• Title/Summary/Keyword: Theoretical potential

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Theoretical and Simulation Study of Thermo-Osmosis of Liquid in Microchannel (마이크로 채널 내 액체에서의 열삼투현상에 대한 이론 및 시뮬레이션 연구)

  • Han, Min-Sub
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.29 no.1 s.232
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    • pp.131-138
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    • 2005
  • Thermo-osmosis of liquids in a microscale channel is investigated by theoretical and simulation study. From the basic set of conservation equations, the temperature and velocity distributions are derived in the function of the given temperatures and pressure gradient. The pressure gradient for a given temperature gradient is then obtained by the molecular simulation. It is shown that the temperature gradient tangential to the surface induces the pressure gradient and thus the flow in the interfacial region between the liquid and channel surface. The thermo-osmotic flow is proportional to the applied temperature gradient, and the factor of proportionality depends on temperature and intermolecular potential. The origin and characteristics of the phenomenon are discussed in molecular details.

컴퓨터지원협동학습(CSCL) 환경 하에서 사회연결망분석(SNA)을 이용한 학습자 상호작용연구

  • 정남호
    • Proceedings of the Korea Inteligent Information System Society Conference
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    • 2004.11a
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    • pp.361-368
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    • 2004
  • The purpose of the study was to explore the potential of the Social Network Analysis as an analytical tool for scientific investigation of learner-learner, or learner-tutor interaction within an Computer Supported Corporative Learning (CSCL) environment. Theoretical and methodological implication of the Social Network Analysis had been discussed. Following theoretical analysis, an exploratory empirical study was conducted to test statistical correlation between traditional performance measures such as achievement and team contribution index, and the centrality measure, one of the many quantitative measures the Social Network Analysis provides. Results indicate the centrality measure was correlated with the higher order learning performance and the peer-evaluated contribution indices. An interpretation of the results and their implication to instructional design theory and practices were provided along with some suggestions for future research.

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A drive-by inspection system via vehicle moving force identification

  • OBrien, E.J.;McGetrick, P.J.;Gonzalez, A.
    • Smart Structures and Systems
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    • v.13 no.5
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    • pp.821-848
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    • 2014
  • This paper presents a novel method to carry out monitoring of transport infrastructure such as pavements and bridges through the analysis of vehicle accelerations. An algorithm is developed for the identification of dynamic vehicle-bridge interaction forces using the vehicle response. Moving force identification theory is applied to a vehicle model in order to identify these dynamic forces between the vehicle and the road and/or bridge. A coupled half-car vehicle-bridge interaction model is used in theoretical simulations to test the effectiveness of the approach in identifying the forces. The potential of the method to identify the global bending stiffness of the bridge and to predict the pavement roughness is presented. The method is tested for a range of bridge spans using theoretical simulations and the influences of road roughness and signal noise on the accuracy of the results are investigated.

Hydrogen-Atom Abstraction Reaction of CF3CH2OCF3 by Hydroxyl Radical

  • Singh, Hari Ji;Mishra, Bhupesh Kumar;Rao, Pradeep Kumar
    • Bulletin of the Korean Chemical Society
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    • v.31 no.12
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    • pp.3718-3722
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    • 2010
  • Theoretical investigations are carried out on the title reaction by means of ab-initio and DFT methods. The optimized geometries, frequencies and minimum energy path are obtained at UB3LYP/6-311G(d,p) level. Single point energy calculations are performed at MP2 and MP4 levels of theory. Energetics are further refined by calculating the energy of the species with a modified Gaussian-2 method, G2M(CC,MP2). The rate constant of the reaction is calculated using Canonical Transition State Theory (CTST) utilizing the ab-initio data obtained during the present study and is found to be $5.47{\times}10^{-12}\;cm^3\;molecule^{-1}s^{-1}$ at 298 K and 1 atm.

