• Title/Summary/Keyword: Theoretical equation

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압축 착화 기관의 연소 변동 특성에 관한 연구

  • 이창식
    • Journal of the korean Society of Automotive Engineers
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    • v.9 no.1
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    • pp.69-76
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    • 1987
  • This paper deals with the theoretical prediction and cyclic variation of combustion characteristics in a four stroke, single0cylinder, diesel engine. Theoretical calculations employed a simple empirical model of analysis of energy equation for the thermodynamic system of engine cylinder. The cyclic variation of combustion characteristics is investigated, in term of frequency distribution and standard deviation of peak characteristics, as obtained by combustion analyzer system. The results of theoretical prediction are shown to be in close agreement with the experimental data. The effect of fuel injection timing, engine speed, cooling water temperature, and the compression ratio on the cyclic variations of combustion characteristics were discussed.

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Analysis of Cyclic Adenosine Monophosphate (cAMP) Separation via RP-HPLC (reversed-phase high-performance liquid chromatography) by the Moment Method and the van Deemter Equation (역상 크로마토그래피에서 모멘트 방법과 van Deemter 식을 이용한 고리형 아데노신 일인산의 분리특성 연구)

  • Lee, Il Song;Ko, Kwan Young;Kim, In Ho
    • Korean Chemical Engineering Research
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    • v.53 no.6
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    • pp.723-729
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    • 2015
  • The moment analysis of cyclic adenosine monophosphate (cAMP) was performed using chromatograms that were obtained with the pulse input method from an octadecyl silica (ODS) high-performance liquid chromatography (HPLC) column. The general rate (GR) model was employed to calculate the first absolute moment and the second central moment. Three important coefficients for moment analysis, which are molecular diffusivity ($D_m$), external mass transfer coefficient ($k_f$), and intra-particle diffusivity ($D_e$), were estimated by the Wilke-Chang equation, Wilson-Geankoplis equation, and comparing van Deemter equation to theoretical plate number equation, respectively. Experiments were conducted by various conditions of flow rates, methanol volume ratio of the mobile phase, and solute concentration. After the moment analysis, results were organized by van Deemter plots. Also van Deemter coefficients were compared each other to effect $H_{ax}$, $H_f$, and $H_d$ on height equivalent to a theoretical plate (HETP, $H_{total}$). The value of intraparticle diffusion ($H_d$) was the primary factor which makes for HETP whereas external mass transfer ($H_f$) was disregardable factor.

A Study for Precision Equation and Transition curve of Vertical Curve (종곡선의 정밀식과 완화곡선에 관한 연구)

  • Shin, Soon-Ho;Kim, Yong-Eul
    • Proceedings of the KSR Conference
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    • 2008.06a
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    • pp.1676-1682
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    • 2008
  • The vertical curve of railway is installed in changing point where the gradient is more than a certain degree to ensure safe operation of train and comfort of passengers. As a result of CAD work with 3D coordination by using the existing equation, it was found that the simple equation about vertical curve installation suggested in the surveying engineering or railway regulations did not reflect theoretical curvature of circular curve in a case of steep grade and large vertical radius. In this study, for derive precision equation and transition curve about vertical curve, gradient parameters, equation of circles and transition curve equation were used, and it was verified by CAD that the derived equation is exactly satisfied with parameters of geometrical circular and transition curve. This equation could be used to provide more smoothing operation of train and comfort of passengers on vertical curves, especially in case that railway requires precision vertical alignment of track such as super high-speed railway, LRT or Maglev system.

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The Time-Dependent Behavior Characteristic of Bottom Ash by Maximum Particle Size and Application of Creep Models (Bottom Ash의 최대입경에 따른 시간-의존적 거동 특성 및 크리프 모델 적용성 검토)

  • Kim, Tae-Wan;Son, Young-Hwan;Bong, Tae-Ho;Noh, Soo-Kack;Park, Jae-Sung
    • Journal of The Korean Society of Agricultural Engineers
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    • v.55 no.5
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    • pp.9-16
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    • 2013
  • This study finds the characteristics of long-term settlement of Bottom Ash and to review the application of Singh-Mitchell creep equation and Burgers Model to the creep behavior of Bottom Ash. In the undrained state, it was confirmed that creep behavior appeared in the range to 30-80 % of the maximum deviator stress by applying condition in other three stresses through triaxial compression test after isotropically consolidation. By using sieve analysis, it was compared to each sample that was passed through 9.5 mm, 2 mm, 0.25 mm sieves. Also, using Singh-Mitchell creep equation and Burgers Model, it was compared between the theoretical behavior and the observed behavior for each sample. In the result, it is found that creep behavior of Bottom Ash is similar to the theoretical behavior of Singh-Mitchell creep equation and Burgers Model in early stage and it is possible to predict creep behavior of Bottom Ash by these models.

Theoretical Analysis at One Degree-at-Freedom Model for Rolling at Ships with Focus on Capsize (횡동요에 기인하는 전복에 대한 1-자유도계 모형의 이론해석)

  • Lee, Seung-Joan
    • Journal of the Society of Naval Architects of Korea
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    • v.43 no.1 s.145
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    • pp.22-31
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    • 2006
  • Recent studies have shown that the short time solution of the equation of motion for the rolling of ships is important in deciding the possibility of capsize of ships due to the excessive heel. Since most of known solutions for nonlinear equations of motion are long time or steady periodic solutions, here a simple way is described to get the short time solutions of the Duffing equation, which was chosen for deriving a criterion for the capsize of the ship. With the small external rolling moment, we first assume the state of the small damping and near resonance. Then, for cases when the frequency of the external moment is higher than the resonant one, an inequality was derived as a criterion for the capsize. This gives the range of the initial condition and the magnitude of the external moment which should be avoided for a ship to be safe from capsize. Furthermore, from the linearized equation, it is also shown that a simple and self-explanatory solution can be obtained consistent with that for the case of no damping, which yields the well-known linear growth with time.

