was synthesized via atom transfer radical polymerization (ATRP) and crosslinked with 4,5-imidazole dicarboxylic acid (IDA) via esterification of the -OH groups of PHEMA in the block copolymer and the -COOH groups of IDA. Upon doping with $H_3PO_4$ to form imidazole-$H_3PO_4$ complexes, the proton conductivity of the membranes continuously increased as the content of $H_3PO_4$ increased. In addition, both the tensile strength and the elongation at break increased with IDA content. A proton conductivity of 0.01 S/cm at $100^{\circ}C$ was obtained for the PS-b-PHEMA/IDA/$H_3PO_4$ membrane with [HEMA]:[IDA]:[$H_3PO_4$] = 3:4:4 under anhydrous conditions. All of the PS-b-PHEMA/IDA/$H_3PO_4$ membranes were thermally stable up to $350^{\circ}C$, as revealed by thermal gravimetric analysis (TGA).

The Persistent Paresthesia Care on Left Lingual & Buccal Shelf Regions after the Lingual & Long Buccal Nerve Block Anesthesia -A Case Report- (설신경과 장협신경 전달마취 시행 후 발생된 설부와 협선반부의 장기간 이상감각증 관리 -증례보고-)

  • Kim, Ha-Rang;Yoo, Jae-Ha;Choi, Byung-Ho;Mo, Dong-Yub;Lee, Chun-Ui;Kim, Jong-Bae
    • Journal of The Korean Dental Society of Anesthesiology
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    • v.9 no.2
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    • pp.108-115
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    • 2009
  • Trauma to any nerve may lead to persistent paresthesia. Trauma to the nerve sheath can be produced by the needle. The patient frequently reports the sensation of an electric shock throughout the distribution of the nerve involved. It is difficult for the type of needle used in dental practice to actually sever a nerve trunk or even its fibers. Trauma to the nerve produced by contact with the needle is all that is needed to produce paresthesia. Hemorrhage into or around the neural sheath is another cause. Bleeding increases pressure on the nerve, leading to paresthesia. Injection of local anesthetic solutions contaminated by alcohol or sterilizing solution near a nerve produces irritation; the resulting edema increases pressure in the region of the nerve, leading to paresthesia. Persistent paresthesia can lead to injury to adjacent tissues. Biting or thermal or chemical insult can occur without a patient's awareness, until the process has progressed to a serious degree. Most paresthesias resolve in approximately 8 weeks without treatment. In most situations paresthesia is only minimal, with the patient retaining most sensory function to the affected area. In these cases there is only a very slight possibility of self injury. But, the patient complaints the discomfort symptoms of paresthesia, such as causalgia, neuralgiaform pain and anesthesia dolorosa. Most paresthesias involve the lingual nerve, with the inferior alveolar nerve a close second. This is the report of a case, that had the persistent paresthesia care on left lingual & buccal shelf regions after the lingual and long buccal nerve block anesthesia.

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Design of a CCM/DCM dual mode DC-DC Buck Converter with Capacitor Multiplier (커패시터 멀티플라이어를 갖는 CCM/DCM 이중모드 DC-DC 벅 컨버터의 설계)

  • Choi, Jin-Woong;Song, Han-Jung
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.17 no.9
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    • pp.21-26
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    • 2016
  • This paper presents a step-down DC-DC buck converter with a CCM/DCM dual-mode function for the internal power stage of portable electronic device. The proposed converter that is operated with a high frequency of 1 MHz consists of a power stage and a control block. The power stage has a power MOS transistor, inductor, capacitor, and feedback resistors for the control loop. The control part has a pulse width modulation (PWM) block, error amplifier, ramp generator, and oscillator. In this paper, an external capacitor for compensation has been replaced with a multiplier equivalent CMOS circuit for area reduction of integrated circuits. In addition, the circuit includes protection block, such as over voltage protection (OVP), under voltage lock out (UVLO), and thermal shutdown (TSD) block. The proposed circuit was designed and verified using a $0.18{\mu}m$ CMOS process parameter by Cadence Spectra circuit design program. The SPICE simulation results showed a peak efficiency of 94.8 %, a ripple voltage of 3.29 mV ripple, and a 1.8 V output voltage with supply voltages ranging from 2.7 to 3.3 V.