Theoretical Computation of the Capacitance of an Asymmetric Coplanar Waveguide

  • Song, Chan Mi;Kwon, Gina;Lee, Jong Min;Lee, Kang-Yoon;Yang, Youngoo;Hwang, Keum Cheol
    • Journal of Electrical Engineering and Technology
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    • v.13 no.1
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    • pp.393-399
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    • 2018
  • An electrostatic boundary-value problem of a dielectric-wedge-backed, double-slotted conducting wedge is investigated to analyze an asymmetric coplanar waveguide with an infinite dielectric thickness using the Mellin transform and a mode-matching method. Our theoretical solution based on eigenfunction expansion and residue calculus is a rigorous and fast-convergent series form. Numerical computations are conducted to evaluate the potential field, capacitance, and characteristic impedance for various structures of the asymmetric coplanar waveguide. The computed results show good agreement with the simulated results.

Theoretical Studies of Surface Diffusion : Multidimensional TST and Effect of Surface Vibrations

  • 곽기정;신석민;이상엽;신국조
    • Bulletin of the Korean Chemical Society
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    • v.17 no.2
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    • pp.192-198
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    • 1996
  • We present a theoretical formulation of diffusion process on solid surface based on multidimensional transition state theory (TST). Surface diffusion of single adatom results from hopping processes on corrugated potential surface and is affected by surface vibrations of surface atoms. The rate of rare events such as hopping between lattice sites can be calculated by transition state theory. In order to include the interactions of the adatom with surface vibrations, it is assumed that the coordinates of adatom are coupled to the bath of harmonic oscillators whose frequencies are those of surface phonon modes. When nearest neighbor surface atoms are considered, we can construct Hamiltonians which contain terms for interactions of adatom with surface vibrations for the well minimum and the saddle point configurations, respectively. The escape rate constants, thus the surface diffusion parameters, are obtained by normal mode analysis of the force constant matrix based on the Hamiltonian. The analysis is applied to the diffusion coefficients of W, Ir, Pt and Ta atoms on the bcc(110) plane of W in the zero-coverage limit. The results of the calculations are encouraging considering the limitations of the model considered in the study.

A Method for Measurement of Roughness of Ground Surfaces by Using Fluxes of Scattered Lights (산란광속측정에 의한 연삭가공 표면 거칠기 측정방법)

  • Hong, Seong-Wook;Kim, Hyun-Soo
    • Journal of the Korean Society for Precision Engineering
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    • v.12 no.4
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    • pp.46-54
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    • 1995
  • This paper presents a simple method for measurenemt of roughness of ground surfaces. The present method utilizes fluxes of scattered lights condensed through lenses aligned along the specular direction. A theoretical analysis is preformed for the purpose of investigating the possibility of the method as well as determining the experimental condition. Experiments are also performed to show the effectiveness and robustness of the proposed method. The theoretical and experimental results show that the proposed method is simple enouth to implement and has a potential to identify a wide range of roughness of ground surfaces.

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Biochemical Methane Potential of Agricultural Byproduct in Greenhouse Vegetable Crops (국내 주요 시설채소 부산물의 메탄 생산 퍼텐셜)

  • Shin, Kook-Sik;Kim, Chang-Hyun;Lee, Sang-Eun;Yoon, Young-Man
    • Korean Journal of Soil Science and Fertilizer
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    • v.44 no.6
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    • pp.1252-1257
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    • 2011
  • Number of crop residues generated at large amount in agriculture can be utilized as substrate in methane production by anaerobic digestion. Greenhouse vegetable crop cultivation that adopting intensive agricultural system require the heating energy during winter season, meanwhile produce waste biomass source for the methane production. The purpose of this study was to investigate the methane production potential of greenhouse vegetable crop residues and to estimate material and energy yield in greenhouse system. Cucumber, tomato, and paprika as greenhouse vegetable crop were used in this study. Fallen fruit, leaf, and stem residues were collected at harvesting period from the farmhouses (Anseong, Gyeonggi, Korea) adopting an intensive greenhouse cultivation system. Also the amount of fallen vegetables and plant residues, and planting density of each vegetable crop were investigated. Chemical properties of vegetable waste biomass were determined, and theoretical methane potentials were calculated using Buswell's formula from the element analysis data. Also, BMP (Biochemical methane potential) assay was carried out for each vegetable waste biomass in mesophilic temperature ($38^{\circ}C$). Theoretical methane potential ($B_{th}$) and Ultimate methane potential ($B_u$) off stem, leaf, and fallen fruit in vegetable residues showed the range of $0.352{\sim}0.485Nm^3\;kg^{-1}VS_{added}$ and $0.136{\sim}0.354Nm^3\;kg^{-1}VS_{added}$ respectively. The biomass yields of residues of tomato, cucumber, and paprika were 28.3, 30.5, and $21.5Mg\;ha^{-1}$ respectively. The methane yields of tomato, cucumber, and paprika residues showed 645.0, 782.5, and $686.8Nm^3\;ha^{-1}$. Methane yield ($Nm^3\;ha^{-1}$) of crop residue may be highly influenced by biomass yield which is mainly affected by planting density.

