• 오토저널
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• 제9권1호
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• pp.69-76
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• 1987

This paper deals with the theoretical prediction and cyclic variation of combustion characteristics in a four stroke, single0cylinder, diesel engine. Theoretical calculations employed a simple empirical model of analysis of energy equation for the thermodynamic system of engine cylinder. The cyclic variation of combustion characteristics is investigated, in term of frequency distribution and standard deviation of peak characteristics, as obtained by combustion analyzer system. The results of theoretical prediction are shown to be in close agreement with the experimental data. The effect of fuel injection timing, engine speed, cooling water temperature, and the compression ratio on the cyclic variations of combustion characteristics were discussed.

• Korean Chemical Engineering Research
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• 제53권6호
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• pp.723-729
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• 2015

고성능액체크로마토그래피(high-performance liquid chromatography, HPLC)에서 C18(octadecyl silica, ODS) 칼럼에서 고리형 아데노신 일인산(cyclic adenosine monophosphate, cAMP)의 크로마토그램을 얻은 후, 모멘트 분석을 수행하였다. 일반속도 모델(general rate model, GR model)을 기반으로 first absolute moment와 second central moment를 계산하였다. 모멘트 분석의 중요한 세 가지 계수인 분자확산계수(molecular diffusivity, $D_m$), 외부물질전달계수(external mass transfer coefficient, $k_f$), 입자내부확산계수(intra-particle diffusivity, $D_e$)는 각각 Wilke-Chang 식, Wilson-Geankoplis 식을 이용하고 이론단수(theoretical plate number) 식과 van Deemter 식을 비교하여 계산하였다. 실험은 각각 세 가지의 이동상 조성, 용질 농도, 유량 조건에서 수행하였다. Van Deemter 그래프를 그려 모멘트 분석결과를 정성적으로 정리했으며, 이론단 상당높이(height equivalent to a theoretical plate, HETP, $H_{total}$)에 $H_{ax}$, $H_f$, $H_d$가 미치는 영향을 알아보기 위해 van Deemter coefficient를 비교했다. HETP에 가장 큰 영향을 주는 요인은 입자내부확산($H_d$)이었으며 외부물질 전달($H_f$)는 그 영향이 매우 작았다.

• 한국철도학회:학술대회논문집
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• 한국철도학회 2008년도 춘계학술대회 논문집
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• pp.1676-1682
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• 2008

The vertical curve of railway is installed in changing point where the gradient is more than a certain degree to ensure safe operation of train and comfort of passengers. As a result of CAD work with 3D coordination by using the existing equation, it was found that the simple equation about vertical curve installation suggested in the surveying engineering or railway regulations did not reflect theoretical curvature of circular curve in a case of steep grade and large vertical radius. In this study, for derive precision equation and transition curve about vertical curve, gradient parameters, equation of circles and transition curve equation were used, and it was verified by CAD that the derived equation is exactly satisfied with parameters of geometrical circular and transition curve. This equation could be used to provide more smoothing operation of train and comfort of passengers on vertical curves, especially in case that railway requires precision vertical alignment of track such as super high-speed railway, LRT or Maglev system.

• 한국농공학회논문집
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• 제55권5호
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• pp.9-16
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• 2013

This study finds the characteristics of long-term settlement of Bottom Ash and to review the application of Singh-Mitchell creep equation and Burgers Model to the creep behavior of Bottom Ash. In the undrained state, it was confirmed that creep behavior appeared in the range to 30-80 % of the maximum deviator stress by applying condition in other three stresses through triaxial compression test after isotropically consolidation. By using sieve analysis, it was compared to each sample that was passed through 9.5 mm, 2 mm, 0.25 mm sieves. Also, using Singh-Mitchell creep equation and Burgers Model, it was compared between the theoretical behavior and the observed behavior for each sample. In the result, it is found that creep behavior of Bottom Ash is similar to the theoretical behavior of Singh-Mitchell creep equation and Burgers Model in early stage and it is possible to predict creep behavior of Bottom Ash by these models.

• 대한조선학회논문집
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• 제43권1호
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• pp.22-31
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• 2006

Recent studies have shown that the short time solution of the equation of motion for the rolling of ships is important in deciding the possibility of capsize of ships due to the excessive heel. Since most of known solutions for nonlinear equations of motion are long time or steady periodic solutions, here a simple way is described to get the short time solutions of the Duffing equation, which was chosen for deriving a criterion for the capsize of the ship. With the small external rolling moment, we first assume the state of the small damping and near resonance. Then, for cases when the frequency of the external moment is higher than the resonant one, an inequality was derived as a criterion for the capsize. This gives the range of the initial condition and the magnitude of the external moment which should be avoided for a ship to be safe from capsize. Furthermore, from the linearized equation, it is also shown that a simple and self-explanatory solution can be obtained consistent with that for the case of no damping, which yields the well-known linear growth with time.