Synthesis and Properties of Nylon 6/PEG Random Block Copolymer/Clay Nanocomposite via in situ Polymerization (in situ중합을 통한 나일론 6-PEG 랜덤공중합체/점토 나노복합체의 합성 및 물성)

  • Angelica S. Lopez;Pio Sifuentes;Kim, Kap-Jin
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.04a
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    • pp.72-74
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    • 2003
  • There has been extensive interest in the development of new nanocomposites. One kind of these systems is the hybrid based on organic polymers and inorganic minerals consisting of layered silicates. Some properties like stiffness, strength, barrier properties, thermal, and oxidative stability can be improved by the presence of the filler in the polymeric matrix[1]. It is reported that, in the nylon 6/clay nanocomposites, the modulus is increased, but impact strength and elongation at break are drastically decreased. (omitted)

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Design and Research on High-Reliability HPEBB Used in Cascaded DSTATCOM

  • Yang, Kun;Wang, Yue;Chen, Guozhu
    • Journal of Power Electronics
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    • v.15 no.3
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    • pp.830-840
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    • 2015
  • The H-bridge inverter is the fundamental power cell of the cascaded distribution static synchronous compensator (DSTATCOM). Thus, cell reliability is important to the compensation performance and stability of the overall system. The concept of the power electronics building block (PEBB) is an ideal solution for the power cell design. In this paper, an H-bridge inverter-based “plug and play” HPEBB is introduced into the main circuit and the controller to improve the compensation performance and reliability of the device. The section that discusses the main circuit primarily emphasizes the design of electrical parameters, physical structure, and thermal dissipation. The section that presents the controller part focuses on the principle of complex programmable logic device -based universal controller This section also analyzes typical reliability and anti-interference issues. The function and reliability of HPEBB are verified by experiments that are conducted on an HPEBB test-bed and on a 10 kV/± 10 Mvar DSTATCOM industrial prototype.

A New Probabilistic Generation Simulation Considering Hydro, Pumped-Storage Plants and Multi-Model (수력,양수 및 다중모델을 고려한 새로운 확률론적 발전시뮬레이션)

  • 송길영;최재석
    • The Transactions of the Korean Institute of Electrical Engineers
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    • v.40 no.6
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    • pp.551-561
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    • 1991
  • The probabilistic generation simulation plays a key role in power system expansion and operational planning especially for the calculation of expected energy, loss of load probaility and unserved energy expected. However, it is crucial to develop a probabilistic generation simulation algorithm which gives sufficiently precise results within a reasonable computation time. In a previous paper, we have proposed an efficent method using Fast Hartley Transform in convolution process for considering the thermal and nuclear units. In this paper, a method considering the scheduling of pumped-storage plants and hydro plants with energy constraint is proposed. The method also adopts FHT techniques. We improve the model to include multi-state and multi-block generation. The method has been applied for a real size model system.

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Computation of Thermal Flow for Automotive Lamp by Using Geometric Octree Method (기하학적 Octree 격자생성법을 이용한 자동차 헤드램프 내부의 열유동 계산)

  • Sah Jong-Youb;Park Jong-Ryul;Kang Dong-Min
    • 한국전산유체공학회:학술대회논문집
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    • 2001.10a
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    • pp.152-156
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    • 2001
  • Three dimensional orthogonal grid generation is able to control effectively the grid spacing near the boundaries, but there are some difficulty to meshing complex geometry. The mesh complex geometry by orthogonal grid generation method must divide block of geometry It is required a careful skill, and long time. Its also difficulty to make unstructured mesh on complex geometry. Particularly, three dimensional geometry must have more time and effort. Recently, there have been growing interests in mesh generation of complex grometry, aslike an automobile headlamp, the heart. The method of easily meshing complex geometry is resarched to solve them. We suggest octree grid into one among these methods. As octrce grid is automaticaly adapted at the boundaries by determine the level operations to control the grid spacing near the boundaries are unnecessary. In this paper we showed throe dimensional mesh generation, and heat-flow analysis on the octree mesh.

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