Biochemical Methane Potential Analysis for Anaerobic Digestion of Marine Algae (해조류의 혐기소화를 위한 메탄생산퍼텐셜 분석)

  • Lee, Jun-Hyeong;Kim, Tae-Bong;Shin, Kook-Sik;Yoon, Young-Man
    • Journal of the Korea Organic Resources Recycling Association
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    • v.28 no.4
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    • pp.23-33
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    • 2020
  • Marine algae(Macro algae) are easily bio-degradable, and by-products are available as feed and fertilizer. The biomass of marine algae has higher CO2 absorption capacity than the wood system, and is highly valuable in use due to its fast growth speed and wide cultivation area without special cost for raw material production. In 2018, Marine algae production was 1,722,486ton, such as Saccharina japonica, Undaria pinnatifida and Porphyra tenera, the large amounts of by-products have been generated in the food processing facilities for commercialization. In this study, Saccharina japonica, Undaria pinnatifida were collected in the south coast region and Porphyra tenera was collected in the west coast region. The theoretical methane potential and biochemical methane potential(BMP) were analyzed, and Modified Gompertz model and Parallel first order kinetics model were adopted for the interpretation of the cumulative methane production curves. The theoretical methane potential of Saccharina japonica, Undaria pinnatifida and Porphyra tenera were 0.393, 0.373 and 0.435 N㎥/kg-VS, respectively. BMP obtained by the Modified gompertz model 0.226, 0.227, and 0.241 N㎥/kg-VS for Saccharina japonica, Undaria pinnatifida and Porphyra tenera, respectively. And BMP obtained by the Parallel first order kinetics model were 0.220, 0.243, and 0.240 N㎥/kg-VS for Saccharina japonica, Undaria pinnatifida and Porphyra tenera, respectively.

The Methane Production from Organic Waste on Single Anaerobic Digester Equipped with MET (Microbial Electrochemical Technology) (미생물 전기화학 기술이 설치된 단일 혐기성소화조에서 유기성폐기물로부터 메탄생성)

  • Park, Jungyu;Tian, Dongjie;Lee, Beom;Jun, Hangbae
    • Journal of Korean Society of Environmental Engineers
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    • v.38 no.4
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    • pp.201-209
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    • 2016
  • Theoretical maximum methane yield of glucose at STP (1 atm, $0^{\circ}C$) is 0.35 L $CH_4/g$ COD. However, most researched actual methane yields of anaerobic digester (AD) on lab scale is lower than theoretical ones. A wide range of them have been reported according to experiments methods and types of organic matters. Recent year, a MET (Microbial electrochemical technology) is a promising technology for producing sustainable bio energies from AD via rapid degradation of high concentration organic wastes, VFAs (Volatile Fatty Acids), toxic materials and non-degradable organic matters with electrochemical reactions. In this study, methane yields of food waste leachate and sewage waste sludge were evaluated by using BMP (Biochemical Methane Potential) and continuous AD tests. As the results, methane production volume from the anaerobic digester equipped with MET (AD + MET) was higher than conventional AD in the ratio of 2 to 3 times. The actual methane yields from all experiments were lower than those of theoretical value of glucose. The methane yield, however, from the AD + MET occurred similar to the theoretical one. Moreover, biogas compositions of AD and AD + MET were similar. Consequently, methane production from anaerobic digester with MET increased from the result of higher organic removal efficiency, while, further researches should be required for investigating methane production mechanisms in the anaerobic digester with MET.