• Proceedings of the Korean Society For Composite Materials Conference
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• 2000.11a
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• pp.34-37
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• 2000

The effect of novel N-crotyl-N,N-dimethyl-4-methylanilinium hexafluroantimonate (CMH) curing agent on cure behavior and thermal properties of DGEBA epoxy cationic system was investigated. From DSC measurements of DGEBA/CMH system, it was shown that this system exhibits an excellent thermal latent characteristic in a given temperature and reveals complex cure behavior as indicated by multiple exotherms. The conversion and conversion rate of DGEBA/CMH system increased with increasing the concentration of initiator due to high activity of CMH. Viscoelastic properties during gel formation of DGEBA with CMH were investigated by rheological techniques under isothermal condition. The gel time obtained from the modulus crossover. point t(G')=G", was affected by high curing temperature and concentration of CMH, resulting in high degree of network formation in cationic polymerization. The thermal stabilities were discussed in terms of the activation energy for decomposition and thermal factors determined from TGA measurements.ents.

• Journal of the Korean Ceramic Society
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• v.48 no.6
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• pp.617-620
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• 2011

Thermal shock behavior of porous ceramic nozzles with various pore sizes for continuous casting process of steel was investigated in terms of physical properties and microstucture. Porous nozzle samples with a composition of $Al_2O_3$-$SiO_2$-$ZrO_2$ were fabricatedby adding various sizes of graphite as the pore forming agent. As the graphite size increased from 45~75 to 150~180 ${\mu}m$, both the resulting pore size and the flexural strength also increased. A thermal shock test was carried out at temperatures (${\Delta}$T) of 600, 700, 800, and 900$^{\circ}C$. Microstructure analysis revealed a small number of cracks on the sample with the largest mean pore size of 22.32 ${\mu}m$. In addition, increasing the pore size led to a smaller decrease in both pressure drop and elastic modulus. In conclusion, controlling the pore size can enhance thermal shock behavior.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.30 no.12 s.255
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• pp.1543-1550
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• 2006

Since the performance of joints usually determines the structural efficiency of composite structures, an extensive knowledge of the behavior of adhesive joints and the related effect on joint strength is essential for design purposes. In this study, the torque capacity of adhesive joints was predicted using the combined thermal and mechanical analyses when the adherend was a composite tube. A finite element analysis was performed to evaluate residual thermal stresses developed in the joint, and mechanical s stresses in the adhesive were calculated including both the nonlinear adhesive behavior and the behavior of composite tubes. Three different joint failure modes were considered to predict joint failure: interfacial failure, adhesive bulk failure, and adherend failure. The influence of the composite adherend stacking angle on the residual thermal stresses was investigated, and how the residual thermal stresses affect the joint strength was also discussed. Finally, the predicted results were compared with experimental results available in literature.

• Journal of the Korean Ceramic Society
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• v.55 no.6
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• pp.608-617
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• 2018

The effects of the purity and monoclinic phase of feedstock powder on the thermal durability of thermal barrier coatings (TBC) were investigated through cyclic thermal exposure. Bond and top coats were deposited by high velocity oxygen fuel method using Ni-Co based feedstock powder and air plasma spray method using three kinds of yttria-stabilized zirconia with different purity and monoclinic phase content, respectively. Furnace cyclic thermal fatigue test was performed to investigate the thermal fatigue behavior and thermal durability of TBCs. TBCs with high purity powder showed better sintering resistance and less thickness in the thermally grown oxide layer. The thermal durability was found to strongly depend on the content of monoclinic phase and the porosity in the top coat; the best thermal fatigue behavior and thermal durability were in the TBC prepared with high purity powder without monoclinic phase.

• Macromolecular Research
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• v.17 no.10
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• pp.785-790
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• 2009

In this paper, the relaxation behavior of the regenerated silk fibroin (SF) films was investigated using dielectric thermal analysis (DETA), and compared with the dynamic mechanical behavior obtained from dynamic mechanical thermal analysis (DMTA), in order to gain a better understanding of the characteristics of dielectric behavior of SF film and identify the differences between the two analyses. Compared to DMTA, DETA exhibited a higher sensitivity on the molecular relaxation behaviors at low temperature ranges that showed a high $\gamma$-relaxation peak intensity without noise. However, it was not effective to examine the relaxation behaviors at high temperatures such as $\alpha-$ and ${\alpha}_c$-relaxations that showed a shoulder peak shape. On the contrary, DMTA provided more information regarding the relaxation behaviors at high temperatures, by exhibiting the changes in width, intensity and temperature shift of the $\alpha$-relaxation peak according to various crystallinities. Conclusively, DETA and DMTA can be utilized in a complementary manner to study the relaxation behavior of SF over a wide temperature range, due to the different sensitivity of each technique at different temperatures.