• Bulletin of the Korean Chemical Society
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• 제33권3호
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• pp.933-940
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• 2012

Recently, it has been shown that quantum coherence appears in energy transfers of various photosynthetic lightharvesting complexes at from cryogenic to even room temperatures. Because the photosynthetic systems are inherently complex, these findings have subsequently interested many researchers in the field of both experiment and theory. From the theoretical part, simplified dynamics or semiclassical approaches have been widely used. In these approaches, the quantum-classical Liouville equation (QCLE) is the fundamental starting point. Toward the semiclassical scheme, approximations are needed to simplify the equations of motion of various degrees of freedom. Here, we have adopted the Poisson bracket mapping equation (PBME) as an approximate form of QCLE and applied it to find the time evolution of the excitation in a photosynthetic complex from marine algae. The benefit of using PBME is its similarity to conventional Hamiltonian dynamics. Through this, we confirmed the coherent population transfer behaviors in short time domain as previously reported with a more accurate but more time-consuming iterative linearized density matrix approach. However, we find that the site populations do not behave according to the Boltzmann law in the long time limit. We also test the effect of adding spurious high frequency vibrations to the spectral density of the bath, and find that their existence does not alter the dynamics to any significant extent as long as the associated reorganization energy is changed not too drastically. This suggests that adopting classical trajectory based ensembles in semiclassical simulations should not influence the coherence dynamics in any practical manner, even though the classical trajectories often yield spurious high frequency vibrational features in the spectral density.

• 한국원자력학회:학술대회논문집
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• 한국원자력학회 2005년도 추계학술발표회
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• pp.117-118
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• 2005

• Bulletin of the Korean Chemical Society
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• 제32권4호
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• pp.1187-1194
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• 2011

The hydrogen abstraction reaction of $CF_3CH_2CHO$ + OH has been studied theoretically by dual-level direct dynamics method. Two stable conformers, trans- and cis-$CF_3CH_2CHO$, have been located, and there are four distinct OH hydrogen-abstraction channels from t-$CF_3CH_2CHO$ and two channels from c-$CF_3CH_2CHO$. The required potential energy surface information for the kinetic calculation was obtained at the MCG3-MPWB//M06-2X/aug-cc-pVDZ level. The rate constants, which were calculated using improved canonical transitionstate theory with small-curvature tunneling correction (ICVT/SCT) were fitted by a four-parameter Arrhenius equation. It is shown that the reaction proceeds predominantly via the H-abstraction from the -CHO group over the temperature range 200-2000 K. The calculated rate constants were in good agreement with the experimental data between 263 and 358 K.

• 정보관리학회지
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• 제21권2호
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• pp.23-44
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• 2004

본 연구의 목적은 사회심리학 이론을 토대로 지역정보 시스템 이용모형을 개발함으로써, 지역주민을 위한 정보통신 서비스의 이용을 효과적으로 설명하는데 있다. 본 연구를 위해 필자는 Ajzen의 계획적 행위 이론(Theory of Planned Behavior: TPB)을 기본모형으로 선택하였는데, 이 이론은 (1) 지역정보 서비스 이용 결과에 대한 기대, (2) 주변 사람들의 권유, (3) 이용을 가능하게 하는 내외적 요인에 대한 자신의 통제 능력의 지각 등을 기본 골격으로 한다. 계획적 행위 이론은 일반적인 사회행동의 설명에 적용되어온 사회심리 이론이므로 필자는 지역정보 시스템 이용의 행동적 특성을 연구 모형에 반영하기 위하여 두 이론 즉, 인터넷 등 매체 이용을 설명하기 위하여 널리 적용되어온 이용과 충족 이론(Uses and gratifications)과 경영정보시스템 이용을 설명하기 위하여 적용되어 온 기술수용모형(Technology Acceptance Model: TAM)을 추가적으로 검토했다. 417명의 지역정보망 시스템 이용자로 부터 수집된 실증자료를 토대로 구조방정식모형(Structural Equation Model: SEM)을 이용하여 제안된 지역정보 시스템 이용모형을 검증한 후 향상된 수정 모형을 제안했다. 그 결과, 지역정보 시스템 이용에 영향을 미치는 주요 요인들로 지역정보를 이용하고자하는 의도, 태도, 주관적 규범, 정보습득에 대한 기대, 사회적 상호작용에 대한 기대, 지역 연계에 대한 기대, 및 개인관련 규범 신념 등을 밝혀 냈다. 이러한 결과를 중심으로 본 연구의 함의와 후속 연구과제가 결론에서 논의되었다.

• 한국지반공학회논문집
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• 제18권5호
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• pp.55-65
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• 2002

소성흐름을 발생시키는 측방유동 가능지반내에 설치된 매설관에 작용하는 토압에 대한 메카니즘을 규명하기 위해 파괴형상실험을 실시하고, 파괴형상실험을 토대로 지반변형속도를 고려하기 위해 Maxwell 점탄성 모델을 적용한 토압산정식을 제안하였다. 직접전단실험으로 구한 점성계수와 내부마찰각과 상재압을 고정하여 이론식으로 도출해낸 점성계수가 잘 일치하고 있음을 확인하였고 모형실험결과와 이론식에 의한 토압은 지반변형속도에 영향을 받으며 비교적 일치하며 지반변형이 없는 경우에도 정지토압을 받음을 알 수 있다. 또한, 지반의 지지력은 점성토에서는 관입전단파괴시의 값과 거의 일치하였다. 또한, 매설관 주변지반의 파괴모드는 매설관직경과 무관하게 지반변형속도에 영향을 받으며 작용토압은 균질한 지층의 경우 선형적으로 증가하고 조립질에 가까울수록 선형적 감소치를 보이므로 매설관주변지반의 매립재를 이용하여 매설관주변의 토압을 경감시킬 수 있음을 알 수 있다.