Behavior of Poisson Bracket Mapping Equation in Studying Excitation Energy Transfer Dynamics of Cryptophyte Phycocyanin 645 Complex

  • Lee, Weon-Gyu;Kelly, Aaron;Rhee, Young-Min
    • Bulletin of the Korean Chemical Society
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    • v.33 no.3
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    • pp.933-940
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    • 2012
  • Recently, it has been shown that quantum coherence appears in energy transfers of various photosynthetic lightharvesting complexes at from cryogenic to even room temperatures. Because the photosynthetic systems are inherently complex, these findings have subsequently interested many researchers in the field of both experiment and theory. From the theoretical part, simplified dynamics or semiclassical approaches have been widely used. In these approaches, the quantum-classical Liouville equation (QCLE) is the fundamental starting point. Toward the semiclassical scheme, approximations are needed to simplify the equations of motion of various degrees of freedom. Here, we have adopted the Poisson bracket mapping equation (PBME) as an approximate form of QCLE and applied it to find the time evolution of the excitation in a photosynthetic complex from marine algae. The benefit of using PBME is its similarity to conventional Hamiltonian dynamics. Through this, we confirmed the coherent population transfer behaviors in short time domain as previously reported with a more accurate but more time-consuming iterative linearized density matrix approach. However, we find that the site populations do not behave according to the Boltzmann law in the long time limit. We also test the effect of adding spurious high frequency vibrations to the spectral density of the bath, and find that their existence does not alter the dynamics to any significant extent as long as the associated reorganization energy is changed not too drastically. This suggests that adopting classical trajectory based ensembles in semiclassical simulations should not influence the coherence dynamics in any practical manner, even though the classical trajectories often yield spurious high frequency vibrational features in the spectral density.

Theoretical Studies on Mechanism and Kinetics of the Hydrogen-Abstraction Reaction of CF3CH2CHO with OH Radicals

  • Ci, Cheng-Gang;Yu, Hong-Bo;Wan, Su-Qin;Liu, Jing-Yao;Sun, Chia-Chung
    • Bulletin of the Korean Chemical Society
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    • v.32 no.4
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    • pp.1187-1194
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    • 2011
  • The hydrogen abstraction reaction of $CF_3CH_2CHO$ + OH has been studied theoretically by dual-level direct dynamics method. Two stable conformers, trans- and cis-$CF_3CH_2CHO$, have been located, and there are four distinct OH hydrogen-abstraction channels from t-$CF_3CH_2CHO$ and two channels from c-$CF_3CH_2CHO$. The required potential energy surface information for the kinetic calculation was obtained at the MCG3-MPWB//M06-2X/aug-cc-pVDZ level. The rate constants, which were calculated using improved canonical transitionstate theory with small-curvature tunneling correction (ICVT/SCT) were fitted by a four-parameter Arrhenius equation. It is shown that the reaction proceeds predominantly via the H-abstraction from the -CHO group over the temperature range 200-2000 K. The calculated rate constants were in good agreement with the experimental data between 263 and 358 K.

Understanding the Use of Community Informatics: A Structural Equation Modeling Approach (지역정보 시스템 이용모형 개발을 위한 이론적 고찰 및 실증적 연구)

  • 권나현
    • Journal of the Korean Society for information Management
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    • v.21 no.2
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    • pp.23-44
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    • 2004
  • This study proposed a theoretical framework that could explain the service use of a community informatics. The proposed community informatics use model was developed based on three theoretical models: (1) Ajzen's Theory of Planned Behavior (TPB) from social psychology: (2) Uses and gratifications approaches from media use research; and (3) Technology Acceptance Model(TAM) from information technology use research. The proposed model consists of three basic components: expectations of the outcomes from use, approvals from important others, and perceivied controllability over using the service. The initially proposed model was assessed using structural equation modeling, and then re-sepcified in order to propose a better fitting model. The initially proposed and revised community informatics use models were discussed with their theoretical and practical implications.

Evaluation of Lateral Earth Pressure on Buried Pipes in Soft Ground Undergoing Lateral Movement (측방유동지반속 지중매설관에 작용하는 토압식 산정)

  • 홍원표;한중근;배태수
    • Journal of the Korean Geotechnical Society
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    • v.18 no.5
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    • pp.55-65
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    • 2002
  • Model tests were performed to investigate the mechanism of lateral earth pressure on a buried pipe, which was installed in a plastic flowing soil mass undergoing lateral movement. On the basis of failure mode tests, the equation of lateral earth pressure to apply Maxwell's visco-elastic model was proposed to consider the soil deformation velocity. Through a series of model tests of differential soil deformation velocity, lateral earth pressure of theoretical equation was compared with experimental results. When lateral soil movement was raised, the lateral earth pressure acting on buried pipe increases linearly with the soil deformation velocity. It shows that the lateral earth pressure on buried pipe is largely affected by soil deformation velocity. When plastic soil movement was raised, lateral earth pressure predicted by theoretical equation showed good agreement with experimental results. Also, coefficient of viscosity by theoretical equation had a good agreement with direct shear test results.