• Structural Monitoring and Maintenance
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• v.2 no.2
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• pp.95-113
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• 2015

The knowledge of the behavior of any roller compacted concrete (RCC) dam and its foundation is gained by studying the service action of the dam and its foundation using measurements of an external and internal nature. The information by which a continuing assurance of structural safety of the RCC dam can be gauged is of primary importance. Similarly, the fact that the information on structural and thermal behavior and the properties of concrete that may be used to give added criteria for use in the design of future RCC dams is of secondary importance. Wide spread attention is now being given to the installation of more expensive instrumentation for studying the behavior of concrete dams and reservoirs and forecasting of any adverse trends. In view of this, the paper traces installation and need of the comprehensive instrumentation scheme implemented to monitor the structural and thermal behavior of 102.4 m high RCC dam constructed near Mumbai in India. An attempt is made in the present paper to emphasize the need to undertake an instrumentation program and evaluate their performance during construction and post construction stage of RCC structures. Few typical results, regarding the thermal and structural behavior of the dam, obtained through instrumentation installed at the dam site are presented and compared with the design considerations. The fair agreement is seen in the response observed through instrumentation with that governing the design criteria.

• Journal of the Korea Convergence Society
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• v.9 no.1
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• pp.283-289
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• 2018

In automotive disc brake systems, frictional heat is not uniformly dispersed for reasons such as heat flux and thermal deformation. The thermoelastic deformation due to the frictional heat affects the contact pressure distribution and the contact load may be concentrated on the contact portion on the the disc brake surface, resulting in thermoelastic instability. In this study, thermal analysis and thermal deformation analysis considering the contact between disk and pad occurred during braking through 3D axial symmetry model with reference to the experimental equation and Kao's analysis method of contact pressure of disk and pad. ANSYS is used to analyze the thermal and elastic instability problems occurring at the contact surface between the disk and the pad, considering both the thermal and mechanical loads. A 3D axisymmetric model with direct contact between the disk and the pad was constructed to more accurately observe the thermal behavior of the disk by observing the frictional surface temperature, thermal deformation and contact thermal stress of the disk.

• Journal of the Korean Ceramic Society
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• v.56 no.2
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• pp.184-190
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• 2019

To improve resistance in thermal shock of zirconia setter which is frequently and repeatedly exposed to high temperature, high degree of porosity and control of thermal expansion are needed for which the fused CSZ (CaO stabilized zirconia) is used to produce the zirconia setter. In the present study, the effects of sintering temperature, cool down condition, addition of CaO stabilizer, and addition of other additives on phase transition and thermal expansion behavior of the fabrication process of zirconia setter, were examined. The zirconia setter, fabricated with fused CSZ at 1550℃, exhibited 20.4 MPa of flexural strength, 6.8% of absorbance, and 27.9% of apparent porosity. The rapid change in thermal expansion of zirconia setter is observed at temperature around 800℃, and it was reduced by low firing temperature, slowed cooled down, and addition of CaO.

• Proceedings of the Korean Powder Metallurgy Institute Conference
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• 2006.09a
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• pp.219-220
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• 2006

To understand the effect of powder characteristics on the thermal debinding behavior, PIM parts produced with powders with different particle sizes and particle shapes were examined to determine their weight losses during thermal debinding. The results show that the average diameter of the pore channel in the compact increased when the temperature increased and when coarse powders were used. However, the weight loss rates did not increase proportionally with the pore size. This suggests that the different powders that are frequently used in PIM parts do not affect the thermal debinding rate significantly. This is because the pore size is much larger than the mean free path of the decomposed gas molecules. Thus, the diffusion rates of the gases are not rate-controlling in thermal debinding. The controlling mechanism of the thermal debinding rate is the decomposition of the backbone binder in the PIM parts.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2000.04a
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• pp.6-6
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• 2000

On-orbit thermal behavior of KOMPSAT (Korea Multi-purpose Satellite) propulsion system employing hydrazine (N$_2$H$_4$) liquid monopropellant is addressed. Thermal control performance to prevent propellant freezing in spacecraft-operational orbit was verified by flight telemetry data obtained during LEOP (Launch and Early Operation Phase). Results are depicted in terms of temperature history during several orbits selected and are compared with acceptable temperature ranges of system components. Cyclic behavior of temperature is reduced into duty cycles of the avionics heaters and subsequently converted into the electrical power required to keep away from propellant freezing. Temperature of each component which was achieved under on-ground thermal-balanced condition of spacecraft, is presented for comparison with the flight data, additionally.